IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-34303-8.html
   My bibliography  Save this article

Development of long lifespan high-energy aqueous organic||iodine rechargeable batteries

Author

Listed:
  • Zishuai Zhang

    (State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology
    Sauvage Laboratory for Smart Materials, School of Materials Science and Engineering, Harbin Institute of Technology
    Shenzhen Key Laboratory of Flexible Printed Electronics Technology, Harbin Institute of Technology)

  • Yilong Zhu

    (The University of Adelaide)

  • Miao Yu

    (State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology)

  • Yan Jiao

    (The University of Adelaide)

  • Yan Huang

    (Sauvage Laboratory for Smart Materials, School of Materials Science and Engineering, Harbin Institute of Technology
    Shenzhen Key Laboratory of Flexible Printed Electronics Technology, Harbin Institute of Technology
    State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology)

Abstract

Rechargeable aqueous metal||I2 electrochemical energy storage systems are a cost-effective alternative to conventional transition-metal-based batteries for grid energy storage. However, the growth of unfavorable metallic deposition and the irreversible formation of electrochemically inactive by-products at the negative electrode during cycling hinder their development. To circumvent these drawbacks, herein we propose 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) as negative electrode active material and a saturated mixed KCl/I2 aqueous electrolyte solution. The use of these components allows for exploiting two sequential reversible electrochemical reactions in a single cell. Indeed, when they are tested in combination with an active carbon-enveloped I2 electrode in a glass cell configuration, we report an initial specific discharge capacity of 900 mAh g−1 (electrode mass of iodine only) and an average cell discharge voltage of 1.25 V at 40 A g−1 and 25 $$\pm$$ ± 1 °C. Finally, we also report the assembly and testing of a PTCDI|KCl-I2|carbon paper multilayer pouch cell prototype with a discharge capacity retention of about 70% after 900 cycles at 80 mA and 25 $$\pm$$ ± 1 °C.

