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Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation

Author

Listed:
  • Pengcheng Ye

    (Zhejiang Normal University)

  • Keqing Fang

    (Zhejiang Normal University)

  • Haiyan Wang

    (Zhejiang Normal University)

  • Yahao Wang

    (Zhejiang Normal University)

  • Hao Huang

    (University of South-Eastern Norway)

  • Chenbin Mo

    (Zhejiang Normal University)

  • Jiqiang Ning

    (Fudan University)

  • Yong Hu

    (Zhejiang A&F University)

Abstract

Oxygen evolution reaction (OER) is critical to renewable energy conversion technologies, but the structure-activity relationships and underlying catalytic mechanisms in catalysts are not fully understood. We herein demonstrate a strategy to promote OER with simultaneously achieved lattice oxygen activation and enhanced local electric field by dual doping of cations and anions. Rough arrays of Fe and F co-doped CoO nanoneedles are constructed, and a low overpotential of 277 mV at 500 mA cm−2 is achieved. The dually doped Fe and F could cooperatively tailor the electronic properties of CoO, leading to improved metal-oxygen covalency and stimulated lattice oxygen activation. Particularly, Fe doping induces a synergetic effect of tip enhancement and proximity effect, which effectively concentrates OH− ions, optimizes reaction energy barrier and promotes O2 desorption. This work demonstrates a conceptual strategy to couple lattice oxygen and local electric field for effective electrocatalytic water oxidation.

Suggested Citation

  • Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45320-0
    DOI: 10.1038/s41467-024-45320-0
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