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Photocatalytic aerobic oxidation of C(sp3)-H bonds

Author

Listed:
  • Lei Zhang

    (South China Normal University)

  • Run-Han Li

    (South China Normal University)

  • Xiao-Xin Li

    (South China Normal University)

  • Shengyao Wang

    (Huazhong Agricultural University)

  • Jiang Liu

    (South China Normal University)

  • Xiao-Xuan Hong

    (South China Normal University)

  • Long-Zhang Dong

    (South China Normal University)

  • Shun-Li Li

    (South China Normal University)

  • Ya-Qian Lan

    (South China Normal University)

Abstract

In modern industries, the aerobic oxidation of C(sp3)-H bonds to achieve the value-added conversion of hydrocarbons requires high temperatures and pressures, which significantly increases energy consumption and capital investment. The development of a light-driven strategy, even under natural sunlight and ambient air, is therefore of great significance. Here we develop a series of hetero-motif molecular junction photocatalysts containing two bifunctional motifs. With these materials, the reduction of O2 and oxidation of C(sp3)-H bonds can be effectively accomplished, thus realizing efficient aerobic oxidation of C(sp3)-H bonds in e.g., toluene and ethylbenzene. Especially for ethylbenzene oxidation reactions, excellent catalytic capacity (861 mmol g cat−1) is observed. In addition to the direct oxidation of C(sp3)-H bonds, CeBTTD-A can also be applied to other types of aerobic oxidation reactions highlighting their potential for industrial applications.

Suggested Citation

  • Lei Zhang & Run-Han Li & Xiao-Xin Li & Shengyao Wang & Jiang Liu & Xiao-Xuan Hong & Long-Zhang Dong & Shun-Li Li & Ya-Qian Lan, 2024. "Photocatalytic aerobic oxidation of C(sp3)-H bonds," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44833-y
    DOI: 10.1038/s41467-024-44833-y
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    References listed on IDEAS

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    1. Yingying Fan & Wencai Zhou & Xueying Qiu & Hongdong Li & Yuheng Jiang & Zhonghui Sun & Dongxue Han & Li Niu & Zhiyong Tang, 2021. "Selective photocatalytic oxidation of methane by quantum-sized bismuth vanadate," Nature Sustainability, Nature, vol. 4(6), pages 509-515, June.
    2. Ranwen Ou & Huacheng Zhang & Vinh X. Truong & Lian Zhang & Hanaa M. Hegab & Li Han & Jue Hou & Xiwang Zhang & Ana Deletic & Lei Jiang & George P. Simon & Huanting Wang, 2020. "A sunlight-responsive metal–organic framework system for sustainable water desalination," Nature Sustainability, Nature, vol. 3(12), pages 1052-1058, December.
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