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Logarithmic and Archimedean organic crystalline spirals

Author

Listed:
  • Xuesong Yang

    (Jilin University)

  • Linfeng Lan

    (Jilin University)

  • Ibrahim Tahir

    (New York University Abu Dhabi)

  • Zainab Alhaddad

    (New York University Abu Dhabi)

  • Qi Di

    (Jilin University)

  • Liang Li

    (New York University Abu Dhabi
    Sorbonne University Abu Dhabi)

  • Baolei Tang

    (Jilin University)

  • Panče Naumov

    (New York University Abu Dhabi
    New York University Abu Dhabi
    Bul. Krste Misirkov 2
    100 Washington Square East)

  • Hongyu Zhang

    (Jilin University)

Abstract

Crystals can be found in many shapes but do not usually grow as spirals. Here we show that applying a non-uniform layer of a polymer blend onto slender centimeter-size organic crystals prestrains the crystals into hybrid dynamic elements with spiral shapes that respond reversibly to environmental variations in temperature or humidity by curling. Exposure to humidity results in partial uncurling within several seconds, whereby a logarithmic-type spiral crystal is transformed into an Archimedean one. Conical helices obtained by lateral pulling of the spirals can wind around solid objects similar to plant tendrils or lift suspended objects with a positive correlation between the actuator’s elongation and the cargo mass. The morphological, kinematic, and kinetic attributes turn these hybrid materials into an attractive platform for flexible sensors and soft robots, while they also provide an approach to morph crystalline fibers in non-natural spiral habits inaccessible with the common crystallization approaches.

Suggested Citation

  • Xuesong Yang & Linfeng Lan & Ibrahim Tahir & Zainab Alhaddad & Qi Di & Liang Li & Baolei Tang & Panče Naumov & Hongyu Zhang, 2024. "Logarithmic and Archimedean organic crystalline spirals," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-53196-3
    DOI: 10.1038/s41467-024-53196-3
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    References listed on IDEAS

    as
    1. Xuesong Yang & Linfeng Lan & Xiuhong Pan & Xiaokong Liu & Yilong Song & Xueying Yang & Qingfeng Dong & Liang Li & Panče Naumov & Hongyu Zhang, 2022. "Electrically conductive hybrid organic crystals as flexible optical waveguides," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Xuesong Yang & Linfeng Lan & Liang Li & Xiaokong Liu & Panče Naumov & Hongyu Zhang, 2022. "Remote and precise control over morphology and motion of organic crystals by using magnetic field," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Takuya Taniguchi & Haruki Sugiyama & Hidehiro Uekusa & Motoo Shiro & Toru Asahi & Hideko Koshima, 2018. "Walking and rolling of crystals induced thermally by phase transition," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
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