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Methane Dry Reforming Catalysts Based on Pr-Doped Ceria–Zirconia Synthesized in Supercritical Propanol

Author

Listed:
  • Marina Arapova

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Ekaterina Smal

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Yuliya Bespalko

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Konstantin Valeev

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Valeria Fedorova

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Amir Hassan

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia
    Novosibirsk State University, 630090 Novosibirsk, Russia)

  • Olga Bulavchenko

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Vladislav Sadykov

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Mikhail Simonov

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

Abstract

This paper is devoted to the study of active and stable nickel catalysts for methane dry reforming based on Pr-doped ceria–zirconia obtained via the solvothermal continuous method. Studies on the physicochemical and catalytic properties of the 5%Ni/Ce 0.75 Zr 0.25−x Pr x O 2 series have showed that Pr introduction leads to an increase in the amount of highly reactive oxygen in the oxide lattice. Praseodymium-based catalysts showed significantly higher reactant conversions. In addition to the nature of support, the method of nickel introduction was also studied; Ni was added both using impregnation and the one-pot procedure with mixed oxide preparation. The method of Ni addition was shown to have significant effect on the morphology of its particles and Ni-support interaction, and, respectively, on catalytic activity and coking stability. The 5%Ni/Ce 0.75 Zr 0.15 Pr 0.1 O 2 catalyst prepared by one-pot method showed stable operation in the MDR reaction for 30 h at CO 2 and CH 4 conversions of ~40% and an H 2 yield of ~18% (T = 700 °C, τ = 10 ms).

Suggested Citation

  • Marina Arapova & Ekaterina Smal & Yuliya Bespalko & Konstantin Valeev & Valeria Fedorova & Amir Hassan & Olga Bulavchenko & Vladislav Sadykov & Mikhail Simonov, 2023. "Methane Dry Reforming Catalysts Based on Pr-Doped Ceria–Zirconia Synthesized in Supercritical Propanol," Energies, MDPI, vol. 16(12), pages 1-17, June.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:12:p:4729-:d:1171743
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    References listed on IDEAS

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    1. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
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