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Customized reaction route for ruthenium oxide towards stabilized water oxidation in high-performance PEM electrolyzers

Author

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  • Zhaoping Shi

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Ji Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yibo Wang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Shiwei Liu

    (Chinese Academy of Sciences)

  • Jianbing Zhu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Jiahao Yang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Xian Wang

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Jing Ni

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Zheng Jiang

    (Chinese Academy of Sciences
    Chinese Academy of Science)

  • Lijuan Zhang

    (Chinese Academy of Sciences
    Chinese Academy of Science)

  • Ying Wang

    (Chinese Academy of Sciences)

  • Changpeng Liu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Wei Xing

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Junjie Ge

    (Chinese Academy of Sciences
    University of Science and Technology of China)

Abstract

The poor stability of Ru-based acidic oxygen evolution (OER) electrocatalysts has greatly hampered their application in polymer electrolyte membrane electrolyzers (PEMWEs). Traditional understanding of performance degradation centered on influence of bias fails in describing the stability trend, calling for deep dive into the essential origin of inactivation. Here we uncover the decisive role of reaction route (including catalytic mechanism and intermediates binding strength) on operational stability of Ru-based catalysts. Using MRuOx (M = Ce4+, Sn4+, Ru4+, Cr4+) solid solution as structure model, we find the reaction route, thereby stability, can be customized by controlling the Ru charge. The screened SnRuOx thus exhibits orders of magnitude lifespan extension. A scalable PEMWE single cell using SnRuOx anode conveys an ever-smallest degradation rate of 53 μV h−1 during a 1300 h operation at 1 A cm−2.

