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Thermal-healing of lattice defects for high-energy single-crystalline battery cathodes

Author

Listed:
  • Shaofeng Li

    (SLAC National Accelerator Laboratory
    Dalian University of Technology)

  • Guannan Qian

    (SLAC National Accelerator Laboratory
    Shanghai Jiao Tong University)

  • Xiaomei He

    (Purdue University)

  • Xiaojing Huang

    (Brookhaven National Laboratory)

  • Sang-Jun Lee

    (SLAC National Accelerator Laboratory)

  • Zhisen Jiang

    (SLAC National Accelerator Laboratory)

  • Yang Yang

    (Brookhaven National Laboratory)

  • Wei-Na Wang

    (Shanghai Jiao Tong University)

  • Dechao Meng

    (Shanghai Jiao Tong University)

  • Chang Yu

    (Dalian University of Technology)

  • Jun-Sik Lee

    (SLAC National Accelerator Laboratory)

  • Yong S. Chu

    (Brookhaven National Laboratory)

  • Zi-Feng Ma

    (Shanghai Jiao Tong University)

  • Piero Pianetta

    (SLAC National Accelerator Laboratory)

  • Jieshan Qiu

    (Dalian University of Technology)

  • Linsen Li

    (Shanghai Jiao Tong University
    Shanghai Jiao Tong University Sichuan Research Institute)

  • Kejie Zhao

    (Purdue University)

  • Yijin Liu

    (SLAC National Accelerator Laboratory)

Abstract

Single-crystalline nickel-rich cathodes are a rising candidate with great potential for high-energy lithium-ion batteries due to their superior structural and chemical robustness in comparison with polycrystalline counterparts. Within the single-crystalline cathode materials, the lattice strain and defects have significant impacts on the intercalation chemistry and, therefore, play a key role in determining the macroscopic electrochemical performance. Guided by our predictive theoretical model, we have systematically evaluated the effectiveness of regaining lost capacity by modulating the lattice deformation via an energy-efficient thermal treatment at different chemical states. We demonstrate that the lattice structure recoverability is highly dependent on both the cathode composition and the state of charge, providing clues to relieving the fatigued cathode crystal for sustainable lithium-ion batteries.

Suggested Citation

  • Shaofeng Li & Guannan Qian & Xiaomei He & Xiaojing Huang & Sang-Jun Lee & Zhisen Jiang & Yang Yang & Wei-Na Wang & Dechao Meng & Chang Yu & Jun-Sik Lee & Yong S. Chu & Zi-Feng Ma & Piero Pianetta & Ji, 2022. "Thermal-healing of lattice defects for high-energy single-crystalline battery cathodes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28325-5
    DOI: 10.1038/s41467-022-28325-5
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    References listed on IDEAS

    as
    1. Pengfei Yan & Jianming Zheng & Tianwu Chen & Langli Luo & Yuyuan Jiang & Kuan Wang & Manling Sui & Ji-Guang Zhang & Sulin Zhang & Chongmin Wang, 2018. "Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. A. Singer & M. Zhang & S. Hy & D. Cela & C. Fang & T. A. Wynn & B. Qiu & Y. Xia & Z. Liu & A. Ulvestad & N. Hua & J. Wingert & H. Liu & M. Sprung & A. V. Zozulya & E. Maxey & R. Harder & Y. S. Meng & , 2018. "Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging," Nature Energy, Nature, vol. 3(8), pages 641-647, August.
    3. Wangda Li & Evan M. Erickson & Arumugam Manthiram, 2020. "High-nickel layered oxide cathodes for lithium-based automotive batteries," Nature Energy, Nature, vol. 5(1), pages 26-34, January.
    4. Shaofeng Li & Zhisen Jiang & Jiaxiu Han & Zhengrui Xu & Chenxu Wang & Hai Huang & Chang Yu & Sang-Jun Lee & Piero Pianetta & Hendrik Ohldag & Jieshan Qiu & Jun-Sik Lee & Feng Lin & Kejie Zhao & Yijin , 2020. "Mutual modulation between surface chemistry and bulk microstructure within secondary particles of nickel-rich layered oxides," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
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    Cited by:

    1. Isaac Martens & Nikita Vostrov & Marta Mirolo & Steven J. Leake & Edoardo Zatterin & Xiaobo Zhu & Lianzhou Wang & Jakub Drnec & Marie-Ingrid Richard & Tobias U. Schulli, 2023. "Defects and nanostrain gradients control phase transition mechanisms in single crystal high-voltage lithium spinel," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Ho-Young Jang & Donggun Eum & Jiung Cho & Jun Lim & Yeji Lee & Jun-Hyuk Song & Hyeokjun Park & Byunghoon Kim & Do-Hoon Kim & Sung-Pyo Cho & Sugeun Jo & Jae Hoon Heo & Sunyoung Lee & Jongwoo Lim & Kisu, 2024. "Structurally robust lithium-rich layered oxides for high-energy and long-lasting cathodes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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