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Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction

Author

Listed:
  • Shulin Liu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Minghua Dong

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yuxuan Wu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Sen Luan

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yu Xin

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Juan Du

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Shaopeng Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Huizhen Liu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Buxing Han

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

Designing heterogeneous solid surface frustrated Lewis pair (ssFLP) catalyst for hydrogenation is a new challenge in catalysis and no research has been reported on the construction of ssFLP on boehmite (AlOOH) surfaces up to now as far as we know. Herein, AlOOH with a layer structure is prepared and it is found that the Lewis basic OHv site (one H removed from OH) and an adjacent Lewis acidic unsaturated Al site (Al3+unsatur.) proximal to a surface OHv (OH vacancy) on AlOOH layers could form the ssFLP. The layered structure of AlOOH and its abundant OH defects over the surface result in a high concentration of OHv/Al3+unsatur. FLPs, which are conducive to highly efficient hydrogen activation for hydrogenation of olefins and alkynes with low H-H bond dissociates activation energy of 0.16 eV under mild conditions (T = 80°C and P(H2) = 2.0 MPa). This work develops a new kind of hydrogenation catalyst and provides a new perspective for creating solid surface FLP.

Suggested Citation

  • Shulin Liu & Minghua Dong & Yuxuan Wu & Sen Luan & Yu Xin & Juan Du & Shaopeng Li & Huizhen Liu & Buxing Han, 2022. "Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29970-6
    DOI: 10.1038/s41467-022-29970-6
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    References listed on IDEAS

    as
    1. Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    2. Zhicheng Luo & Renfeng Nie & Vy T. Nguyen & Abhranil Biswas & Ranjan K. Behera & Xun Wu & Takeshi Kobayashi & Aaron Sadow & Bin Wang & Wenyu Huang & Long Qi, 2020. "Transition metal-like carbocatalyst," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Ana Primo & Florentina Neatu & Mihaela Florea & Vasile Parvulescu & Hermenegildo Garcia, 2014. "Graphenes in the absence of metals as carbocatalysts for selective acetylene hydrogenation and alkene hydrogenation," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
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    Cited by:

    1. Tianjiao Wang & Yu Xin & Bingfeng Chen & Bin Zhang & Sen Luan & Minghua Dong & Yuxuan Wu & Xiaomeng Cheng & Ye Liu & Huizhen Liu & Buxing Han, 2024. "Selective hydrodeoxygenation of α, β-unsaturated carbonyl compounds to alkenes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Rishi Verma & Charvi Singhvi & Amrit Venkatesh & Vivek Polshettiwar, 2024. "Defects tune the acidic strength of amorphous aluminosilicates," Nature Communications, Nature, vol. 15(1), pages 1-16, December.

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