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Halogen hydrogen-bonded organic framework (XHOF) constructed by singlet open-shell diradical for efficient photoreduction of U(VI)

Author

Listed:
  • Lijuan Feng

    (Hainan University)

  • Yihui Yuan

    (Hainan University)

  • Bingjie Yan

    (Hainan University)

  • Tiantian Feng

    (Hainan University)

  • Yaping Jian

    (Hainan University)

  • Jiacheng Zhang

    (Hainan University)

  • Wenyan Sun

    (Hainan University)

  • Ke Lin

    (Hainan University)

  • Guangsheng Luo

    (Hainan University)

  • Ning Wang

    (Hainan University)

Abstract

Synthesis of framework materials possessing specific spatial structures or containing functional ligands has attracted tremendous attention. Herein, a halogen hydrogen-bonded organic framework (XHOF) is fabricated by using Cl− ions as central connection nodes to connect organic ligands, 7,7,8,8-tetraaminoquinodimethane (TAQ), by forming a Cl−···H3 hydrogen bond structure. Unlike metallic node-linked MOFs, covalent bond-linked COFs, and intermolecular hydrogen bond-linked HOFs, XHOFs represent a different kind of crystalline framework. The electron-withdrawing effect of Cl− combined with the electron-rich property of the organic ligand TAQ strengthens the hydrogen bonds and endows XHOF-TAQ with high stability. Due to the production of excited electrons by TAQ under light irradiation, XHOF-TAQ can efficiently catalyze the reduction of soluble U(VI) to insoluble U(IV) with a capacity of 1708 mg-U g−1-material. This study fabricates a material for uranium immobilization for the sustainability of the environment and opens up a new direction for synthesizing crystalline framework materials.

Suggested Citation

  • Lijuan Feng & Yihui Yuan & Bingjie Yan & Tiantian Feng & Yaping Jian & Jiacheng Zhang & Wenyan Sun & Ke Lin & Guangsheng Luo & Ning Wang, 2022. "Halogen hydrogen-bonded organic framework (XHOF) constructed by singlet open-shell diradical for efficient photoreduction of U(VI)," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29107-9
    DOI: 10.1038/s41467-022-29107-9
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    References listed on IDEAS

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    1. Ranwen Ou & Huacheng Zhang & Vinh X. Truong & Lian Zhang & Hanaa M. Hegab & Li Han & Jue Hou & Xiwang Zhang & Ana Deletic & Lei Jiang & George P. Simon & Huanting Wang, 2020. "A sunlight-responsive metal–organic framework system for sustainable water desalination," Nature Sustainability, Nature, vol. 3(12), pages 1052-1058, December.
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    Cited by:

    1. Yuanshan Huang & Xin Zheng & Junyan Wu & Yong Gao & Qidan Ling & Zhenghuan Lin, 2024. "Photoinduced π-Bond breakage causing dynamic closing-opening shell transition of Z-type Diphenylmaleonitriles molecules," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Ruoting Yin & Xiang Zhu & Qiang Fu & Tianyi Hu & Lingyun Wan & Yingying Wu & Yifan Liang & Zhengya Wang & Zhen-Lin Qiu & Yuan-Zhi Tan & Chuanxu Ma & Shijing Tan & Wei Hu & Bin Li & Z. F. Wang & Jinlon, 2024. "Artificial kagome lattices of Shockley surface states patterned by halogen hydrogen-bonded organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Zhongshan Chen & Jingyi Wang & Mengjie Hao & Yinghui Xie & Xiaolu Liu & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2023. "Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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