IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-42131-7.html
   My bibliography  Save this article

Autonomous self-healing organic crystals for nonlinear optics

Author

Listed:
  • Saikat Mondal

    (Indian Institute of Science Education and Research Kolkata)

  • Pratap Tanari

    (Indian Institute of Science Education and Research Kolkata)

  • Samrat Roy

    (Indian Institute of Science Education and Research Kolkata)

  • Surojit Bhunia

    (Indian Institute of Science Education and Research Kolkata)

  • Rituparno Chowdhury

    (Indian Institute of Science Education and Research Kolkata)

  • Arun K. Pal

    (Indian Association for the Cultivation of Science)

  • Ayan Datta

    (Indian Association for the Cultivation of Science)

  • Bipul Pal

    (Indian Institute of Science Education and Research Kolkata)

  • C. Malla Reddy

    (Indian Institute of Science Education and Research Kolkata)

Abstract

Non-centrosymmetric molecular crystals have a plethora of applications, such as piezoelectric transducers, energy storage and nonlinear optical materials owing to their unique structural order which is absent in other synthetic materials. As most crystals are brittle, their efficiency declines upon prolonged usage due to fatigue or catastrophic failure, limiting their utilities. Some natural substances, like bone, enamel, leaf and skin, function efficiently, last a life-time, thanks to their inherent self-healing nature. Therefore, incorporating self-healing ability in crystalline materials will greatly broaden their scope. Here, we report single crystals of a dibenzoate derivative, capable of self-healing within milliseconds via autonomous actuation. Systematic quantitative experiments reveal the limit of mechanical forces that the self-healing crystals can withstand. As a proof-of-concept, we also demonstrate that our self-healed crystals can retain their second harmonic generation (SHG) with high efficiency. Kinematic analysis of the actuation in our system also revealed its impressive performance parameters, and shows actuation response times in the millisecond range.

Suggested Citation

  • Saikat Mondal & Pratap Tanari & Samrat Roy & Surojit Bhunia & Rituparno Chowdhury & Arun K. Pal & Ayan Datta & Bipul Pal & C. Malla Reddy, 2023. "Autonomous self-healing organic crystals for nonlinear optics," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42131-7
    DOI: 10.1038/s41467-023-42131-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-42131-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-42131-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Takuya Taniguchi & Haruki Sugiyama & Hidehiro Uekusa & Motoo Shiro & Toru Asahi & Hideko Koshima, 2018. "Walking and rolling of crystals induced thermally by phase transition," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. S. R. White & N. R. Sottos & P. H. Geubelle & J. S. Moore & M. R. Kessler & S. R. Sriram & E. N. Brown & S. Viswanathan, 2001. "Autonomic healing of polymer composites," Nature, Nature, vol. 409(6822), pages 794-797, February.
    3. Mark Burnworth & Liming Tang & Justin R. Kumpfer & Andrew J. Duncan & Frederick L. Beyer & Gina L. Fiore & Stuart J. Rowan & Christoph Weder, 2011. "Optically healable supramolecular polymers," Nature, Nature, vol. 472(7343), pages 334-337, April.
    4. Christopher M. Barr & Ta Duong & Daniel C. Bufford & Zachary Milne & Abhilash Molkeri & Nathan M. Heckman & David P. Adams & Ankit Srivastava & Khalid Hattar & Michael J. Demkowicz & Brad L. Boyce, 2023. "Autonomous healing of fatigue cracks via cold welding," Nature, Nature, vol. 620(7974), pages 552-556, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marieh B. Al-Handawi & Patrick Commins & Ahmed S. Dalaq & Pedro A. Santos-Florez & Srujana Polavaram & Pascal Didier & Durga Prasad Karothu & Qiang Zhu & Mohammed Daqaq & Liang Li & Panče Naumov, 2024. "Ferroelastic ionic organic crystals that self-heal to 95%," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Marieh B. Al-Handawi & Patrick Commins & Ahmed S. Dalaq & Pedro A. Santos-Florez & Srujana Polavaram & Pascal Didier & Durga Prasad Karothu & Qiang Zhu & Mohammed Daqaq & Liang Li & Panče Naumov, 2024. "Ferroelastic ionic organic crystals that self-heal to 95%," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. H R Williams & R S Trask & I P Bond, 2011. "A probabilistic approach for design and certification of self-healing advanced composite structures," Journal of Risk and Reliability, , vol. 225(4), pages 435-449, December.
    3. Alexander D. Snyder & Zachary J. Phillips & Jack S. Turicek & Charles E. Diesendruck & Kalyana B. Nakshatrala & Jason F. Patrick, 2022. "Prolonged in situ self-healing in structural composites via thermo-reversible entanglement," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Gorshkov, Vyacheslav & Privman, Vladimir & Libert, Sergiy, 2016. "Lattice percolation approach to 3D modeling of tissue aging," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 462(C), pages 207-216.
    5. Jing Chen & Yiyang Gao & Lei Shi & Wei Yu & Zongjie Sun & Yifan Zhou & Shuang Liu & Heng Mao & Dongyang Zhang & Tongqing Lu & Quan Chen & Demei Yu & Shujiang Ding, 2022. "Phase-locked constructing dynamic supramolecular ionic conductive elastomers with superior toughness, autonomous self-healing and recyclability," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Mehdi Rohullah & Vuppu Vinay Pradeep & Shruti Singh & Rajadurai Chandrasekar, 2024. "Mechanically controlled multifaceted dynamic transformations in twisted organic crystal waveguides," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Yuki Hagiwara & Shodai Hasebe & Hiroki Fujisawa & Junko Morikawa & Toru Asahi & Hideko Koshima, 2023. "Photothermally induced natural vibration for versatile and high-speed actuation of crystals," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Xuesong Yang & Linfeng Lan & Xiuhong Pan & Qi Di & Xiaokong Liu & Liang Li & Panče Naumov & Hongyu Zhang, 2023. "Bioinspired soft robots based on organic polymer-crystal hybrid materials with response to temperature and humidity," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    9. Rui Xu & Gilbert Santiago Cañón Bermúdez & Oleksandr V. Pylypovskyi & Oleksii M. Volkov & Eduardo Sergio Oliveros Mata & Yevhen Zabila & Rico Illing & Pavlo Makushko & Pavel Milkin & Leonid Ionov & Jü, 2022. "Self-healable printed magnetic field sensors using alternating magnetic fields," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    10. Ghasan Fahim Huseien & Moncef L. Nehdi & Iman Faridmehr & Sib Krishna Ghoshal & Hussein K. Hamzah & Omrane Benjeddou & Fahed Alrshoudi, 2022. "Smart Bio-Agents-Activated Sustainable Self-Healing Cementitious Materials: An All-Inclusive Overview on Progress, Benefits and Challenges," Sustainability, MDPI, vol. 14(4), pages 1-37, February.
    11. Jiawei Lin & Jianmin Zhou & Liang Li & Ibrahim Tahir & Songgu Wu & Panče Naumov & Junbo Gong, 2024. "Highly efficient in crystallo energy transduction of light to work," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42131-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.