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Promoting water dissociation for efficient solar driven CO2 electroreduction via improving hydroxyl adsorption

Author

Listed:
  • Xin Chen

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Junxiang Chen

    (Chinese Academy of Sciences)

  • Huayu Chen

    (China Jiliang University)

  • Qiqi Zhang

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Jiaxuan Li

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Jiwei Cui

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Yanhui Sun

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Defa Wang

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

  • Jinhua Ye

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University
    National Institute for Materials Science (NIMS))

  • Lequan Liu

    (Key Lab of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin University)

Abstract

Exploring efficient electrocatalysts with fundamental understanding of the reaction mechanism is imperative in CO2 electroreduction. However, the impact of sluggish water dissociation as proton source and the surface species in reaction are still unclear. Herein, we report a strategy of promoting protonation in CO2 electroreduction by implementing oxygen vacancy engineering on Bi2O2CO3 over which high Faradaic efficiency of formate (above 90%) and large partial current density (162 mA cm−2) are achieved. Systematic study reveals that the production rate of formate is mainly hampered by water dissociation, while the introduction of oxygen vacancy accelerates water dissociation kinetics by strengthening hydroxyl adsorption and reduces the energetic span of CO2 electroreduction. Moreover, CO3* involved in formate formation as the key surface species is clearly identified by electron spin resonance measurements and designed in situ Raman spectroscopy study combined with isotopic labelling. Coupled with photovoltaic device, the solar to formate energy conversion efficiency reaches as high as 13.3%.

Suggested Citation

  • Xin Chen & Junxiang Chen & Huayu Chen & Qiqi Zhang & Jiaxuan Li & Jiwei Cui & Yanhui Sun & Defa Wang & Jinhua Ye & Lequan Liu, 2023. "Promoting water dissociation for efficient solar driven CO2 electroreduction via improving hydroxyl adsorption," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36263-z
    DOI: 10.1038/s41467-023-36263-z
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    2. Li, Zhiyu & Li, Jian & Yu, Tianxiao & Jia, Xiaopeng & Zhao, Juan & Yan, Beibei & Chen, Guanyi, 2024. "Chemical looping gasification of high-moisture content biomass: The interactions between H2O and oxygen carrier," Applied Energy, Elsevier, vol. 368(C).

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