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Enhanced hydrogen production enabled by pulsed potential coupled sulfite electrooxidation water electrolysis system

Author

Listed:
  • Zhang, Xuewei
  • Zhou, Wei
  • Huang, Yuming
  • Ding, Yani
  • Li, Junfeng
  • Xie, Liang
  • Yu, Yang
  • Chen, Jiaxiang
  • Sun, Miaoting
  • Meng, Xiaoxiao

Abstract

Water electrolysis (WE) from renewable energy sources is broadly acknowledged as a critical future route for hydrogen production. Reducing energy consumption and enhancing hydrogen production rates are both important directions for future WE technology. In this work, pulsed potential coupled anodic sulfite (SO32−) electrooxidation water electrolysis (PSWE) system was proposed, enabling the production of hydrogen at low cell voltages as well as enhanced rates. The onset potential for the electrooxidation of sulfite to sulfate (SO42−) is as low as 0.6 V vs. RHE. Under pulsed parameter of 0.75 V vs. RHE and frequency of 0.5 Hz, the hydrogen production rate increased by 321 % compared to constant potential of 0.75 V vs. RHE. Pulsed potential increased the local concentration of SO32− anions at the anode, thereby enhancing the accumulation of total charges on the electrode surface. In the H-cell, operating voltage as low as 1.15 V could drive current density of 10 mA cm−2, demonstrating excellent hydrogen production capability and lower electricity consumption. The proposed PSWE system offers a potential route for coupling WE with intermittent renewable energy sources, as well as with low-energy consumption.

Suggested Citation

  • Zhang, Xuewei & Zhou, Wei & Huang, Yuming & Ding, Yani & Li, Junfeng & Xie, Liang & Yu, Yang & Chen, Jiaxiang & Sun, Miaoting & Meng, Xiaoxiao, 2024. "Enhanced hydrogen production enabled by pulsed potential coupled sulfite electrooxidation water electrolysis system," Renewable Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:renene:v:227:y:2024:i:c:s0960148124005299
    DOI: 10.1016/j.renene.2024.120464
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    References listed on IDEAS

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    1. Rosa M. Arán-Ais & Fabian Scholten & Sebastian Kunze & Rubén Rizo & Beatriz Roldan Cuenya, 2020. "The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction," Nature Energy, Nature, vol. 5(4), pages 317-325, April.
    2. Yanmei Huang & Caihong He & Chuanqi Cheng & Shuhe Han & Meng He & Yuting Wang & Nannan Meng & Bin Zhang & Qipeng Lu & Yifu Yu, 2023. "Pulsed electroreduction of low-concentration nitrate to ammonia," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Huang, Yuming & Zhou, Wei & Xie, Liang & Li, Jiayi & He, Yong & Chen, Shuai & Meng, Xiaoxiao & Gao, Jihui & Qin, Yukun, 2022. "Edge and defect sites in porous activated coke enable highly efficient carbon-assisted water electrolysis for energy-saving hydrogen production," Renewable Energy, Elsevier, vol. 195(C), pages 283-292.
    4. Wei-Kean Chong & Boon-Junn Ng & Yong Jieh Lee & Lling-Lling Tan & Lutfi Kurnianditia Putri & Jingxiang Low & Abdul Rahman Mohamed & Siang-Piao Chai, 2023. "Self-activated superhydrophilic green ZnIn2S4 realizing solar-driven overall water splitting: close-to-unity stability for a full daytime," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Zhenhua Li & Yifan Yan & Si-Min Xu & Hua Zhou & Ming Xu & Lina Ma & Mingfei Shao & Xianggui Kong & Bin Wang & Lirong Zheng & Haohong Duan, 2022. "Alcohols electrooxidation coupled with H2 production at high current densities promoted by a cooperative catalyst," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    6. Jianxiao Wang & Liudong Chen & Zhenfei Tan & Ershun Du & Nian Liu & Jing Ma & Mingyang Sun & Canbing Li & Jie Song & Xi Lu & Chin-Woo Tan & Guannan He, 2023. "Inherent spatiotemporal uncertainty of renewable power in China," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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