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Ferroelastic ionic organic crystals that self-heal to 95%

Author

Listed:
  • Marieh B. Al-Handawi

    (New York University Abu Dhabi)

  • Patrick Commins

    (New York University Abu Dhabi)

  • Ahmed S. Dalaq

    (King Fahd University of Petroleum & Minerals)

  • Pedro A. Santos-Florez

    (University of North Carolina at Charlotte)

  • Srujana Polavaram

    (New York University Abu Dhabi)

  • Pascal Didier

    (UMR 7021 CNRS Université de Strasbourg)

  • Durga Prasad Karothu

    (New York University Abu Dhabi
    New York University Abu Dhabi)

  • Qiang Zhu

    (University of North Carolina at Charlotte)

  • Mohammed Daqaq

    (New York University Abu Dhabi
    Brooklyn)

  • Liang Li

    (New York University Abu Dhabi
    Sorbonne University Abu Dhabi)

  • Panče Naumov

    (New York University Abu Dhabi
    New York University Abu Dhabi
    New York University
    Macedonian Academy of Sciences and Arts)

Abstract

The realm of self-healing materials integrates chemical and physical mechanisms that prevent wear and fracturing and extend the operational lifetime. Unlike the favorable rheology of amorphous soft materials that facilitates efficient contact between fragments, the efficiency of recovery of atomistically ordered materials is restricted by slower interfacial mass transport and the need for ideal physical alignment, which limits their real-world application. We report drastic enhancements in efficiency and recovery time in the self-healing of anilinium bromide, challenging these limitations. Crystals of this material recovered up to 49% within seconds and up to 95% after 100 min via ferroelastic detwinning. The spatial evolution of strain during cracking and healing was measured in real time using digital image correlation. Favorable alignment and strong ionic bonding across the interface of partially fractured crystals facilitate self-healing. This study elevates organic crystals close to the best-in-class self-healing polymers and sets an approach for durable crystal-based optoelectronics.

Suggested Citation

  • Marieh B. Al-Handawi & Patrick Commins & Ahmed S. Dalaq & Pedro A. Santos-Florez & Srujana Polavaram & Pascal Didier & Durga Prasad Karothu & Qiang Zhu & Mohammed Daqaq & Liang Li & Panče Naumov, 2024. "Ferroelastic ionic organic crystals that self-heal to 95%," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51625-x
    DOI: 10.1038/s41467-024-51625-x
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    References listed on IDEAS

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    1. Hyunjoong Chung & Dmytro Dudenko & Fengjiao Zhang & Gabriele D’Avino & Christian Ruzié & Audrey Richard & Guillaume Schweicher & Jérôme Cornil & David Beljonne & Yves Geerts & Ying Diao, 2018. "Rotator side chains trigger cooperative transition for shape and function memory effect in organic semiconductors," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    2. S. R. White & N. R. Sottos & P. H. Geubelle & J. S. Moore & M. R. Kessler & S. R. Sriram & E. N. Brown & S. Viswanathan, 2001. "Autonomic healing of polymer composites," Nature, Nature, vol. 409(6822), pages 794-797, February.
    3. Saikat Mondal & Pratap Tanari & Samrat Roy & Surojit Bhunia & Rituparno Chowdhury & Arun K. Pal & Ayan Datta & Bipul Pal & C. Malla Reddy, 2023. "Autonomous self-healing organic crystals for nonlinear optics," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
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