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Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution

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  • Shenlong Zhao

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology
    School of Materials Science and Engineering, Harbin Institute of Technology)

  • Yun Wang

    (Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University)

  • Juncai Dong

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Chun-Ting He

    (MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University)

  • Huajie Yin

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
    Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University)

  • Pengfei An

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Kun Zhao

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Xiaofei Zhang

    (School of Materials Science and Engineering, Harbin Institute of Technology)

  • Chao Gao

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Lijuan Zhang

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology)

  • Jiawei Lv

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Jinxin Wang

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology)

  • Jianqi Zhang

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Abdul Muqsit Khattak

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Niaz Ali Khan

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Zhixiang Wei

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Jing Zhang

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Shaoqin Liu

    (State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology
    School of Materials Science and Engineering, Harbin Institute of Technology)

  • Huijun Zhao

    (Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University)

  • Zhiyong Tang

    (CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

Abstract

The design and synthesis of efficient electrocatalysts are important for electrochemical conversion technologies. The oxygen evolution reaction (OER) is a key process in such conversions, having applications in water splitting and metal–air batteries. Here, we report ultrathin metal–organic frameworks (MOFs) as promising electrocatalysts for the OER in alkaline conditions. Our as-prepared ultrathin NiCo bimetal–organic framework nanosheets on glassy-carbon electrodes require an overpotential of 250 mV to achieve a current density of 10 mA cm−2. When the MOF nanosheets are loaded on copper foam, this decreases to 189 mV. We propose that the surface atoms in the ultrathin MOF sheets are coordinatively unsaturated—that is, they have open sites for adsorption—as evidenced by a suite of measurements, including X-ray spectroscopy and density-functional theory calculations. The findings suggest that the coordinatively unsaturated metal atoms are the dominating active centres and the coupling effect between Ni and Co metals is crucial for tuning the electrocatalytic activity.

Suggested Citation

  • Shenlong Zhao & Yun Wang & Juncai Dong & Chun-Ting He & Huajie Yin & Pengfei An & Kun Zhao & Xiaofei Zhang & Chao Gao & Lijuan Zhang & Jiawei Lv & Jinxin Wang & Jianqi Zhang & Abdul Muqsit Khattak & N, 2016. "Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution," Nature Energy, Nature, vol. 1(12), pages 1-10, December.
    • Handle: RePEc:nat:natene:v:1:y:2016:i:12:d:10.1038_nenergy.2016.184
    DOI: 10.1038/nenergy.2016.184
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    Cited by:

    1. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    2. Qianbao Wu & Junwu Liang & Mengjun Xiao & Chang Long & Lei Li & Zhenhua Zeng & Andraž Mavrič & Xia Zheng & Jing Zhu & Hai-Wei Liang & Hongfei Liu & Matjaz Valant & Wei Wang & Zhengxing Lv & Jiong Li &, 2023. "Non-covalent ligand-oxide interaction promotes oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Lingxin Luo & Lingxiang Hou & Xueping Cui & Pengxin Zhan & Ping He & Chuying Dai & Ruian Li & Jichen Dong & Ye Zou & Guoming Liu & Yanpeng Liu & Jian Zheng, 2024. "Self-condensation-assisted chemical vapour deposition growth of atomically two-dimensional MOF single-crystals," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    5. Fanpeng Cheng & Xianyun Peng & Lingzi Hu & Bin Yang & Zhongjian Li & Chung-Li Dong & Jeng-Lung Chen & Liang-Ching Hsu & Lecheng Lei & Qiang Zheng & Ming Qiu & Liming Dai & Yang Hou, 2022. "Accelerated water activation and stabilized metal-organic framework via constructing triangular active-regions for ampere-level current density hydrogen production," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Yun Fan & Yu Shen & Jia Zhang & Xinglong Zhang & Zeqi Zhang & Hongfeng Li & Yong Peng & Jiena Weng & Ruijie Xie & Wenlei Zhang & Yu Han & Yawen Xiao & Suoying Zhang & Bing Zheng & Hao-Li Zhang & Sheng, 2024. "Wedging crystals to fabricate crystalline framework nanosheets via mechanochemistry," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Zilong Wu & Xiangyu Liu & Haijing Li & Zhiyi Sun & Maosheng Cao & Zezhou Li & Chaohe Fang & Jihan Zhou & Chuanbao Cao & Juncai Dong & Shenlong Zhao & Zhuo Chen, 2023. "A semiconductor-electrocatalyst nano interface constructed for successive photoelectrochemical water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Yubo Chen & Joon Kyo Seo & Yuanmiao Sun & Thomas A. Wynn & Marco Olguin & Minghao Zhang & Jingxian Wang & Shibo Xi & Yonghua Du & Kaidi Yuan & Wei Chen & Adrian C. Fisher & Maoyu Wang & Zhenxing Feng , 2022. "Enhanced oxygen evolution over dual corner-shared cobalt tetrahedra," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Subhabrata Mukhopadhyay & Muhammad Saad Naeem & G. Shiva Shanker & Arnab Ghatak & Alagar R. Kottaichamy & Ran Shimoni & Liat Avram & Itamar Liberman & Rotem Balilty & Raya Ifraemov & Illya Rozenberg &, 2024. "Local CO2 reservoir layer promotes rapid and selective electrochemical CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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