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Hydrogen production and purification from the water–gas shift reaction on CuO/CeO2–TiO2 catalysts

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  • Maciel, Cristhiane Guimarães
  • Silva, Tatiana de Freitas
  • Assaf, Elisabete Moreira
  • Assaf, José Mansur

Abstract

The present study evaluates the use of copper catalysts supported on ceria and/or titania for water–gas shift reaction (WGSR). The effect of metal-support interaction coupled with structural properties such as surface area and oxidation state favor the conversion of CO to CO2 and the hydrogen formation. The strong copper–ceria interaction promotes the good performance of the CuCe system, while the poor interaction between titania and copper disadvantaged the performance of the CuTi catalyst. However, the addition of ceria into the titania support hampers the transformation of anatase to rutile phase, facilitates the reduction of metal species and favors the metal-support interaction. The combined results of these features are a better performance for CuCeTi catalyst compared to the system only containing ceria or titania. The catalytic evaluation has revealed that both CuCeTi and CuCe catalysts produce significant amounts of H2 during the WGSR process and favor a H2/CO ratio close to 2. The use of these catalysts for WGSR, especially at high temperature (HT-WGSR), showed good performance, fulfilling the goal of CO in reducing levels for hydrogen fuel cell applications.

Suggested Citation

  • Maciel, Cristhiane Guimarães & Silva, Tatiana de Freitas & Assaf, Elisabete Moreira & Assaf, José Mansur, 2013. "Hydrogen production and purification from the water–gas shift reaction on CuO/CeO2–TiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 52-59.
    • Handle: RePEc:eee:appene:v:112:y:2013:i:c:p:52-59
    DOI: 10.1016/j.apenergy.2013.06.003
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    1. Wang, Xiaoyue & Li, Haibo & Liu, Yong & Zhao, Wenxia & Liang, Chaolun & Huang, Hong & Mo, Delin & Liu, Zhong & Yu, Xiao & Deng, Youjun & Shen, Hui, 2012. "Hydrothermal synthesis of well-aligned hierarchical TiO2 tubular macrochannel arrays with large surface area for high performance dye-sensitized solar cells," Applied Energy, Elsevier, vol. 99(C), pages 198-205.
    2. Guo, Yong & Azmat, Muhammad Usman & Liu, Xiaohui & Wang, Yanqin & Lu, Guanzhong, 2012. "Effect of support’s basic properties on hydrogen production in aqueous-phase reforming of glycerol and correlation between WGS and APR," Applied Energy, Elsevier, vol. 92(C), pages 218-223.
    3. Khobragade, Murnal & Majhi, Sachchit & Pant, K.K., 2012. "Effect of K and CeO2 promoters on the activity of Co/SiO2 catalyst for liquid fuel production from syngas," Applied Energy, Elsevier, vol. 94(C), pages 385-394.
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    Cited by:

    1. Lee, Chan Hyun & Lee, Ki Bong, 2017. "Sorption-enhanced water gas shift reaction for high-purity hydrogen production: Application of a Na-Mg double salt-based sorbent and the divided section packing concept," Applied Energy, Elsevier, vol. 205(C), pages 316-322.
    2. Chen, Wei-Hsin & Chen, Chia-Yang, 2020. "Water gas shift reaction for hydrogen production and carbon dioxide capture: A review," Applied Energy, Elsevier, vol. 258(C).
    3. Renda, Simona & Ricca, Antonio & Palma, Vincenzo, 2020. "Precursor salts influence in Ruthenium catalysts for CO2 hydrogenation to methane," Applied Energy, Elsevier, vol. 279(C).
    4. Wang, Shuofeng & Ji, Changwei & Zhang, Bo & Liu, Xiaolong, 2014. "Lean burn performance of a hydrogen-blended gasoline engine at the wide open throttle condition," Applied Energy, Elsevier, vol. 136(C), pages 43-50.
    5. Gradisher, Logan & Dutcher, Bryce & Fan, Maohong, 2015. "Catalytic hydrogen production from fossil fuels via the water gas shift reaction," Applied Energy, Elsevier, vol. 139(C), pages 335-349.

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    More about this item

    Keywords

    WGSR; H2 production; CO purification; Fuel cells;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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