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Efficient and stable visible-light-driven Z-scheme overall water splitting using an oxysulfide H2 evolution photocatalyst

Author

Listed:
  • Lihua Lin

    (Shinshu University)

  • Yiwen Ma

    (Shinshu University)

  • Junie Jhon M. Vequizo

    (Shinshu University)

  • Mamiko Nakabayashi

    (The University of Tokyo)

  • Chen Gu

    (Shinshu University)

  • Xiaoping Tao

    (Shinshu University)

  • Hiroaki Yoshida

    (Science and Innovation Center, Mitsubishi Chemical Corporation, Aoba-ku
    Japan Technological Research Association of Artificial Photosynthetic Chemical Process (ARPChem))

  • Yuriy Pihosh

    (Office of University Professors, The University of Tokyo)

  • Yuta Nishina

    (Okayama University)

  • Akira Yamakata

    (Okayama University)

  • Naoya Shibata

    (The University of Tokyo)

  • Takashi Hisatomi

    (Shinshu University)

  • Tsuyoshi Takata

    (Shinshu University)

  • Kazunari Domen

    (Shinshu University
    Office of University Professors, The University of Tokyo)

Abstract

So-called Z-scheme systems permit overall water splitting using narrow-bandgap photocatalysts. To boost the performance of such systems, it is necessary to enhance the intrinsic activities of the hydrogen evolution photocatalyst and oxygen evolution photocatalyst, promote electron transfer from the oxygen evolution photocatalyst to the hydrogen evolution photocatalyst, and suppress back reactions. The present work develop a high-performance oxysulfide photocatalyst, Sm2Ti2O5S2, as an hydrogen evolution photocatalyst for use in a Z-scheme overall water splitting system in combination with BiVO4 as the oxygen evolution photocatalyst and reduced graphene oxide as the solid-state electron mediator. After surface modifications of the photocatalysts to promote charge separation and redox reactions, this system is able to split water into hydrogen and oxygen for more than 100 hours with a solar-to-hydrogen energy conversion efficiency of 0.22%. In contrast to many existing photocatalytic systems, the water splitting activity of the present system is only minimally reduced by increasing the background pressure to 90 kPa. These results suggest characteristics suitable for applications under practical operating conditions.

Suggested Citation

  • Lihua Lin & Yiwen Ma & Junie Jhon M. Vequizo & Mamiko Nakabayashi & Chen Gu & Xiaoping Tao & Hiroaki Yoshida & Yuriy Pihosh & Yuta Nishina & Akira Yamakata & Naoya Shibata & Takashi Hisatomi & Tsuyosh, 2024. "Efficient and stable visible-light-driven Z-scheme overall water splitting using an oxysulfide H2 evolution photocatalyst," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-44706-4
    DOI: 10.1038/s41467-024-44706-4
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    References listed on IDEAS

    as
    1. Tian Liu & Zhenhua Pan & Kosaku Kato & Junie Jhon M. Vequizo & Rito Yanagi & Xiaoshan Zheng & Weilai Yu & Akira Yamakata & Baoliang Chen & Shu Hu & Kenji Katayama & Chiheng Chu, 2022. "A general interfacial-energetics-tuning strategy for enhanced artificial photosynthesis," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Zheng Wang & Ying Luo & Takashi Hisatomi & Junie Jhon M. Vequizo & Sayaka Suzuki & Shanshan Chen & Mamiko Nakabayashi & Lihua Lin & Zhenhua Pan & Nobuko Kariya & Akira Yamakata & Naoya Shibata & Tsuyo, 2021. "Sequential cocatalyst decoration on BaTaO2N towards highly-active Z-scheme water splitting," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Hiroshi Nishiyama & Taro Yamada & Mamiko Nakabayashi & Yoshiki Maehara & Masaharu Yamaguchi & Yasuko Kuromiya & Yoshie Nagatsuma & Hiromasa Tokudome & Seiji Akiyama & Tomoaki Watanabe & Ryoichi Narush, 2021. "Photocatalytic solar hydrogen production from water on a 100-m2 scale," Nature, Nature, vol. 598(7880), pages 304-307, October.
    4. Yu Qi & Jiangwei Zhang & Yuan Kong & Yue Zhao & Shanshan Chen & Deng Li & Wei Liu & Yifan Chen & Tengfeng Xie & Junyan Cui & Can Li & Kazunari Domen & Fuxiang Zhang, 2022. "Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Tian Liu & Zhenhua Pan & Junie Jhon M. Vequizo & Kosaku Kato & Binbin Wu & Akira Yamakata & Kenji Katayama & Baoliang Chen & Chiheng Chu & Kazunari Domen, 2022. "Overall photosynthesis of H2O2 by an inorganic semiconductor," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
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