IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51183-2.html
   My bibliography  Save this article

0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst

Author

Listed:
  • Wei Li

    (Shaanxi University of Science and Technology)

  • Wen Duan

    (Shaanxi University of Science and Technology)

  • Guocheng Liao

    (Shaanxi University of Science and Technology)

  • Fanfan Gao

    (Shaanxi University of Science and Technology)

  • Yusen Wang

    (Shaanxi University of Science and Technology)

  • Rongxia Cui

    (Shaanxi University of Science and Technology)

  • Jincai Zhao

    (Chinese Academy of Sciences)

  • Chuanyi Wang

    (Shaanxi University of Science and Technology)

Abstract

Solar-driven flat-panel H2O-to-H2 conversion is an important technology for value-added solar fuel production. However, most frequently used particulate photocatalysts are hard to achieve stable photocatalysis in flat-panel reaction module due to the influence of mechanical shear force. Herein, a highly active CdS@SiO2-Pt composite with rapid CdS-to-Pt electron transfer and restrained photoexciton recombination was prepared to process into an organic-inorganic membrane by compounding with polyvinylidene fluoride (PVDF). This PVDF networked organic-inorganic membrane displays high photostability and excellent operability, achieving improved simulated sunlight-driven alkaline H2O-to-H2 conversion activity (213.48 mmol m−2 h−1) following a 0.68% of solar-to-hydrogen efficiency. No obvious variation in its appearance and micromorphology was observed even being recycled for 50-times, which considerably outperforms the existing membrane photocatalysts. Subsequently, a homemade panel H2O-to-H2 conversion system was fabricated to obtain a 0.05% of solar-to-hydrogen efficiency. In this study, we opens up a prospect for practical application of photocatalysis technology.

