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High Temperature Pyrolysis of Municipal Plastic Waste Using Me/Ni/ZSM-5 Catalysts: The Effect of Metal/Nickel Ratio

Author

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  • Mohammed Al-asadi

    (Institute of Chemical Engineering and Process Engineering, University of Pannonia, Egyetem utca 10, H-8200 Veszprém, Hungary)

  • Norbert Miskolczi

    (Institute of Chemical Engineering and Process Engineering, University of Pannonia, Egyetem utca 10, H-8200 Veszprém, Hungary)

Abstract

This work is dedicated to the high temperature pyrolysis of municipal plastic waste using Me/Ni/ZSM-5 catalysts. Catalysts were synthetized by wet impregnation. In addition to nickel, synthetic zeolite catalysts contain calcium, ceria, lanthanum, magnesia or manganese. Catalysts were prepared and tested using 0.1, 0.5 and 2.0 Me/Ni ratios. Catalyst morphology was investigated by SEM and surface analysis. Higher concentrations of second metals can block catalyst pore channels due to the more coke formation, which leads to smaller surface area. Furthermore, the chemicals used for the impregnation were among the catalyst grains, especially in case of 2.0 Me/Ni ratios. For pyrolysis, a horizontal tubular furnace reactor was used at 700 °C. The highest hydrogen and syngas yields were observed using ceria- and lanthanum-covered catalysts. The maximum production of syngas and hydrogen (69.8 and 49.2 mmol/g raw material) was found in the presence of Ce/Ni/ZSM-5 catalyst with a 0.5 Me/Ni ratio.

Suggested Citation

  • Mohammed Al-asadi & Norbert Miskolczi, 2020. "High Temperature Pyrolysis of Municipal Plastic Waste Using Me/Ni/ZSM-5 Catalysts: The Effect of Metal/Nickel Ratio," Energies, MDPI, vol. 13(5), pages 1-11, March.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1284-:d:330855
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    References listed on IDEAS

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    1. Kunwar, Bidhya & Cheng, H.N. & Chandrashekaran, Sriram R & Sharma, Brajendra K, 2016. "Plastics to fuel: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 421-428.
    2. Khobragade, Murnal & Majhi, Sachchit & Pant, K.K., 2012. "Effect of K and CeO2 promoters on the activity of Co/SiO2 catalyst for liquid fuel production from syngas," Applied Energy, Elsevier, vol. 94(C), pages 385-394.
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    1. Ying-Che Hung & Chien-Hua Ho & Liang-Yü Chen & Shih-Chieh Ma & Te-I Liu & Yi-Chen Shen, 2023. "Using a Low-Temperature Pyrolysis Device for Polymeric Waste to Implement a Distributed Energy System," Sustainability, MDPI, vol. 15(2), pages 1-15, January.

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