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An acid-tolerant metal-organic framework for industrial CO2 electrolysis using a proton exchange membrane

Author

Listed:
  • Kang Yang

    (Nanjing University of Science and Technology)

  • Ming Li

    (Nanjing University of Science and Technology)

  • Tianqi Gao

    (Nanjing University of Science and Technology)

  • Guoliang Xu

    (Nanjing University of Science and Technology)

  • Di Li

    (Nanjing University of Science and Technology)

  • Yao Zheng

    (The University of Adelaide)

  • Qiang Li

    (Nanjing University of Science and Technology)

  • Jingjing Duan

    (Nanjing University of Science and Technology)

Abstract

Industrial CO2 electrolysis via electrochemical CO2 reduction has achieved progress in alkaline solutions, while the same reaction in acidic solution remains challenging because of severe hydrogen evolution side reactions, acid corrosion, and low target product selectivity. Herein, an industrial acidic CO2 electrolysis to pure HCOOH system is realized in a proton-exchange-membrane electrolyzer using an acid-tolerant Bi-based metal-organic framework guided by a Pourbaix diagram. Significantly, the Faradaic efficiency of HCOOH synthesis reaches 95.10% at a large current density of 400 mA/cm2 with a high CO2 single-pass conversion efficiency of 64.91%. Moreover, the proton-exchange-membrane device also achieves an industrial-level current density of 250 mA/cm2 under a relatively low voltage of 3.5 V for up to 100 h with a Faradaic efficiency of 93.5% for HCOOH production, which corresponds to an energy consumption of 200.65 kWh/kmol, production rate of 12.1 mmol/m2/s, and an energy conversion efficiency of 38.2%. These results will greatly aid the contemporary research moving toward commercial implementation and success of CO2 electrolysis technology.

Suggested Citation

  • Kang Yang & Ming Li & Tianqi Gao & Guoliang Xu & Di Li & Yao Zheng & Qiang Li & Jingjing Duan, 2024. "An acid-tolerant metal-organic framework for industrial CO2 electrolysis using a proton exchange membrane," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51475-7
    DOI: 10.1038/s41467-024-51475-7
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