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A Ni4O4-cubane-squarate coordination framework for molecular recognition

Author

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  • Qingqing Yan

    (University of Science and Technology of China)

  • Shuyi An

    (University of Science and Technology of China)

  • Liang Yu

    (Shenzhen Polytechnic University)

  • Shenfang Li

    (Shenzhen Polytechnic University)

  • Xiaonan Wu

    (China Academy of Engineering Physics (CAEP))

  • Siqi Dong

    (China Academy of Engineering Physics (CAEP))

  • Shunshun Xiong

    (China Academy of Engineering Physics (CAEP))

  • Hao Wang

    (Shenzhen Polytechnic University)

  • Sujing Wang

    (University of Science and Technology of China)

  • Jiangfeng Du

    (University of Science and Technology of China)

Abstract

Molecular recognition is a fundamental function of natural systems that ensures biological activity. This is achieved through the sieving effect, host-guest interactions, or both in biological environments. Recent advancements in multifunctional proteins reveal a new dimension of functional organization that goes beyond single-function molecular recognition, emphasizing the need for artificial multifunctional materials in industrial applications. Herein, we have designed a porous Ni4O4-cubane squarate coordination polymer as an artificial molecular recognition host, drawing inspiration from the structural and functional features of natural enzymes. A comprehensive assessment of the material’s ability to distinguish target species under different operating conditions was carried out. The results confirm its sieving function through hexane isomers separation, host-guest interaction function via xenon/krypton separation, and dual presence of sieving and interaction through carbon dioxide/nitrogen separation. Additionally, the material demonstrates good stability and feasibility for large-scale production, indicating its practical potential. Our findings provide a bio-inspired multifunctional recognition material for chemical separations as proof-of-concept while offering solutions to advance artificial multifunctional materials adaptable to other applications beyond chemical separations.

Suggested Citation

  • Qingqing Yan & Shuyi An & Liang Yu & Shenfang Li & Xiaonan Wu & Siqi Dong & Shunshun Xiong & Hao Wang & Sujing Wang & Jiangfeng Du, 2024. "A Ni4O4-cubane-squarate coordination framework for molecular recognition," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54348-1
    DOI: 10.1038/s41467-024-54348-1
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    References listed on IDEAS

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