IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v6y2015i1d10.1038_ncomms9550.html
   My bibliography  Save this article

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit

Author

Listed:
  • Felicia R. Lucci

    (Tufts University)

  • Jilei Liu

    (Tufts University)

  • Matthew D. Marcinkowski

    (Tufts University)

  • Ming Yang

    (Tufts University)

  • Lawrence F. Allard

    (Oak Ridge National Laboratory)

  • Maria Flytzani-Stephanopoulos

    (Tufts University)

  • E. Charles H. Sykes

    (Tufts University)

Abstract

Platinum is ubiquitous in the production sectors of chemicals and fuels; however, its scarcity in nature and high price will limit future proliferation of platinum-catalysed reactions. One promising approach to conserve platinum involves understanding the smallest number of platinum atoms needed to catalyse a reaction, then designing catalysts with the minimal platinum ensembles. Here we design and test a new generation of platinum–copper nanoparticle catalysts for the selective hydrogenation of 1,3-butadiene,, an industrially important reaction. Isolated platinum atom geometries enable hydrogen activation and spillover but are incapable of C–C bond scission that leads to loss of selectivity and catalyst deactivation. γ-Alumina-supported single-atom alloy nanoparticle catalysts with

Suggested Citation

  • Felicia R. Lucci & Jilei Liu & Matthew D. Marcinkowski & Ming Yang & Lawrence F. Allard & Maria Flytzani-Stephanopoulos & E. Charles H. Sykes, 2015. "Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit," Nature Communications, Nature, vol. 6(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms9550
    DOI: 10.1038/ncomms9550
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms9550
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms9550?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yong-Qing Yan & Ya Chen & Zhao Wang & Li-Hua Chen & Hao-Lin Tang & Bao-Lian Su, 2023. "Electrochemistry-assisted selective butadiene hydrogenation with water," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Manjeet Chhetri & Mingyu Wan & Zehua Jin & John Yeager & Case Sandor & Conner Rapp & Hui Wang & Sungsik Lee & Cameron J. Bodenschatz & Michael J. Zachman & Fanglin Che & Ming Yang, 2023. "Dual-site catalysts featuring platinum-group-metal atoms on copper shapes boost hydrocarbon formations in electrocatalytic CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Liu-Chun Wang & Li-Chan Chang & Wen-Qi Chen & Yi-Hsin Chien & Po-Ya Chang & Chih-Wen Pao & Yin-Fen Liu & Hwo-Shuenn Sheu & Wen-Pin Su & Chen-Hao Yeh & Chen-Sheng Yeh, 2022. "Atomically dispersed golds on degradable zero-valent copper nanocubes augment oxygen driven Fenton-like reaction for effective orthotopic tumor therapy," Nature Communications, Nature, vol. 13(1), pages 1-17, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms9550. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.