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Analysis of Hybrid Hetero-Homo Junction Lead-Free Perovskite Solar Cells by SCAPS Simulator

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  • Marwa. S. Salem

    (Department of Computer Engineering, Computer Science and Engineering College, University of Ha’il, Ha’il 55211, Saudi Arabia
    Department of Electrical Communication and Electronics Systems Engineering, Faculty of Engineering, Modern Science and Arts (MSA) University, Cairo 12566, Egypt)

  • Ahmed Shaker

    (Department of Engineering Physics and Mathematics, Faculty of Engineering, Ain Shams University, Cairo 11566, Egypt)

  • Abdelhalim Zekry

    (Department of Electronics and Communications, Faculty of Engineering, Ain Shams University, Cairo 11566, Egypt)

  • Mohamed Abouelatta

    (Department of Electronics and Communications, Faculty of Engineering, Ain Shams University, Cairo 11566, Egypt)

  • Adwan Alanazi

    (Department of Computer Science and Information, Computer Science and Engineering College, University of Ha’il, Ha’il 55211, Saudi Arabia)

  • Mohammad T. Alshammari

    (Department of Computer Science and Information, Computer Science and Engineering College, University of Ha’il, Ha’il 55211, Saudi Arabia)

  • Christian Gontand

    (INSA–Lyon, Villeurbanne, 69621 Lyon, France
    IEP, Université Euro-Mé Diterrané enne de Fès, INSA-Fès, Fès 30120, Morocco)

Abstract

In this work, we report on the effect of substituting the active intrinsic i-layer on a conventional pin structure of lead-free perovskite solar cell (PSC) by a homo p-n junction, keeping the thickness of the active layer constant. It is expected that when the active i-layer is substituted by a p-n homo junction, one can increase the collection efficiency of the photo-generated electrons and holes due to the built-in electric field of the homo junction. The impact of the technological and physical device parameters on the performance parameters of the solar cell have been worked out. It was found that p-side thickness must be wider than the n-side, while its acceptor concentration should be slightly lower than the donor concentration of the n-side to achieve maximum efficiency. In addition, different absorber types, namely, i-absorber, n-absorber and p-absorber, are compared to the proposed pn-absorber, showing a performance-boosting effect when using the latter. Moreover, the proposed structure is made without a hole transport layer (HTL) to avoid the organic issues of the HTL materials. The back metal work function, bulk trap density and ETL material are optimized for best performance of the HTL-free structure, giving J sc = 26.48, V oc = 0.948 V, FF = 77.20 and PCE = 19.37% for AM1.5 solar spectra. Such results highlight the prospective of the proposed structure and emphasize the importance of using HTL-free solar cells without deteriorating the efficiency. The solar cell is investigated by using SCAPS simulator.

Suggested Citation

  • Marwa. S. Salem & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Adwan Alanazi & Mohammad T. Alshammari & Christian Gontand, 2021. "Analysis of Hybrid Hetero-Homo Junction Lead-Free Perovskite Solar Cells by SCAPS Simulator," Energies, MDPI, vol. 14(18), pages 1-22, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:18:p:5741-:d:633891
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    References listed on IDEAS

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    1. Julian Burschka & Norman Pellet & Soo-Jin Moon & Robin Humphry-Baker & Peng Gao & Mohammad K. Nazeeruddin & Michael Grätzel, 2013. "Sequential deposition as a route to high-performance perovskite-sensitized solar cells," Nature, Nature, vol. 499(7458), pages 316-319, July.
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    3. Xiaopeng Zheng & Bo Chen & Jun Dai & Yanjun Fang & Yang Bai & Yuze Lin & Haotong Wei & Xiao Cheng Zeng & Jinsong Huang, 2017. "Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations," Nature Energy, Nature, vol. 2(7), pages 1-9, July.
    4. Syed Afaq Ali Shah & Muhammad Hassan Sayyad & Karim Khan & Kai Guo & Fei Shen & Jinghua Sun & Ayesha Khan Tareen & Yubin Gong & Zhongyi Guo, 2020. "Progress towards High-Efficiency and Stable Tin-Based Perovskite Solar Cells," Energies, MDPI, vol. 13(19), pages 1-42, September.
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    Cited by:

    1. Mostafa M. Salah & Abdelhalim Zekry & Ahmed Shaker & Mohamed Abouelatta & Mohamed Mousa & Ahmed Saeed, 2022. "Investigation of Electron Transport Material-Free Perovskite/CIGS Tandem Solar Cell," Energies, MDPI, vol. 15(17), pages 1-16, August.
    2. Marwa S. Salem & Abdelhalim Zekry & Ahmed Shaker & Mohamed Abouelatta & Tariq S. Almurayziq & Mohammad T. Alshammari & Mohamed M. El-Banna, 2022. "Performance Improvement of npn Solar Cell Microstructure by TCAD Simulation: Role of Emitter Contact and ARC," Energies, MDPI, vol. 15(19), pages 1-12, September.
    3. Tarek I. Alanazi & Omer I. Eid, 2023. "Simulation of Triple-Cation Perovskite Solar Cells: Key Design Factors for Efficiency Promotion," Energies, MDPI, vol. 16(6), pages 1-14, March.
    4. Kumar, Amarjeet & Ranjan, Rahutosh & Mishra, Vijay Kumar & Srivastava, Neelabh & Tiwari, Rajanish N. & Singh, Laxman & Sharma, Arvind Kumar, 2024. "Boosting the efficiency up to 33 % for chalcogenide tin mono-sulfide-based heterojunction solar cell using SCAPS simulation technique," Renewable Energy, Elsevier, vol. 226(C).
    5. Omar M. Saif & Yasmine Elogail & Tarek M. Abdolkader & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Marwa S. Salem & Mostafa Fedawy, 2023. "Comprehensive Review on Thin Film Homojunction Solar Cells: Technologies, Progress and Challenges," Energies, MDPI, vol. 16(11), pages 1-23, May.

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