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Kilowatt-scale solar hydrogen production system using a concentrated integrated photoelectrochemical device

Author

Listed:
  • Isaac Holmes-Gentle

    (Laboratory of Renewable Energy Science and Engineering, EPFL)

  • Saurabh Tembhurne

    (Laboratory of Renewable Energy Science and Engineering, EPFL
    SoHHytec SA, EPFL Innovation Park, Batiment C)

  • Clemens Suter

    (Laboratory of Renewable Energy Science and Engineering, EPFL)

  • Sophia Haussener

    (Laboratory of Renewable Energy Science and Engineering, EPFL)

Abstract

The production of synthetic fuels and chemicals from solar energy and abundant reagents offers a promising pathway to a sustainable fuel economy and chemical industry. For the production of hydrogen, photoelectrochemical or integrated photovoltaic and electrolysis devices have demonstrated outstanding performance at the lab scale, but there remains a lack of larger-scale on-sun demonstrations (>100 W). Here we present the successful scaling of a thermally integrated photoelectrochemical device—utilizing concentrated solar irradiation—to a kW-scale pilot plant capable of co-generation of hydrogen and heat. A solar-to-hydrogen device-level efficiency of greater than 20% at an H2 production rate of >2.0 kW (>0.8 g min−1) is achieved. A validated model-based optimization highlights the dominant energetic losses and predicts straightforward strategies to improve the system-level efficiency of >5.5% towards the device-level efficiency. We identify solutions to the key technological challenges, control and operation strategies and discuss the future outlook of this emerging technology.

Suggested Citation

  • Isaac Holmes-Gentle & Saurabh Tembhurne & Clemens Suter & Sophia Haussener, 2023. "Kilowatt-scale solar hydrogen production system using a concentrated integrated photoelectrochemical device," Nature Energy, Nature, vol. 8(6), pages 586-596, June.
  • Handle: RePEc:nat:natene:v:8:y:2023:i:6:d:10.1038_s41560-023-01247-2
    DOI: 10.1038/s41560-023-01247-2
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    References listed on IDEAS

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    1. Hiroshi Nishiyama & Taro Yamada & Mamiko Nakabayashi & Yoshiki Maehara & Masaharu Yamaguchi & Yasuko Kuromiya & Yoshie Nagatsuma & Hiromasa Tokudome & Seiji Akiyama & Tomoaki Watanabe & Ryoichi Narush, 2021. "Photocatalytic solar hydrogen production from water on a 100-m2 scale," Nature, Nature, vol. 598(7880), pages 304-307, October.
    2. Saurabh Tembhurne & Fredy Nandjou & Sophia Haussener, 2019. "A thermally synergistic photo-electrochemical hydrogen generator operating under concentrated solar irradiation," Nature Energy, Nature, vol. 4(5), pages 399-407, May.
    3. James L. Young & Myles A. Steiner & Henning Döscher & Ryan M. France & John A. Turner & Todd G. Deutsch, 2017. "Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures," Nature Energy, Nature, vol. 2(4), pages 1-8, April.
    4. Buscemi, Alessandro & Lo Brano, Valerio & Chiaruzzi, Christian & Ciulla, Giuseppina & Kalogeri, Christina, 2020. "A validated energy model of a solar dish-Stirling system considering the cleanliness of mirrors," Applied Energy, Elsevier, vol. 260(C).
    5. Jieyang Jia & Linsey C. Seitz & Jesse D. Benck & Yijie Huo & Yusi Chen & Jia Wei Desmond Ng & Taner Bilir & James S. Harris & Thomas F. Jaramillo, 2016. "Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30%," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
    6. Qian Wang & Chanon Pornrungroj & Stuart Linley & Erwin Reisner, 2022. "Strategies to improve light utilization in solar fuel synthesis," Nature Energy, Nature, vol. 7(1), pages 13-24, January.
    7. Davis, Steven J & Lewis, Nathan S. & Shaner, Matthew & Aggarwal, Sonia & Arent, Doug & Azevedo, Inês & Benson, Sally & Bradley, Thomas & Brouwer, Jack & Chiang, Yet-Ming & Clack, Christopher T.M. & Co, 2018. "Net-Zero Emissions Energy Systems," Institute of Transportation Studies, Working Paper Series qt7qv6q35r, Institute of Transportation Studies, UC Davis.
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    2. Jimiao Zhang & Jie Li, 2024. "Revolution in Renewables: Integration of Green Hydrogen for a Sustainable Future," Energies, MDPI, vol. 17(16), pages 1-26, August.

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