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Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2

Author

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  • Sai Zhang

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University)

  • Zheng-Qing Huang

    (Institute of Industrial Catalysis, School of Chemical Engineering and Technology, Xi’an Jiaotong University)

  • Yuanyuan Ma

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University
    MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University)

  • Wei Gao

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University)

  • Jing Li

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University)

  • Fangxian Cao

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University)

  • Lin Li

    (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Chun-Ran Chang

    (Institute of Industrial Catalysis, School of Chemical Engineering and Technology, Xi’an Jiaotong University)

  • Yongquan Qu

    (Center for Applied Chemical Research, Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University
    MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University)

Abstract

Identification on catalytic sites of heterogeneous catalysts at atomic level is important to understand catalytic mechanism. Surface engineering on defects of metal oxides can construct new active sites and regulate catalytic activity and selectivity. Here we outline the strategy by controlling surface defects of nanoceria to create the solid frustrated Lewis pair (FLP) metal oxide for efficient hydrogenation of alkenes and alkynes. Porous nanorods of ceria (PN-CeO2) with a high concentration of surface defects construct new Lewis acidic sites by two adjacent surface Ce3+. The neighbouring surface lattice oxygen as Lewis base and constructed Lewis acid create solid FLP site due to the rigid lattice of ceria, which can easily dissociate H–H bond with low activation energy of 0.17 eV.

Suggested Citation

  • Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15266
    DOI: 10.1038/ncomms15266
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    Cited by:

    1. De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Sai Zhang & Yuxuan Liu & Mingkai Zhang & Yuanyuan Ma & Jun Hu & Yongquan Qu, 2022. "Sustainable production of hydrogen with high purity from methanol and water at low temperatures," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Shulin Liu & Minghua Dong & Yuxuan Wu & Sen Luan & Yu Xin & Juan Du & Shaopeng Li & Huizhen Liu & Buxing Han, 2022. "Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Hao Yan & Bowen Liu & Xin Zhou & Fanyu Meng & Mingyue Zhao & Yue Pan & Jie Li & Yining Wu & Hui Zhao & Yibin Liu & Xiaobo Chen & Lina Li & Xiang Feng & De Chen & Honghong Shan & Chaohe Yang & Ning Yan, 2023. "Enhancing polyol/sugar cascade oxidation to formic acid with defect rich MnO2 catalysts," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Xin Tang & Chuqiao Song & Haibo Li & Wenyu Liu & Xinyu Hu & Qiaoli Chen & Hanfeng Lu & Siyu Yao & Xiao-nian Li & Lili Lin, 2024. "Thermally stable Ni foam-supported inverse CeAlOx/Ni ensemble as an active structured catalyst for CO2 hydrogenation to methane," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Zelun Zhao & Guang Gao & Yongjie Xi & Jia Wang & Peng Sun & Qi Liu & Chengyang Li & Zhiwei Huang & Fuwei Li, 2024. "Inverse ceria-nickel catalyst for enhanced C–O bond hydrogenolysis of biomass and polyether," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Ziyu Chen & Yutao Ye & Xiaoyi Feng & Yan Wang & Xiaowei Han & Yu Zhu & Shiqun Wu & Senyao Wang & Wenda Yang & Lingzhi Wang & Jinlong Zhang, 2023. "High-density frustrated Lewis pairs based on Lamellar Nb2O5 for photocatalytic non-oxidative methane coupling," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Jie Yin & Jing Jin & Zhouyang Yin & Liu Zhu & Xin Du & Yong Peng & Pinxian Xi & Chun-Hua Yan & Shouheng Sun, 2023. "The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Shuang Xiang & Lin Dong & Zhi-Qiang Wang & Xue Han & Luke L. Daemen & Jiong Li & Yongqiang Cheng & Yong Guo & Xiaohui Liu & Yongfeng Hu & Anibal J. Ramirez-Cuesta & Sihai Yang & Xue-Qing Gong & Yanqin, 2022. "A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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