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Large off-diagonal magnetoelectricity in a triangular Co2+-based collinear antiferromagnet

Author

Listed:
  • Xianghan Xu

    (Princeton University)

  • Yiqing Hao

    (Oak Ridge National Laboratory)

  • Shiyu Peng

    (Hong Kong University of Science and Technology)

  • Qiang Zhang

    (Oak Ridge National Laboratory)

  • Danrui Ni

    (Princeton University)

  • Chen Yang

    (Princeton University)

  • Xi Dai

    (Hong Kong University of Science and Technology)

  • Huibo Cao

    (Oak Ridge National Laboratory)

  • R. J. Cava

    (Princeton University)

Abstract

Magnetic toroidicity is an uncommon type of magnetic structure in solid-state materials. Here, we experimentally demonstrate that collinear spins in a material with R-3 lattice symmetry can host a significant magnetic toroidicity, even parallel to the ordered spins. Taking advantage of a single crystal sample of CoTe6O13 with an R-3 space group and a Co2+ triangular sublattice, temperature-dependent magnetic, thermodynamic, and neutron diffraction results reveal A-type antiferromagnetic order below 19.5 K, with magnetic point group -3′ and k = (0,0,0). Our symmetry analysis suggests that the missing mirror symmetry in the lattice could lead to the local spin canting for a toroidal moment along the c axis. Experimentally, we observe a large off-diagonal magnetoelectric coefficient of 41.2 ps/m that evidences the magnetic toroidicity. In addition, the paramagnetic state exhibits a large effective moment per Co2+, indicating that the magnetic moment in CoTe6O13 has a significant orbital contribution. CoTe6O13 embodies an excellent opportunity for the study of next-generation functional magnetoelectric materials.

Suggested Citation

  • Xianghan Xu & Yiqing Hao & Shiyu Peng & Qiang Zhang & Danrui Ni & Chen Yang & Xi Dai & Huibo Cao & R. J. Cava, 2023. "Large off-diagonal magnetoelectricity in a triangular Co2+-based collinear antiferromagnet," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43858-z
    DOI: 10.1038/s41467-023-43858-z
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    1. T. Hayashida & Y. Uemura & K. Kimura & S. Matsuoka & D. Morikawa & S. Hirose & K. Tsuda & T. Hasegawa & T. Kimura, 2020. "Visualization of ferroaxial domains in an order-disorder type ferroaxial crystal," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Anne S. Zimmermann & Dennis Meier & Manfred Fiebig, 2014. "Ferroic nature of magnetic toroidal order," Nature Communications, Nature, vol. 5(1), pages 1-6, December.
    3. N. Hur & S. Park & P. A. Sharma & J. S. Ahn & S. Guha & S-W. Cheong, 2004. "Electric polarization reversal and memory in a multiferroic material induced by magnetic fields," Nature, Nature, vol. 429(6990), pages 392-395, May.
    4. Sasikanth Manipatruni & Dmitri E. Nikonov & Chia-Ching Lin & Tanay A. Gosavi & Huichu Liu & Bhagwati Prasad & Yen-Lin Huang & Everton Bonturim & Ramamoorthy Ramesh & Ian A. Young, 2019. "Scalable energy-efficient magnetoelectric spin–orbit logic," Nature, Nature, vol. 565(7737), pages 35-42, January.
    5. Lei Ding & Xianghan Xu & Harald O. Jeschke & Xiaojian Bai & Erxi Feng & Admasu Solomon Alemayehu & Jaewook Kim & Fei-Ting Huang & Qiang Zhang & Xiaxin Ding & Neil Harrison & Vivien Zapf & Daniel Khoms, 2021. "Field-tunable toroidal moment in a chiral-lattice magnet," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
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