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Generation of Hydrogen, Lignin and Sodium Hydroxide from Pulping Black Liquor by Electrolysis

Author

Listed:
  • Guangzai Nong

    (Institute of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China)

  • Zongwen Zhou

    (Institute of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China)

  • Shuangfei Wang

    (Institute of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China)

Abstract

Black liquor is generated in Kraft pulping of wood or non-wood raw material in pulp mills, and regarded as a renewable resource. The objective of this paper was to develop an effective means to remove the water pollutants by recovery of both lignin and sodium hydroxide from black liquor, based on electrolysis. The treatment of a 1000 mL of black liquor (122 g/L solid contents) consumed 345.6 kJ of electric energy, and led to the generation of 30.7 g of sodium hydroxide, 0.82 g of hydrogen gas and 52.1 g of biomass solids. Therefore, the recovery ratios of elemental sodium and biomass solids are 80.4% and 76%, respectively. Treating black liquor by electrolysis is an environmentally friendly technology that can, in particular, be an alternative process in addressing the environmental issues of pulping waste liquor to the small-scale mills without black liquor recovery.

Suggested Citation

  • Guangzai Nong & Zongwen Zhou & Shuangfei Wang, 2015. "Generation of Hydrogen, Lignin and Sodium Hydroxide from Pulping Black Liquor by Electrolysis," Energies, MDPI, vol. 9(1), pages 1-11, December.
  • Handle: RePEc:gam:jeners:v:9:y:2015:i:1:p:13-:d:61320
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    References listed on IDEAS

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    1. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    2. Y. X. Chen & A. Lavacchi & H. A. Miller & M. Bevilacqua & J. Filippi & M. Innocenti & A. Marchionni & W. Oberhauser & L. Wang & F. Vizza, 2014. "Nanotechnology makes biomass electrolysis more energy efficient than water electrolysis," Nature Communications, Nature, vol. 5(1), pages 1-6, September.
    3. Cassie Marie Welker & Vimal Kumar Balasubramanian & Carloalberto Petti & Krishan Mohan Rai & Seth DeBolt & Venugopal Mendu, 2015. "Engineering Plant Biomass Lignin Content and Composition for Biofuels and Bioproducts," Energies, MDPI, vol. 8(8), pages 1-23, July.
    4. Budzianowski, Wojciech M., 2012. "Negative carbon intensity of renewable energy technologies involving biomass or carbon dioxide as inputs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(9), pages 6507-6521.
    5. Zhang, Xinghua & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Huang, Xiaoming & Yu, Yuxiao, 2013. "Production of cyclohexane from lignin degradation compounds over Ni/ZrO2–SiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 533-538.
    6. Wen, Jia-Long & Sun, Shao-Long & Yuan, Tong-Qi & Xu, Feng & Sun, Run-Cang, 2014. "Understanding the chemical and structural transformations of lignin macromolecule during torrefaction," Applied Energy, Elsevier, vol. 121(C), pages 1-9.
    7. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Bio-refinery system in a pulp mill for methanol production with comparison of pressurized black liquor gasification and dry gasification using direct causticization," Applied Energy, Elsevier, vol. 90(1), pages 24-31.
    8. Xiaona Lin & Shujuan Sui & Shun Tan & Charles U. Pittman & Jianping Sun & Zhijun Zhang, 2015. "Fast Pyrolysis of Four Lignins from Different Isolation Processes Using Py-GC/MS," Energies, MDPI, vol. 8(6), pages 1-15, June.
    9. Eriksson, H. & Harvey, S., 2004. "Black liquor gasification—consequences for both industry and society," Energy, Elsevier, vol. 29(4), pages 581-612.
    10. Marcelo Hamaguchi & Marcelo Cardoso & Esa Vakkilainen, 2012. "Alternative Technologies for Biofuels Production in Kraft Pulp Mills—Potential and Prospects," Energies, MDPI, vol. 5(7), pages 1-22, July.
    11. Nong, Guangzai & Huang, Lijie & Mo, Haitao & Wang, Shuangfei, 2013. "Investigate the variability of gas compositions and thermal efficiency of bagasse black liquor gasification," Energy, Elsevier, vol. 49(C), pages 178-181.
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