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Capture of single Ag atoms through high-temperature-induced crystal plane reconstruction

Author

Listed:
  • Jiaxin Li

    (Kunming University of Science and Technology)

  • Kai Li

    (Kunming University of Science and Technology
    National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries)

  • Zhao Li

    (Kunming University of Science and Technology)

  • Chunxue Wang

    (Kunming University of Science and Technology)

  • Yifei Liang

    (Kunming University of Science and Technology)

  • Yatong Pang

    (Kunming University of Science and Technology)

  • Jinzhu Ma

    (Chinese Academy of Sciences
    Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Fei Wang

    (Kunming University of Science and Technology
    National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries)

  • Ping Ning

    (Kunming University of Science and Technology
    National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries)

  • Hong He

    (Chinese Academy of Sciences
    Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

The “terminal hydroxyl group anchoring mechanism” has been studied on metal oxides (Al2O3, CeO2) as well as a variety of noble and transition metals (Ag, Pt, Pd, Cu, Ni, Fe, Mn, and Co) in a number of generalized studies, but there is still a gap in how to regulate the content of terminal hydroxyl groups to influence the dispersion of the active species and thus to achieve optimal catalytic performance. Herein, we utilized AlOOH as a precursor for γ-Al2O3 and induced the transformation of the exposed crystal face of γ-Al2O3 from (110) to (100) by controlling the calcination temperature to generate more terminal hydroxyl groups to anchor Ag species. Experimental results combined with AIMD and DFT show that temperature can drive the atomic rearrangement on the (110) crystal face, thereby forming a structure similar to the atomic arrangement of the (100) crystal face. This resulted in the formation of more terminal hydroxyl groups during the high-temperature calcination of the support (Al-900), which can capture Ag species to form single-atom dispersions, and ultimately develop a stable and efficient single-atom Ag-based catalyst.

Suggested Citation

  • Jiaxin Li & Kai Li & Zhao Li & Chunxue Wang & Yifei Liang & Yatong Pang & Jinzhu Ma & Fei Wang & Ping Ning & Hong He, 2024. "Capture of single Ag atoms through high-temperature-induced crystal plane reconstruction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47836-x
    DOI: 10.1038/s41467-024-47836-x
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    References listed on IDEAS

    as
    1. Fei Wang & Jinzhu Ma & Shaohui Xin & Qiang Wang & Jun Xu & Changbin Zhang & Hong He & Xiao Cheng Zeng, 2020. "Resolving the puzzle of single-atom silver dispersion on nanosized γ-Al2O3 surface for high catalytic performance," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Kai Ling Zhou & Zelin Wang & Chang Bao Han & Xiaoxing Ke & Changhao Wang & Yuhong Jin & Qianqian Zhang & Jingbing Liu & Hao Wang & Hui Yan, 2021. "Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    3. Yiwei Liu & Xi Wu & Zhi Li & Jian Zhang & Shu-Xia Liu & Shoujie Liu & Lin Gu & Li Rong Zheng & Jia Li & Dingsheng Wang & Yadong Li, 2021. "Fabricating polyoxometalates-stabilized single-atom site catalysts in confined space with enhanced activity for alkynes diboration," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. John Meurig Thomas, 2015. "Tens of thousands of atoms replaced by one," Nature, Nature, vol. 525(7569), pages 325-326, September.
    5. Xun Wang & Jing Zhuang & Qing Peng & Yadong Li, 2005. "A general strategy for nanocrystal synthesis," Nature, Nature, vol. 437(7055), pages 121-124, September.
    6. Rui Lang & Wei Xi & Jin-Cheng Liu & Yi-Tao Cui & Tianbo Li & Adam Fraser Lee & Fang Chen & Yang Chen & Lei Li & Lin Li & Jian Lin & Shu Miao & Xiaoyan Liu & Ai-Qin Wang & Xiaodong Wang & Jun Luo & Bot, 2019. "Non defect-stabilized thermally stable single-atom catalyst," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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