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0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst

Author

Listed:
  • Wei Li

    (Shaanxi University of Science and Technology)

  • Wen Duan

    (Shaanxi University of Science and Technology)

  • Guocheng Liao

    (Shaanxi University of Science and Technology)

  • Fanfan Gao

    (Shaanxi University of Science and Technology)

  • Yusen Wang

    (Shaanxi University of Science and Technology)

  • Rongxia Cui

    (Shaanxi University of Science and Technology)

  • Jincai Zhao

    (Chinese Academy of Sciences)

  • Chuanyi Wang

    (Shaanxi University of Science and Technology)

Abstract

Solar-driven flat-panel H2O-to-H2 conversion is an important technology for value-added solar fuel production. However, most frequently used particulate photocatalysts are hard to achieve stable photocatalysis in flat-panel reaction module due to the influence of mechanical shear force. Herein, a highly active CdS@SiO2-Pt composite with rapid CdS-to-Pt electron transfer and restrained photoexciton recombination was prepared to process into an organic-inorganic membrane by compounding with polyvinylidene fluoride (PVDF). This PVDF networked organic-inorganic membrane displays high photostability and excellent operability, achieving improved simulated sunlight-driven alkaline H2O-to-H2 conversion activity (213.48 mmol m−2 h−1) following a 0.68% of solar-to-hydrogen efficiency. No obvious variation in its appearance and micromorphology was observed even being recycled for 50-times, which considerably outperforms the existing membrane photocatalysts. Subsequently, a homemade panel H2O-to-H2 conversion system was fabricated to obtain a 0.05% of solar-to-hydrogen efficiency. In this study, we opens up a prospect for practical application of photocatalysis technology.

Suggested Citation

  • Wei Li & Wen Duan & Guocheng Liao & Fanfan Gao & Yusen Wang & Rongxia Cui & Jincai Zhao & Chuanyi Wang, 2024. "0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51183-2
    DOI: 10.1038/s41467-024-51183-2
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