IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-48349-3.html
   My bibliography  Save this article

Heterogeneous organophotocatalytic HBr oxidation coupled with oxygen reduction for boosting bromination of arenes

Author

Listed:
  • Jie Wang

    (Shenzhen University
    Shenzhen University)

  • Jiahao Liang

    (Shenzhen University
    Shenzhen University)

  • Hao Hou

    (Shenzhen University
    Shenzhen University)

  • Wei Liu

    (Shenzhen University
    Shenzhen University)

  • Hongru Wu

    (Shenzhen University
    Shenzhen University)

  • Hongli Sun

    (Shenzhen University
    Shenzhen University)

  • Wei Ou

    (Shenzhen University
    Shenzhen University)

  • Chenliang Su

    (Shenzhen University
    Shenzhen University)

  • Bin Liu

    (Kowloon
    Kowloon)

Abstract

Developing mild photocatalytic bromination strategies using sustainable bromo source has been attracting intense interests, but there is still much room for improvement. Full utilization of redox centers of photocatalysts for efficient generation of Br+ species is the key. Herein we report heterogenous organophotocatalytic HBr oxidation coupled with oxygen reduction to furnish Br2 and H2O2 for effective bromination of arenes over Al2O3 supported perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA). Mechanism studies suggest that O-vacancy in Al2O3 can provide Lewis-acid-type anchoring sites for O2, enabling unexpected dual-electron transfer from anchored photoexcited PTCDA to chemically bound O2 to produce H2O2. The in-situ generated H2O2 and Br2 over redox centers work together to generate HBrO for bromination of arenes. This work provides new insights that heterogenization of organophotocatalysts can not only help to improve their stability and recyclability, but also endow them with the ability to trigger unusual reaction mode via cooperative catalysis with supports.

Suggested Citation

  • Jie Wang & Jiahao Liang & Hao Hou & Wei Liu & Hongru Wu & Hongli Sun & Wei Ou & Chenliang Su & Bin Liu, 2024. "Heterogeneous organophotocatalytic HBr oxidation coupled with oxygen reduction for boosting bromination of arenes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48349-3
    DOI: 10.1038/s41467-024-48349-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-48349-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-48349-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Richard Y. Liu & Sheng Guo & Shao-Xiong Lennon Luo & Timothy M. Swager, 2022. "Solution-processable microporous polymer platform for heterogenization of diverse photoredox catalysts," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Yubao Zhao & Peng Zhang & Zhenchun Yang & Lina Li & Jingyu Gao & Sheng Chen & Tengfeng Xie & Caozheng Diao & Shibo Xi & Beibei Xiao & Chun Hu & Wonyong Choi, 2021. "Mechanistic analysis of multiple processes controlling solar-driven H2O2 synthesis using engineered polymeric carbon nitride," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Tian Liu & Zhenhua Pan & Junie Jhon M. Vequizo & Kosaku Kato & Binbin Wu & Akira Yamakata & Kenji Katayama & Baoliang Chen & Chiheng Chu & Kazunari Domen, 2022. "Overall photosynthesis of H2O2 by an inorganic semiconductor," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Yajun Zou & Sara Abednatanzi & Parviz Gohari Derakhshandeh & Stefano Mazzanti & Christoph M. Schüßlbauer & Daniel Cruz & Pascal Voort & Jian-Wen Shi & Markus Antonietti & Dirk M. Guldi & Aleksandr Sav, 2022. "Red edge effect and chromoselective photocatalysis with amorphous covalent triazine-based frameworks," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xidong Zhang & Duoduo Gao & Bicheng Zhu & Bei Cheng & Jiaguo Yu & Huogen Yu, 2024. "Enhancing photocatalytic H2O2 production with Au co-catalysts through electronic structure modification," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    3. Floriana Moruzzi & Weimin Zhang & Balaji Purushothaman & Soranyel Gonzalez-Carrero & Catherine M. Aitchison & Benjamin Willner & Fabien Ceugniet & Yuanbao Lin & Jan Kosco & Hu Chen & Junfu Tian & Mary, 2023. "Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Jaeho Yoon & Hanhwi Jang & Min-Wook Oh & Thomas Hilberath & Frank Hollmann & Yeon Sik Jung & Chan Beum Park, 2022. "Heat-fueled enzymatic cascade for selective oxyfunctionalization of hydrocarbons," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Xinzhe Tian & Yinggang Guo & Wankai An & Yun-Lai Ren & Yuchen Qin & Caoyuan Niu & Xin Zheng, 2022. "Coupling photocatalytic water oxidation with reductive transformations of organic molecules," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Jie Huang & Yuyang Kang & Jianan Liu & Tingting Yao & Jianhang Qiu & Peipei Du & Biaohong Huang & Weijin Hu & Yan Liang & Tengfeng Xie & Chunlin Chen & Li-Chang Yin & Lianzhou Wang & Hui-Ming Cheng & , 2023. "Gradient tungsten-doped Bi3TiNbO9 ferroelectric photocatalysts with additional built-in electric field for efficient overall water splitting," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    8. Ji Wu & Zhonghuan Liu & Xinyu Lin & Enhui Jiang & Shuai Zhang & Pengwei Huo & Yan Yan & Peng Zhou & Yongsheng Yan, 2022. "Breaking through water-splitting bottlenecks over carbon nitride with fluorination," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Lihua Lin & Yiwen Ma & Junie Jhon M. Vequizo & Mamiko Nakabayashi & Chen Gu & Xiaoping Tao & Hiroaki Yoshida & Yuriy Pihosh & Yuta Nishina & Akira Yamakata & Naoya Shibata & Takashi Hisatomi & Tsuyosh, 2024. "Efficient and stable visible-light-driven Z-scheme overall water splitting using an oxysulfide H2 evolution photocatalyst," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Tian Liu & Zhenhua Pan & Kosaku Kato & Junie Jhon M. Vequizo & Rito Yanagi & Xiaoshan Zheng & Weilai Yu & Akira Yamakata & Baoliang Chen & Shu Hu & Kenji Katayama & Chiheng Chu, 2022. "A general interfacial-energetics-tuning strategy for enhanced artificial photosynthesis," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    11. Xu Zhang & Hui Su & Peixin Cui & Yongyong Cao & Zhenyuan Teng & Qitao Zhang & Yang Wang & Yibo Feng & Ran Feng & Jixiang Hou & Xiyuan Zhou & Peijie Ma & Hanwen Hu & Kaiwen Wang & Cong Wang & Liyong Ga, 2023. "Developing Ni single-atom sites in carbon nitride for efficient photocatalytic H2O2 production," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48349-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.