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High-nickel layered oxide cathodes for lithium-based automotive batteries

Author

Listed:
  • Wangda Li

    (University of Texas at Austin)

  • Evan M. Erickson

    (University of Texas at Austin)

  • Arumugam Manthiram

    (University of Texas at Austin)

Abstract

High-nickel layered oxide cathode materials will be at the forefront to enable longer driving-range electric vehicles at more affordable costs with lithium-based batteries. A continued push to higher energy content and less usage of costly raw materials, such as cobalt, while preserving acceptable power, lifetime and safety metrics, calls for a suite of strategic compositional, morphological and microstructural designs and efficient material production processes. In this Perspective, we discuss several important design considerations for high-nickel layered oxide cathodes that will be implemented in the automotive market for the coming decade. We outline various intrinsic restraints of maximizing their energy output and compare current/emerging development roadmaps approaching low-/zero-cobalt chemistry. Materials production is another focus, relevant to driving down costs and addressing the practical challenges of high-nickel layered oxides for demanding vehicle applications. We further assess a series of stabilization techniques on their prospects to fulfill the aggressive targets of vehicle electrification.

Suggested Citation

  • Wangda Li & Evan M. Erickson & Arumugam Manthiram, 2020. "High-nickel layered oxide cathodes for lithium-based automotive batteries," Nature Energy, Nature, vol. 5(1), pages 26-34, January.
    • Handle: RePEc:nat:natene:v:5:y:2020:i:1:d:10.1038_s41560-019-0513-0
    DOI: 10.1038/s41560-019-0513-0
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    Cited by:

    1. Lu, Jiajia & Zhang, Yanqiong & Huang, Weiwei & Omran, Mamdouh & Zhang, Fan & Gao, Lei & Chen, Guo, 2023. "Reductive roasting of cathode powder of spent ternary lithium-ion battery by pyrolysis of invasive plant Crofton weed," Renewable Energy, Elsevier, vol. 206(C), pages 86-96.
    2. Han Yang & Shiyu Lin & Alex Cheng & Fangbo He & Zhoulu Wang & Yutong Wu & Yi Zhang & Xiang Liu, 2023. "Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries," Energies, MDPI, vol. 16(7), pages 1-21, March.
    3. Zhichen Xue & Nikhil Sharma & Feixiang Wu & Piero Pianetta & Feng Lin & Luxi Li & Kejie Zhao & Yijin Liu, 2023. "Asynchronous domain dynamics and equilibration in layered oxide battery cathode," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Zhongsheng Dai & Zhujie Li & Renjie Chen & Feng Wu & Li Li, 2023. "Defective oxygen inert phase stabilized high-voltage nickel-rich cathode for high-energy lithium-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Gogwon Choe & Hyungsub Kim & Jaesub Kwon & Woochul Jung & Kyu-Young Park & Yong-Tae Kim, 2024. "Re-evaluation of battery-grade lithium purity toward sustainable batteries," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Ziyao Gao & Chenglong Zhao & Kai Zhou & Junru Wu & Yao Tian & Xianming Deng & Lihan Zhang & Kui Lin & Feiyu Kang & Lele Peng & Marnix Wagemaker & Baohua Li, 2024. "Kirkendall effect-induced uniform stress distribution stabilizes nickel-rich layered oxide cathodes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Yu, Hanqing & Zhang, Lisheng & Wang, Wentao & Li, Shen & Chen, Siyan & Yang, Shichun & Li, Junfu & Liu, Xinhua, 2023. "State of charge estimation method by using a simplified electrochemical model in deep learning framework for lithium-ion batteries," Energy, Elsevier, vol. 278(C).
    8. Jung-Hui Kim & Ju-Myung Kim & Seok-Kyu Cho & Nag-Young Kim & Sang-Young Lee, 2022. "Redox-homogeneous, gel electrolyte-embedded high-mass-loading cathodes for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Tang, Chen & Sprecher, Benjamin & Tukker, Arnold & Mogollón, José M., 2021. "The impact of climate policy implementation on lithium, cobalt and nickel demand: The case of the Dutch automotive sector up to 2040," Resources Policy, Elsevier, vol. 74(C).
    10. Ruixia Chu & Yujian Zou & Peidong Zhu & Shiwei Tan & Fangyuan Qiu & Wenjun Fu & Fu Niu & Wanyou Huang, 2022. "Progress of Single-Crystal Nickel-Cobalt-Manganese Cathode Research," Energies, MDPI, vol. 15(23), pages 1-32, December.
    11. Yi Pei & Qing Chen & Meiyu Wang & Pengjun Zhang & Qingyong Ren & Jingkai Qin & Penghao Xiao & Li Song & Yu Chen & Wen Yin & Xin Tong & Liang Zhen & Peng Wang & Cheng-Yan Xu, 2022. "A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    12. Danfeng Zhang & Ming Liu & Jiabin Ma & Ke Yang & Zhen Chen & Kaikai Li & Chen Zhang & Yinping Wei & Min Zhou & Peng Wang & Yuanbiao He & Wei Lv & Quan-Hong Yang & Feiyu Kang & Yan-Bing He, 2022. "Lithium hexamethyldisilazide as electrolyte additive for efficient cycling of high-voltage non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    13. Muhammad Mominur Rahman & Sha Tan & Yang Yang & Hui Zhong & Sanjit Ghose & Iradwikanari Waluyo & Adrian Hunt & Lu Ma & Xiao-Qing Yang & Enyuan Hu, 2023. "An inorganic-rich but LiF-free interphase for fast charging and long cycle life lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    14. Pranjal Barman & Lachit Dutta & Brian Azzopardi, 2023. "Electric Vehicle Battery Supply Chain and Critical Materials: A Brief Survey of State of the Art," Energies, MDPI, vol. 16(8), pages 1-23, April.
    15. Camba, Alvin, 2021. "The unintended consequences of national regulations: Large-scale-small-scale relations in Philippine and Indonesian nickel mining," Resources Policy, Elsevier, vol. 74(C).
    16. Shaofeng Li & Guannan Qian & Xiaomei He & Xiaojing Huang & Sang-Jun Lee & Zhisen Jiang & Yang Yang & Wei-Na Wang & Dechao Meng & Chang Yu & Jun-Sik Lee & Yong S. Chu & Zi-Feng Ma & Piero Pianetta & Ji, 2022. "Thermal-healing of lattice defects for high-energy single-crystalline battery cathodes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    17. Liang, Yanan & Kleijn, René & van der Voet, Ester, 2023. "Increase in demand for critical materials under IEA Net-Zero emission by 2050 scenario," Applied Energy, Elsevier, vol. 346(C).
    18. Held, Marcel & Tuchschmid, Martin & Zennegg, Markus & Figi, Renato & Schreiner, Claudia & Mellert, Lars Derek & Welte, Urs & Kompatscher, Michael & Hermann, Michael & Nachef, Léa, 2022. "Thermal runaway and fire of electric vehicle lithium-ion battery and contamination of infrastructure facility," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).

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