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Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid

Author

Listed:
  • Zhe An

    (Beijing University of Chemical Technology)

  • Zilong Zhang

    (Beijing University of Chemical Technology)

  • Zeyu Huang

    (Beijing University of Chemical Technology)

  • Hongbo Han

    (Beijing University of Chemical Technology)

  • Binbin Song

    (Beijing University of Chemical Technology)

  • Jian Zhang

    (Beijing University of Chemical Technology)

  • Qi Ping

    (Beijing University of Chemical Technology)

  • Yanru Zhu

    (Beijing University of Chemical Technology)

  • Hongyan Song

    (Beijing University of Chemical Technology)

  • Bin Wang

    (Sinopec Group)

  • Lirong Zheng

    (Chinese Academy of Sciences)

  • Jing He

    (Beijing University of Chemical Technology)

Abstract

The selective oxidation of glycerol to glyceric acid, an important value-added reaction from polyols, is a typical cascade catalytic process. It is still of great challenge to simultaneously achieve high glycerol activity and glyceric acid selectivity, suffering from either deep oxidation and C-C cleavage or poor oxidation efficiency from glyceraldehyde to glyceric acid. Herein, this work, inspired by nature, proposes a cascade synergistic catalysis strategy by atomic and low-coordinated cluster Pt on well-defined Cu-CuZrOx, which involves enhanced C-H activation on atomic Pt1 and O-H activation on cluster Ptn in the oxidation of glycerol to glyceraldehyde, and cluster Ptn for C=O activation followed by O-H insertion and atomic Pt1 for C-H activation in the tandem oxidation of glyceraldehyde to glyceric acid. The enhanced C-H activation in the cascade process by atomic Pt1 is revealed to be essential for the high glycerol activity (90.0±0.1%) and the glyceric acid selectivity (80.2±0.2%).

Suggested Citation

  • Zhe An & Zilong Zhang & Zeyu Huang & Hongbo Han & Binbin Song & Jian Zhang & Qi Ping & Yanru Zhu & Hongyan Song & Bin Wang & Lirong Zheng & Jing He, 2022. "Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33038-w
    DOI: 10.1038/s41467-022-33038-w
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    References listed on IDEAS

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    1. Dong Liu & Jin-Cheng Liu & Weizheng Cai & Jun Ma & Hong Bin Yang & Hai Xiao & Jun Li & Yujie Xiong & Yanqiang Huang & Bin Liu, 2019. "Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Xi Zhang & Guoqing Cui & Haisong Feng & Lifang Chen & Hui Wang & Bin Wang & Xin Zhang & Lirong Zheng & Song Hong & Min Wei, 2019. "Platinum–copper single atom alloy catalysts with high performance towards glycerol hydrogenolysis," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
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    2. Yuan Lu & Byoung Guan Lee & Cheng Lin & Tae-Kyung Liu & Zhipeng Wang & Jiaming Miao & Sang Ho Oh & Ki Chul Kim & Kan Zhang & Jong Hyeok Park, 2024. "Solar-driven highly selective conversion of glycerol to dihydroxyacetone using surface atom engineered BiVO4 photoanodes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Jingjing Cao & Huaxing Liang & Jie Yang & Zhiyang Zhu & Jin Deng & Xiaodong Li & Menachem Elimelech & Xinglin Lu, 2024. "Depolymerization mechanisms and closed-loop assessment in polyester waste recycling," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Wei Chen & Liang Zhang & Leitao Xu & Yuanqing He & Huan Pang & Shuangyin Wang & Yuqin Zou, 2024. "Pulse potential mediated selectivity for the electrocatalytic oxidation of glycerol to glyceric acid," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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