Suggested Citation

  • Zishuai Zhang & Yilong Zhu & Miao Yu & Yan Jiao & Yan Huang, 2022. "Development of long lifespan high-energy aqueous organic||iodine rechargeable batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34303-8
    DOI: 10.1038/s41467-022-34303-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-34303-8
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-34303-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Cuiping Han & Hongfei Li & Yu Li & Jiaxiong Zhu & Chunyi Zhi, 2021. "Proton-assisted calcium-ion storage in aromatic organic molecular crystal with coplanar stacked structure," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Hui Dong & Oscar Tutusaus & Yanliang Liang & Ye Zhang & Zachary Lebens-Higgins & Wanli Yang & Rana Mohtadi & Yan Yao, 2020. "High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes," Nature Energy, Nature, vol. 5(12), pages 1043-1050, December.
    3. Yiping Zou & Tingting Liu & Qijun Du & Yingying Li & Haibo Yi & Xing Zhou & Zhuxin Li & Lujie Gao & Lan Zhang & Xiao Liang, 2021. "A four-electron Zn-I2 aqueous battery enabled by reversible I−/I2/I+ conversion," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Huajun Tian & Tao Gao & Xiaogang Li & Xiwen Wang & Chao Luo & Xiulin Fan & Chongyin Yang & Liumin Suo & Zhaohui Ma & Weiqiang Han & Chunsheng Wang, 2017. "High power rechargeable magnesium/iodine battery chemistry," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    5. Shuo Jin & Jiefu Yin & Xiaosi Gao & Arpita Sharma & Pengyu Chen & Shifeng Hong & Qing Zhao & Jingxu Zheng & Yue Deng & Yong Lak Joo & Lynden A. Archer, 2022. "Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Junmin Ge & Ling Fan & Apparao M. Rao & Jiang Zhou & Bingan Lu, 2022. "Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries," Nature Sustainability, Nature, vol. 5(3), pages 225-234, March.
    7. Yu Zhao & Lina Wang & Hye Ryung Byon, 2013. "High-performance rechargeable lithium-iodine batteries using triiodide/iodide redox couples in an aqueous cathode," Nature Communications, Nature, vol. 4(1), pages 1-7, October.
    8. Dongliang Chao & Changrong Zhu & Peihua Yang & Xinhui Xia & Jilei Liu & Jin Wang & Xiaofeng Fan & Serguei V. Savilov & Jianyi Lin & Hong Jin Fan & Ze Xiang Shen, 2016. "Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance," Nature Communications, Nature, vol. 7(1), pages 1-8, November.
    9. Liwei Jiang & Yaxiang Lu & Chenglong Zhao & Lilu Liu & Jienan Zhang & Qiangqiang Zhang & Xing Shen & Junmei Zhao & Xiqian Yu & Hong Li & Xuejie Huang & Liquan Chen & Yong-Sheng Hu, 2019. "Building aqueous K-ion batteries for energy storage," Nature Energy, Nature, vol. 4(6), pages 495-503, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wenjiao Ma & Tingting Liu & Chen Xu & Chengjun Lei & Pengjie Jiang & Xin He & Xiao Liang, 2023. "A twelve-electron conversion iodine cathode enabled by interhalogen chemistry in aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Weibin Yan & Ying Liu & Jiazhen Qiu & Feipeng Tan & Jiahui Liang & Xinze Cai & Chunlong Dai & Jiangqi Zhao & Zifeng Lin, 2024. "A tripartite synergistic optimization strategy for zinc-iodine batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Songshan Bi & Shuai Wang & Fang Yue & Zhiwei Tie & Zhiqiang Niu, 2021. "A rechargeable aqueous manganese-ion battery based on intercalation chemistry," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Wenjiao Ma & Tingting Liu & Chen Xu & Chengjun Lei & Pengjie Jiang & Xin He & Xiao Liang, 2023. "A twelve-electron conversion iodine cathode enabled by interhalogen chemistry in aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Han Wu & Junnan Hao & Yunling Jiang & Yiran Jiao & Jiahao Liu & Xin Xu & Kenneth Davey & Chunsheng Wang & Shi-Zhang Qiao, 2024. "Alkaline-based aqueous sodium-ion batteries for large-scale energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Li, Yong & Yang, Jie & Song, Jian, 2015. "Electromagnetic effects model and design of energy systems for lithium batteries with gradient structure in sustainable energy electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 842-851.
    5. Abdelaziz, Fouad Ben & Maddah, Bacel & Flamand, Tülay & Azar, Jimmy, 2024. "Store-Wide space planning balancing impulse and convenience," European Journal of Operational Research, Elsevier, vol. 312(1), pages 211-226.
    6. Li, Yong & Yang, Jie & Song, Jian, 2017. "Design principles and energy system scale analysis technologies of new lithium-ion and aluminum-ion batteries for sustainable energy electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 645-651.
    7. Haiming Lv & Zhiquan Wei & Cuiping Han & Xiaolong Yang & Zijie Tang & Yantu Zhang & Chunyi Zhi & Hongfei Li, 2023. "Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Li, Yong & Yang, Jie & Song, Jian, 2016. "Structural model, size effect and nano-energy system design for more sustainable energy of solid state automotive battery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 685-697.
    9. Chao-Yu Li & Ming Chen & Shuai Liu & Xinyao Lu & Jinhui Meng & Jiawei Yan & Héctor D. Abruña & Guang Feng & Tianquan Lian, 2022. "Unconventional interfacial water structure of highly concentrated aqueous electrolytes at negative electrode polarizations," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    10. Hasan, Md. Mahedi & Islam, Tamanna & Ratan, Zubair Ahmed & Shaikh, M. Nasiruzzaman & Karim, Mohammad Rezaul & Rahman, Mohammad Mominur & Alharbi, Hamad F. & Uddin, Jamal & Aziz, Md. Abdul & Ahammad, A, 2021. "Ni and Co oxide water oxidation electrocatalysts: Effect of thermal treatment on catalytic activity and surface morphology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    11. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Alves, Ana Cristina & Gong, Xue & Li, Mingjiang, 2023. "The BRI: A new development cooperation paradigm in the making? Unpacking China’s infrastructure cooperation along the Maritime Silk Road," World Development, Elsevier, vol. 169(C).
    13. Xia, Liangyu & Zhao, Xingyu & Wu, Yao, 2023. "Status, disadvantages, and prospects of oil shale in China: An economic perspective," Energy Policy, Elsevier, vol. 183(C).
    14. Li, Yong & Yang, Jie & Song, Jian, 2015. "Microscale characterization of coupled degradation mechanism of graded materials in lithium batteries of electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1445-1461.
    15. Zhaoheng Liang & Fei Tian & Gongzheng Yang & Chengxin Wang, 2023. "Enabling long-cycling aqueous sodium-ion batteries via Mn dissolution inhibition using sodium ferrocyanide electrolyte additive," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    16. Shuo Sun & Zhen Han & Wei Liu & Qiuying Xia & Liang Xue & Xincheng Lei & Teng Zhai & Dong Su & Hui Xia, 2023. "Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    17. Huanxin Li & Yi Gong & Haihui Zhou & Jing Li & Kai Yang & Boyang Mao & Jincan Zhang & Yan Shi & Jinhai Deng & Mingxuan Mao & Zhongyuan Huang & Shuqiang Jiao & Yafei Kuang & Yunlong Zhao & Shenglian Lu, 2023. "Ampere-hour-scale soft-package potassium-ion hybrid capacitors enabling 6-minute fast-charging," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Wu, Xi-Shuo & Dong, Xiao-Ling & Wang, Bo-Yang & Xia, Ji-Li & Li, Wen-Cui, 2022. "Revealing the sodium storage behavior of biomass-derived hard carbon by using pure lignin and cellulose as model precursors," Renewable Energy, Elsevier, vol. 189(C), pages 630-638.
    19. Zhiquan Wei & Zhaodong Huang & Guojin Liang & Yiqiao Wang & Shixun Wang & Yihan Yang & Tao Hu & Chunyi Zhi, 2024. "Starch-mediated colloidal chemistry for highly reversible zinc-based polyiodide redox flow batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    20. Ana Sanz Matias & Fabrice Roncoroni & Siddharth Sundararaman & David Prendergast, 2024. "Ca-dimers, solvent layering, and dominant electrochemically active species in Ca(BH4)2 in THF," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34303-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.