Suggested Citation

  • Zhaoping Shi & Ji Li & Yibo Wang & Shiwei Liu & Jianbing Zhu & Jiahao Yang & Xian Wang & Jing Ni & Zheng Jiang & Lijuan Zhang & Ying Wang & Changpeng Liu & Wei Xing & Junjie Ge, 2023. "Customized reaction route for ruthenium oxide towards stabilized water oxidation in high-performance PEM electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36380-9
    DOI: 10.1038/s41467-023-36380-9
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    as
    1. Xinghui Liu & Shibo Xi & Hyunwoo Kim & Ashwani Kumar & Jinsun Lee & Jian Wang & Ngoc Quang Tran & Taehun Yang & Xiaodong Shao & Mengfang Liang & Min Gyu Kim & Hyoyoung Lee, 2021. "Restructuring highly electron-deficient metal-metal oxides for boosting stability in acidic oxygen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Julius Knöppel & Maximilian Möckl & Daniel Escalera-López & Kevin Stojanovski & Markus Bierling & Thomas Böhm & Simon Thiele & Matthias Rzepka & Serhiy Cherevko, 2021. "On the limitations in assessing stability of oxygen evolution catalysts using aqueous model electrochemical cells," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Linlin Cao & Qiquan Luo & Jiajia Chen & Lan Wang & Yue Lin & Huijuan Wang & Xiaokang Liu & Xinyi Shen & Wei Zhang & Wei Liu & Zeming Qi & Zheng Jiang & Jinlong Yang & Tao Yao, 2019. "Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Hui Su & Wanlin Zhou & Wu Zhou & Yuanli Li & Lirong Zheng & Hui Zhang & Meihuan Liu & Xiuxiu Zhang & Xuan Sun & Yanzhi Xu & Fengchun Hu & Jing Zhang & Tiandou Hu & Qinghua Liu & Shiqiang Wei, 2021. "In-situ spectroscopic observation of dynamic-coupling oxygen on atomically dispersed iridium electrocatalyst for acidic water oxidation," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    5. Qian Dang & Haiping Lin & Zhenglong Fan & Lu Ma & Qi Shao & Yujin Ji & Fangfang Zheng & Shize Geng & Shi-Ze Yang & Ningning Kong & Wenxiang Zhu & Youyong Li & Fan Liao & Xiaoqing Huang & Mingwang Shao, 2021. "Iridium metallene oxide for acidic oxygen evolution catalysis," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    6. Rui Li & Haiyun Wang & Fei Hu & K. C. Chan & Xiongjun Liu & Zhaoping Lu & Jing Wang & Zhibin Li & Longjiao Zeng & Yuanyuan Li & Xiaojun Wu & Yujie Xiong, 2021. "IrW nanochannel support enabling ultrastable electrocatalytic oxygen evolution at 2 A cm−2 in acidic media," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    7. Hong Nhan Nong & Lorenz J. Falling & Arno Bergmann & Malte Klingenhof & Hoang Phi Tran & Camillo Spöri & Rik Mom & Janis Timoshenko & Guido Zichittella & Axel Knop-Gericke & Simone Piccinin & Javier P, 2020. "Key role of chemistry versus bias in electrocatalytic oxygen evolution," Nature, Nature, vol. 587(7834), pages 408-413, November.
    8. Zhen-Feng Huang & Jiajia Song & Yonghua Du & Shibo Xi & Shuo Dou & Jean Marie Vianney Nsanzimana & Cheng Wang & Zhichuan J. Xu & Xin Wang, 2019. "Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts," Nature Energy, Nature, vol. 4(4), pages 329-338, April.
    9. Shunsuke Yagi & Ikuya Yamada & Hirofumi Tsukasaki & Akihiro Seno & Makoto Murakami & Hiroshi Fujii & Hungru Chen & Naoto Umezawa & Hideki Abe & Norimasa Nishiyama & Shigeo Mori, 2015. "Covalency-reinforced oxygen evolution reaction catalyst," Nature Communications, Nature, vol. 6(1), pages 1-6, November.
    10. Xianbing Miao & Lifu Zhang & Liang Wu & Zhenpeng Hu & Lei Shi & Shiming Zhou, 2019. "Quadruple perovskite ruthenate as a highly efficient catalyst for acidic water oxidation," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
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    2. Qianqian Ji & Bing Tang & Xilin Zhang & Chao Wang & Hao Tan & Jie Zhao & Ruiqi Liu & Mei Sun & Hengjie Liu & Chang Jiang & Jianrong Zeng & Xingke Cai & Wensheng Yan, 2024. "Operando identification of the oxide path mechanism with different dual-active sites for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Ding Chen & Ruohan Yu & Kesong Yu & Ruihu Lu & Hongyu Zhao & Jixiang Jiao & Youtao Yao & Jiawei Zhu & Jinsong Wu & Shichun Mu, 2024. "Bicontinuous RuO2 nanoreactors for acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Yu Shen & Xiao-Long Zhang & Ming-Rong Qu & Jie Ma & Sheng Zhu & Yu-Lin Min & Min-Rui Gao & Shu-Hong Yu, 2024. "Cr dopant mediates hydroxyl spillover on RuO2 for high-efficiency proton exchange membrane electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Yanrong Xue & Jiwu Zhao & Liang Huang & Ying-Rui Lu & Abdul Malek & Ge Gao & Zhongbin Zhuang & Dingsheng Wang & Cafer T. Yavuz & Xu Lu, 2023. "Stabilizing ruthenium dioxide with cation-anchored sulfate for durable oxygen evolution in proton-exchange membrane water electrolyzers," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Xinyu Ping & Yongduo Liu & Lixia Zheng & Yang Song & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Locking the lattice oxygen in RuO2 to stabilize highly active Ru sites in acidic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Lu Li & Gengwei Zhang & Chenhui Zhou & Fan Lv & Yingjun Tan & Ying Han & Heng Luo & Dawei Wang & Youxing Liu & Changshuai Shang & Lingyou Zeng & Qizheng Huang & Ruijin Zeng & Na Ye & Mingchuan Luo & S, 2024. "Lanthanide-regulating Ru-O covalency optimizes acidic oxygen evolution electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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