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Challenging thermodynamics: combining immiscible elements in a single-phase nano-ceramic

Author

Listed:
  • Shuo Liu

    (University at Buffalo, The State University of New York)

  • Chaochao Dun

    (Lawrence Berkeley National Laboratory)

  • Qike Jiang

    (Westlake University)

  • Zhengxi Xuan

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York)

  • Feipeng Yang

    (Lawrence Berkeley National Laboratory)

  • Jinghua Guo

    (Lawrence Berkeley National Laboratory)

  • Jeffrey J. Urban

    (Lawrence Berkeley National Laboratory)

  • Mark T. Swihart

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York)

Abstract

The Hume-Rothery rules governing solid-state miscibility limit the compositional space for new inorganic material discovery. Here, we report a non-equilibrium, one-step, and scalable flame synthesis method to overcome thermodynamic limits and incorporate immiscible elements into single phase ceramic nanoshells. Starting from prototype examples including (NiMg)O, (NiAl)Ox, and (NiZr)Ox, we then extend this method to a broad range of Ni-containing ceramic solid solutions, and finally to general binary combinations of elements. Furthermore, we report an “encapsulated exsolution” phenomenon observed upon reducing the metastable porous (Ni0.07Al0.93)Ox to create ultra-stable Ni nanoparticles embedded within the walls of porous Al2O3 nanoshells. This nanoconfined structure demonstrated high sintering resistance during 640 h of catalysis of CO2 reforming of methane, maintaining constant 96% CH4 and CO2 conversion at 800 °C and dramatically outperforming conventional catalysts. Our findings could greatly expand opportunities to develop novel inorganic energy, structural, and functional materials.

Suggested Citation

  • Shuo Liu & Chaochao Dun & Qike Jiang & Zhengxi Xuan & Feipeng Yang & Jinghua Guo & Jeffrey J. Urban & Mark T. Swihart, 2024. "Challenging thermodynamics: combining immiscible elements in a single-phase nano-ceramic," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45413-w
    DOI: 10.1038/s41467-024-45413-w
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    References listed on IDEAS

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    1. Shengtai Hou & Xuefeng Ma & Yuan Shu & Jiafeng Bao & Qiuyue Zhang & Mingshu Chen & Pengfei Zhang & Sheng Dai, 2021. "Self-regeneration of supported transition metals by a high entropy-driven principle," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Jun Peng & Felipe Kremer & Daniel Walter & Yiliang Wu & Yi Ji & Jin Xiang & Wenzhu Liu & The Duong & Heping Shen & Teng Lu & Frank Brink & Dingyong Zhong & Li Li & Olivier Lee Cheong Lem & Yun Liu & K, 2022. "Centimetre-scale perovskite solar cells with fill factors of more than 86 per cent," Nature, Nature, vol. 601(7894), pages 573-578, January.
    3. Dragos Neagu & Tae-Sik Oh & David N. Miller & Hervé Ménard & Syed M. Bukhari & Stephen R. Gamble & Raymond J. Gorte & John M. Vohs & John T.S. Irvine, 2015. "Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    4. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    5. Mohcin Akri & Shu Zhao & Xiaoyu Li & Ketao Zang & Adam F. Lee & Mark A. Isaacs & Wei Xi & Yuvaraj Gangarajula & Jun Luo & Yujing Ren & Yi-Tao Cui & Lei Li & Yang Su & Xiaoli Pan & Wu Wen & Yang Pan & , 2019. "Atomically dispersed nickel as coke-resistant active sites for methane dry reforming," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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    1. Shuo Liu & Chaochao Dun & Feipeng Yang & Kang-Lan Tung & Dominik Wierzbicki & Sanjit Ghose & Kaiwen Chen & Linfeng Chen & Richard Ciora & Mohd A. Khan & Zhengxi Xuan & Miao Yu & Jeffrey J. Urban & Mar, 2024. "A general flame aerosol route to kinetically stabilized metal-organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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