Suggested Citation

  • Wei Li & Wen Duan & Guocheng Liao & Fanfan Gao & Yusen Wang & Rongxia Cui & Jincai Zhao & Chuanyi Wang, 2024. "0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51183-2
    DOI: 10.1038/s41467-024-51183-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51183-2
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51183-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. R. Yukawa & M. Kobayashi & T. Kanda & D. Shiga & K. Yoshimatsu & S. Ishibashi & M. Minohara & M. Kitamura & K. Horiba & A. F. Santander-Syro & H. Kumigashira, 2021. "Resonant tunneling driven metal-insulator transition in double quantum-well structures of strongly correlated oxide," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    2. Jan Kosco & Soranyel Gonzalez-Carrero & Calvyn T. Howells & Teng Fei & Yifan Dong & Rachid Sougrat & George T. Harrison & Yuliar Firdaus & Rajendar Sheelamanthula & Balaji Purushothaman & Floriana Mor, 2022. "Generation of long-lived charges in organic semiconductor heterojunction nanoparticles for efficient photocatalytic hydrogen evolution," Nature Energy, Nature, vol. 7(4), pages 340-351, April.
    3. Hiroshi Nishiyama & Taro Yamada & Mamiko Nakabayashi & Yoshiki Maehara & Masaharu Yamaguchi & Yasuko Kuromiya & Yoshie Nagatsuma & Hiromasa Tokudome & Seiji Akiyama & Tomoaki Watanabe & Ryoichi Narush, 2021. "Photocatalytic solar hydrogen production from water on a 100-m2 scale," Nature, Nature, vol. 598(7880), pages 304-307, October.
    4. Xunliang Hu & Zhen Zhan & Jianqiao Zhang & Irshad Hussain & Bien Tan, 2021. "Immobilized covalent triazine frameworks films as effective photocatalysts for hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    5. Gianluca Aiello & Mathieu Féchant & Alexis Morvan & Julien Basset & Marco Aprili & Julien Gabelli & Jérôme Estève, 2022. "Quantum bath engineering of a high impedance microwave mode through quasiparticle tunneling," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    6. Yu Qi & Jiangwei Zhang & Yuan Kong & Yue Zhao & Shanshan Chen & Deng Li & Wei Liu & Yifan Chen & Tengfeng Xie & Junyan Cui & Can Li & Kazunari Domen & Fuxiang Zhang, 2022. "Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Zhenyu Shi & Xiao Zhang & Xiaoqian Lin & Guigao Liu & Chongyi Ling & Shibo Xi & Bo Chen & Yiyao Ge & Chaoliang Tan & Zhuangchai Lai & Zhiqi Huang & Xinyang Ruan & Li Zhai & Lujiang Li & Zijian Li & Xi, 2023. "Phase-dependent growth of Pt on MoS2 for highly efficient H2 evolution," Nature, Nature, vol. 621(7978), pages 300-305, September.
    8. Yuanjie Su & Weixiong Li & Xiaoxing Cheng & Yihao Zhou & Shuai Yang & Xu Zhang & Chunxu Chen & Tiannan Yang & Hong Pan & Guangzhong Xie & Guorui Chen & Xun Zhao & Xiao Xiao & Bei Li & Huiling Tai & Ya, 2022. "High-performance piezoelectric composites via β phase programming," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Wan Jae Dong & Yixin Xiao & Ke R. Yang & Zhengwei Ye & Peng Zhou & Ishtiaque Ahmed Navid & Victor S. Batista & Zetian Mi, 2023. "Pt nanoclusters on GaN nanowires for solar-asssisted seawater hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Takuya Suguro & Fuminao Kishimoto & Nobuko Kariya & Tsuyoshi Fukui & Mamiko Nakabayashi & Naoya Shibata & Tsuyoshi Takata & Kazunari Domen & Kazuhiro Takanabe, 2022. "A hygroscopic nano-membrane coating achieves efficient vapor-fed photocatalytic water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    11. Chunyang Dong & Cheng Lian & Songchang Hu & Zesheng Deng & Jianqiu Gong & Mingde Li & Honglai Liu & Mingyang Xing & Jinlong Zhang, 2018. "Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    12. Xiaowei Shi & Chao Dai & Xin Wang & Jiayue Hu & Junying Zhang & Lingxia Zheng & Liang Mao & Huajun Zheng & Mingshan Zhu, 2022. "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Zhongshan Chen & Jingyi Wang & Mengjie Hao & Yinghui Xie & Xiaolu Liu & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2023. "Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qitao Chen & Baodong Mao & Yanhong Liu & Yunjie Zhou & Hui Huang & Song Wang & Longhua Li & Wei-Cheng Yan & Weidong Shi & Zhenhui Kang, 2024. "Designing 2D carbon dot nanoreactors for alcohol oxidation coupled with hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Ting He & Wenlong Zhen & Yongzhi Chen & Yuanyuan Guo & Zhuoer Li & Ning Huang & Zhongping Li & Ruoyang Liu & Yuan Liu & Xu Lian & Can Xue & Tze Chien Sum & Wei Chen & Donglin Jiang, 2023. "Integrated interfacial design of covalent organic framework photocatalysts to promote hydrogen evolution from water," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Lihua Lin & Yiwen Ma & Junie Jhon M. Vequizo & Mamiko Nakabayashi & Chen Gu & Xiaoping Tao & Hiroaki Yoshida & Yuriy Pihosh & Yuta Nishina & Akira Yamakata & Naoya Shibata & Takashi Hisatomi & Tsuyosh, 2024. "Efficient and stable visible-light-driven Z-scheme overall water splitting using an oxysulfide H2 evolution photocatalyst," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Chong Wang & Bo Wu & Yang Li & Shen Zhou & Conghui Wu & Tianyang Dong & Ying