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Electrochemistry-assisted selective butadiene hydrogenation with water

Author

Listed:
  • Yong-Qing Yan

    (Wuhan University of Technology)

  • Ya Chen

    (Wuhan University of Technology)

  • Zhao Wang

    (Wuhan University of Technology
    Foshan Xianhu Laboratory of the Advanced Energy Science and Technology, Guangdong Laboratory, Xianhu Hydrogen Valley)

  • Li-Hua Chen

    (Wuhan University of Technology)

  • Hao-Lin Tang

    (Wuhan University of Technology
    Foshan Xianhu Laboratory of the Advanced Energy Science and Technology, Guangdong Laboratory, Xianhu Hydrogen Valley)

  • Bao-Lian Su

    (Wuhan University of Technology
    University of Namur)

Abstract

Alkene feedstocks are used to produce polymers with a market expected to reach 128.4 million metric tons by 2027. Butadiene is one of the impurities poisoning alkene polymerization catalysts and is usually removed by thermocatalytic selective hydrogenation. Excessive use of H2, poor alkene selectivity and high operating temperature (e.g. up to 350 °C) remain the most significant drawbacks of the thermocatalytic process, calling for innovative alternatives. Here we report a room-temperature (25~30 °C) electrochemistry-assisted selective hydrogenation process in a gas-fed fixed bed reactor, using water as the hydrogen source. Using a palladium membrane as the catalyst, this process offers a robust catalytic performance for selective butadiene hydrogenation, with alkene selectivity staying around 92% at a butadiene conversion above 97% for over 360 h of time on stream. The overall energy consumption of this process is 0.003 Wh/mLbutadiene, which is thousands of times lower than that of the thermocatalytic route. This study proposes an alternative electrochemical technology for industrial hydrogenation without the need for elevated temperature and hydrogen gas.

Suggested Citation

  • Yong-Qing Yan & Ya Chen & Zhao Wang & Li-Hua Chen & Hao-Lin Tang & Bao-Lian Su, 2023. "Electrochemistry-assisted selective butadiene hydrogenation with water," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37708-1
    DOI: 10.1038/s41467-023-37708-1
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    References listed on IDEAS

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    1. Kailong Hu & Tatsuhiko Ohto & Yuki Nagata & Mitsuru Wakisaka & Yoshitaka Aoki & Jun-ichi Fujita & Yoshikazu Ito, 2021. "Catalytic activity of graphene-covered non-noble metals governed by proton penetration in electrochemical hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Felicia R. Lucci & Jilei Liu & Matthew D. Marcinkowski & Ming Yang & Lawrence F. Allard & Maria Flytzani-Stephanopoulos & E. Charles H. Sykes, 2015. "Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit," Nature Communications, Nature, vol. 6(1), pages 1-8, December.
    3. Ian T. McCrum & Marc T. M. Koper, 2020. "The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum," Nature Energy, Nature, vol. 5(11), pages 891-899, November.
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