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A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries

Author

Listed:
  • Yi Pei

    (Harbin Institute of Technology (Shenzhen))

  • Qing Chen

    (Harbin Institute of Technology (Shenzhen))

  • Meiyu Wang

    (Nanjing University)

  • Pengjun Zhang

    (University of Science and Technology of China)

  • Qingyong Ren

    (Chinese Academy of Sciences
    Spallation Neutron Source Science Center)

  • Jingkai Qin

    (Harbin Institute of Technology (Shenzhen))

  • Penghao Xiao

    (Dalhousie University)

  • Li Song

    (University of Science and Technology of China)

  • Yu Chen

    (Chinese Academy of Sciences)

  • Wen Yin

    (Chinese Academy of Sciences
    Spallation Neutron Source Science Center)

  • Xin Tong

    (Chinese Academy of Sciences
    Spallation Neutron Source Science Center)

  • Liang Zhen

    (Harbin Institute of Technology (Shenzhen)
    Harbin Institute of Technology)

  • Peng Wang

    (Nanjing University
    University of Warwick)

  • Cheng-Yan Xu

    (Harbin Institute of Technology (Shenzhen)
    Harbin Institute of Technology)

Abstract

The limited capacity of the positive electrode active material in non-aqueous rechargeable lithium-based batteries acts as a stumbling block for developing high-energy storage devices. Although lithium transition metal oxides are high-capacity electrochemical active materials, the structural instability at high cell voltages (e.g., >4.3 V) detrimentally affects the battery performance. Here, to circumvent this issue, we propose a Li1.46Ni0.32Mn1.2O4-x (0

Suggested Citation

  • Yi Pei & Qing Chen & Meiyu Wang & Pengjun Zhang & Qingyong Ren & Jingkai Qin & Penghao Xiao & Li Song & Yu Chen & Wen Yin & Xin Tong & Liang Zhen & Peng Wang & Cheng-Yan Xu, 2022. "A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33927-0
    DOI: 10.1038/s41467-022-33927-0
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