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Membrane-Assisted Removal of Hydrogen and Nitrogen from Synthetic Natural Gas for Energy-Efficient Liquefaction

Author

Listed:
  • Muhammad Abdul Qyyum

    (School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Korea
    These authors contributed equally.)

  • Yus Donald Chaniago

    (School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Korea
    These authors contributed equally.)

  • Wahid Ali

    (Department of Chemical Engineering and Technology, Jazan University, Jazan 45971, Saudi Arabia)

  • Hammad Saulat

    (State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China)

  • Moonyong Lee

    (School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Korea)

Abstract

Synthetic natural gas (SNG) production from coal is one of the well-matured options to make clean utilization of coal a reality. For the ease of transportation and supply, liquefaction of SNG is highly desirable. In the liquefaction of SNG, efficient removal of low boiling point impurities such as hydrogen (H 2 ) and nitrogen (N 2 ) is highly desirable to lower the power of the liquefaction process. Among several separation processes, membrane-based separation exhibits the potential for the separation of low boiling point impurities at low power consumption as compared to the existing separation processes. In this study, the membrane unit was used to simulate the membrane module by using Aspen HYSYS V10 (Version 10, AspenTech, Bedford, MA, United States). The two-stage and two-step system designs of the N 2 -selective membrane are utilized for SNG separation. The two-stage membrane process feasibly recovers methane (CH 4 ) at more than 95% (by mol) recovery with a H 2 composition of ≤0.05% by mol, but requires a larger membrane area than a two-stage system. While maintaining the minimum internal temperature approach value of 3 °C inside a cryogenic heat exchanger, the optimization of the SNG liquefaction process shows a large reduction in power consumption. Membrane-assisted removal of H 2 and N 2 for the liquefaction process exhibits the beneficial removal of H 2 before liquefaction by achieving low net specific power at 0.4010 kW·h/kg· CH 4 .

Suggested Citation

  • Muhammad Abdul Qyyum & Yus Donald Chaniago & Wahid Ali & Hammad Saulat & Moonyong Lee, 2020. "Membrane-Assisted Removal of Hydrogen and Nitrogen from Synthetic Natural Gas for Energy-Efficient Liquefaction," Energies, MDPI, vol. 13(19), pages 1-18, September.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:19:p:5023-:d:418638
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    References listed on IDEAS

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    1. Khan, Mohd Shariq & Lee, Moonyong, 2013. "Design optimization of single mixed refrigerant natural gas liquefaction process using the particle swarm paradigm with nonlinear constraints," Energy, Elsevier, vol. 49(C), pages 146-155.
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    Cited by:

    1. Yasunari Shinoda & Masakazu Takeuchi & Hikaru Mizukami & Norikazu Dezawa & Yasuhiro Komo & Takuya Harada & Hiroki Takasu & Yukitaka Kato, 2021. "Characterization of Pd 60 Cu 40 Composite Membrane Prepared by a Reverse Build-Up Method for Hydrogen Purification," Energies, MDPI, vol. 14(24), pages 1-16, December.
    2. Evgeny Solomin & Shanmuga Priya Selvanathan & Sudhakar Kumarasamy & Anton Kovalyov & Ramyashree Maddappa Srinivasa, 2021. "The Comparison of Solar-Powered Hydrogen Closed-Cycle System Capacities for Selected Locations," Energies, MDPI, vol. 14(9), pages 1-18, May.
    3. Hafiz Muhammad Uzair Ayub & Sang Jin Park & Michael Binns, 2020. "Biomass to Syngas: Modified Non-Stoichiometric Thermodynamic Models for the Downdraft Biomass Gasification," Energies, MDPI, vol. 13(21), pages 1-17, October.
    4. Qyyum, Muhammad Abdul & Naquash, Ahmad & Sial, Noman Raza & Lee, Moonyong, 2023. "CO2 precooled dual phase expander refrigeration cycles for offshore and small-scale LNG production: Energy, exergy, and economic evaluation," Energy, Elsevier, vol. 262(PA).

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