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Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation

Author

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  • Ning Zhang

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon
    The Hong Kong Polytechnic University Shenzhen Research Institute)

  • Xiaobin Feng

    (City University of Hong Kong, Kowloon
    Shenzhen Research Institute of City University of Hong Kong)

  • Dewei Rao

    (Jiangsu University)

  • Xi Deng

    (University of Science and Technology of China)

  • Lejuan Cai

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon
    The Hong Kong Polytechnic University Shenzhen Research Institute)

  • Bocheng Qiu

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon
    The Hong Kong Polytechnic University Shenzhen Research Institute)

  • Ran Long

    (University of Science and Technology of China)

  • Yujie Xiong

    (University of Science and Technology of China)

  • Yang Lu

    (City University of Hong Kong, Kowloon
    Shenzhen Research Institute of City University of Hong Kong)

  • Yang Chai

    (The Hong Kong Polytechnic University, Hung Hom, Kowloon
    The Hong Kong Polytechnic University Shenzhen Research Institute)

Abstract

Anodic oxygen evolution reaction (OER) is recognized as kinetic bottleneck in water electrolysis. Transition metal sites with high valence states can accelerate the reaction kinetics to offer highly intrinsic activity, but suffer from thermodynamic formation barrier. Here, we show subtle engineering of highly oxidized Ni4+ species in surface reconstructed (oxy)hydroxides on multicomponent FeCoCrNi alloy film through interatomically electronic interplay. Our spectroscopic investigations with theoretical studies uncover that Fe component enables the formation of Ni4+ species, which is energetically favored by the multistep evolution of Ni2+→Ni3+→Ni4+. The dynamically constructed Ni4+ species drives holes into oxygen ligands to facilitate intramolecular oxygen coupling, triggering lattice oxygen activation to form Fe-Ni dual-sites as ultimate catalytic center with highly intrinsic activity. As a result, the surface reconstructed FeCoCrNi OER catalyst delivers outstanding mass activity and turnover frequency of 3601 A gmetal−1 and 0.483 s−1 at an overpotential of 300 mV in alkaline electrolyte, respectively.

Suggested Citation

  • Ning Zhang & Xiaobin Feng & Dewei Rao & Xi Deng & Lejuan Cai & Bocheng Qiu & Ran Long & Yujie Xiong & Yang Lu & Yang Chai, 2020. "Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-17934-7
    DOI: 10.1038/s41467-020-17934-7
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    Cited by:

    1. Xu Luo & Hongyu Zhao & Xin Tan & Sheng Lin & Kesong Yu & Xueqin Mu & Zhenhua Tao & Pengxia Ji & Shichun Mu, 2024. "Fe-S dually modulated adsorbate evolution and lattice oxygen compatible mechanism for water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Shanlin Li & Ruguang Ma & Jingcong Hu & Zichuang Li & Lijia Liu & Xunlu Wang & Yue Lu & George E. Sterbinsky & Shuhu Liu & Lei Zheng & Jie Liu & Danmin Liu & Jiacheng Wang, 2022. "Coordination environment tuning of nickel sites by oxyanions to optimize methanol electro-oxidation activity," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Zuyun He & Jun Zhang & Zhiheng Gong & Hang Lei & Deng Zhou & Nian Zhang & Wenjie Mai & Shijun Zhao & Yan Chen, 2022. "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Qianbao Wu & Junwu Liang & Mengjun Xiao & Chang Long & Lei Li & Zhenhua Zeng & Andraž Mavrič & Xia Zheng & Jing Zhu & Hai-Wei Liang & Hongfei Liu & Matjaz Valant & Wei Wang & Zhengxing Lv & Jiong Li &, 2023. "Non-covalent ligand-oxide interaction promotes oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Zheng-Jie Chen & Jiuyi Dong & Jiajing Wu & Qiting Shao & Na Luo & Minwei Xu & Yuanmiao Sun & Yongbing Tang & Jing Peng & Hui-Ming Cheng, 2023. "Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Achim Füngerlings & Marcus Wohlgemuth & Denis Antipin & Emma Minne & Ellen Marijn Kiens & Javier Villalobos & Marcel Risch & Felix Gunkel & Rossitza Pentcheva & Christoph Baeumer, 2023. "Crystal-facet-dependent surface transformation dictates the oxygen evolution reaction activity in lanthanum nickelate," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    8. Zuyun He & Jinwoo Hwang & Zhiheng Gong & Mengzhen Zhou & Nian Zhang & Xiongwu Kang & Jeong Woo Han & Yan Chen, 2022. "Promoting biomass electrooxidation via modulating proton and oxygen anion deintercalation in hydroxide," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Shangkun Li & Zeyi Zhang & Walker R. Marks & Xinan Huang & Hang Chen & Dragos C. Stoian & Rolf Erni & Carlos A. Triana & Greta R. Patzke, 2024. "{Co4O4} Cubanes in a conducting polymer matrix as bio-inspired molecular oxygen evolution catalysts," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    10. Jie Wei & Yangfan Shao & Jingbo Xu & Fang Yin & Zejian Li & Haitao Qian & Yinping Wei & Liang Chang & Yu Han & Jia Li & Lin Gan, 2024. "Sequential oxygen evolution and decoupled water splitting via electrochemical redox reaction of nickel hydroxides," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    11. Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Jingjing Cao & Huaxing Liang & Jie Yang & Zhiyang Zhu & Jin Deng & Xiaodong Li & Menachem Elimelech & Xinglin Lu, 2024. "Depolymerization mechanisms and closed-loop assessment in polyester waste recycling," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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