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Pulse potential mediated selectivity for the electrocatalytic oxidation of glycerol to glyceric acid

Author

Listed:
  • Wei Chen

    (Hunan University
    Yangzhou University)

  • Liang Zhang

    (Hunan University
    Wenzhou University)

  • Leitao Xu

    (Hunan University)

  • Yuanqing He

    (Hunan University
    Yangzhou University)

  • Huan Pang

    (Yangzhou University)

  • Shuangyin Wang

    (Hunan University)

  • Yuqin Zou

    (Hunan University)

Abstract

Preventing the deactivation of noble metal-based catalysts due to self-oxidation and poisonous adsorption is a significant challenge in organic electro-oxidation. In this study, we employ a pulsed potential electrolysis strategy for the selective electrocatalytic oxidation of glycerol to glyceric acid over a Pt-based catalyst. In situ Fourier-transform infrared spectroscopy, quasi-in situ X-ray photoelectron spectroscopy, and finite element simulations reveal that the pulsed potential could tailor the catalyst’s oxidation and surface micro-environment. This prevents the overaccumulation of poisoning intermediate species and frees up active sites for the re-adsorption of OH adsorbate and glycerol. The pulsed potential electrolysis strategy results in a higher glyceric acid selectivity (81.8%) than constant-potential electrocatalysis with 0.7 VRHE (37.8%). This work offers an efficient strategy to mitigate the deactivation of noble metal-based electrocatalysts.

Suggested Citation

  • Wei Chen & Liang Zhang & Leitao Xu & Yuanqing He & Huan Pang & Shuangyin Wang & Yuqin Zou, 2024. "Pulse potential mediated selectivity for the electrocatalytic oxidation of glycerol to glyceric acid," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46752-4
    DOI: 10.1038/s41467-024-46752-4
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    References listed on IDEAS

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    4. Zhenhua Li & Yifan Yan & Si-Min Xu & Hua Zhou & Ming Xu & Lina Ma & Mingfei Shao & Xianggui Kong & Bin Wang & Lirong Zheng & Haohong Duan, 2022. "Alcohols electrooxidation coupled with H2 production at high current densities promoted by a cooperative catalyst," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
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