Jiang & Zihui Hua & Yupeng Song & Wei Wen & Jianxin Tian & Yongqiang Chai & Rui Wen & Chunru Wang, 2024. "Aggregation promotes charge separation in fullerene-indacenodithiophene dyad," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Lili Zhang & Ning Zhang & Huishan Shang & Zhiyi Sun & Zihao Wei & Jingtao Wang & Yuanting Lei & Xiaochen Wang & Dan Wang & Yafei Zhao & Zhongti Sun & Fang Zhang & Xu Xiang & Bing Zhang & Wenxing Chen, 2024. "High-density asymmetric iron dual-atom sites for efficient and stable electrochemical water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    6. Isaac Holmes-Gentle & Saurabh Tembhurne & Clemens Suter & Sophia Haussener, 2023. "Kilowatt-scale solar hydrogen production system using a concentrated integrated photoelectrochemical device," Nature Energy, Nature, vol. 8(6), pages 586-596, June.
    7. Zhengwei Yang & Zhen-Yu Wu & Zhexing Lin & Tianji Liu & Liping Ding & Wenbo Zhai & Zipeng Chen & Yi Jiang & Jinlei Li & Siyun Ren & Zhenhui Lin & Wangxi Liu & Jianyong Feng & Xing Zhang & Wei Li & Yi , 2024. "Optically selective catalyst design with minimized thermal emission for facilitating photothermal catalysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Xiaolu Liu & Yinghui Xie & Mengjie Hao & Yang Li & Zhongshan Chen & Hui Yang & Geoffrey I. N. Waterhouse & Xiangke Wang & Shengqian Ma, 2024. "Secondary metal ion-induced electrochemical reduction of U(VI) to U(IV) solids," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Xin Wang & Boyan Liu & Siqing Ma & Yingjuan Zhang & Lianzhou Wang & Gangqiang Zhu & Wei Huang & Songcan Wang, 2024. "Induced dipole moments in amorphous ZnCdS catalysts facilitate photocatalytic H2 evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    10. Xinyi Zhang & Michael Schwarze & Reinhard Schomäcker & Roel Krol & Fatwa F. Abdi, 2023. "Life cycle net energy assessment of sustainable H2 production and hydrogenation of chemicals in a coupled photoelectrochemical device," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    11. Shengqi Wang & Wenjie Li & Junying Xue & Jifeng Ge & Jing He & Junyang Hou & Yu Xie & Yuan Li & Hao Zhang & Zdeněk Sofer & Zhaoyang Lin, 2024. "A library of 2D electronic material inks synthesized by liquid-metal-assisted intercalation of crystal powders," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    12. Mahdi Takach & Mirza Sarajlić & Dorothee Peters & Michael Kroener & Frank Schuldt & Karsten von Maydell, 2022. "Review of Hydrogen Production Techniques from Water Using Renewable Energy Sources and Its Storage in Salt Caverns," Energies, MDPI, vol. 15(4), pages 1-17, February.
    13. Changhao Liu & Ningsi Zhang & Yang Li & Rongli Fan & Wenjing Wang & Jianyong Feng & Chen Liu & Jiaou Wang & Weichang Hao & Zhaosheng Li & Zhigang Zou, 2023. "Long-term durability of metastable β-Fe2O3 photoanodes in highly corrosive seawater," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    14. Weijun Weng & Jia Guo, 2022. "The effect of enantioselective chiral covalent organic frameworks and cysteine sacrificial donors on photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    15. Yannan Liu & Cheng-Hao Liu & Tushar Debnath & Yong Wang & Darius Pohl & Lucas V. Besteiro & Debora Motta Meira & Shengyun Huang & Fan Yang & Bernd Rellinghaus & Mohamed Chaker & Dmytro F. Perepichka &, 2023. "Silver nanoparticle enhanced metal-organic matrix with interface-engineering for efficient photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    16. Chenhui Zhou & Lu Li & Zhaoqi Dong & Fan Lv & Hongyu Guo & Kai Wang & Menggang Li & Zhengyi Qian & Na Ye & Zheng Lin & Mingchuan Luo & Shaojun Guo, 2024. "Pinning effect of lattice Pb suppressing lattice oxygen reactivity of Pb-RuO2 enables stable industrial-level electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    17. Artem Musiienko & Fengjiu Yang & Thomas William Gries & Chiara Frasca & Dennis Friedrich & Amran Al-Ashouri & Elifnaz Sağlamkaya & Felix Lang & Danny Kojda & Yi-Teng Huang & Valerio Stacchini & Robert, 2024. "Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    18. Kenichi Endo & Masaki Saruyama & Toshiharu Teranishi, 2023. "Location-selective immobilisation of single-atom catalysts on the surface or within the interior of ionic nanocrystals using coordination chemistry," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    19. Xianlong Li & Zhiliang Wang & Alireza Sasani & Ardeshir Baktash & Kai Wang & Haijiao Lu & Jiakang You & Peng Chen & Ping Chen & Yifan Bao & Shujun Zhang & Gang Liu & Lianzhou Wang, 2024. "Oxygen vacancy induced defect dipoles in BiVO4 for photoelectrocatalytic partial oxidation of methane," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Takuya Suguro & Fuminao Kishimoto & Nobuko Kariya & Tsuyoshi Fukui & Mamiko Nakabayashi & Naoya Shibata & Tsuyoshi Takata & Kazunari Domen & Kazuhiro Takanabe, 2022. "A hygroscopic nano-membrane coating achieves efficient vapor-fed photocatalytic water splitting," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51183-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.