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Active and conductive layer stacked superlattices for highly selective CO2 electroreduction

Author

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  • Junyuan Duan

    (Huazhong University of Science and Technology)

  • Tianyang Liu

    (Nanjing Normal University)

  • Yinghe Zhao

    (Huazhong University of Science and Technology)

  • Ruoou Yang

    (Huazhong University of Science and Technology)

  • Yang Zhao

    (Huazhong University of Science and Technology)

  • Wenbin Wang

    (Huazhong University of Science and Technology)

  • Youwen Liu

    (Huazhong University of Science and Technology)

  • Huiqiao Li

    (Huazhong University of Science and Technology)

  • Yafei Li

    (Nanjing Normal University)

  • Tianyou Zhai

    (Huazhong University of Science and Technology)

Abstract

Metal oxides are archetypal CO2 reduction reaction electrocatalysts, yet inevitable self-reduction will enhance competitive hydrogen evolution and lower the CO2 electroreduction selectivity. Herein, we propose a tangible superlattice model of alternating metal oxides and selenide sublayers in which electrons are rapidly exported through the conductive metal selenide layer to protect the active oxide layer from self-reduction. Taking BiCuSeO superlattices as a proof-of-concept, a comprehensive characterization reveals that the active [Bi2O2]2+ sublayers retain oxidation states rather than their self-reduced Bi metal during CO2 electroreduction because of the rapid electron transfer through the conductive [Cu2Se2]2- sublayer. Theoretical calculations uncover the high activity over [Bi2O2]2+ sublayers due to the overlaps between the Bi p orbitals and O p orbitals in the OCHO* intermediate, thus achieving over 90% formate selectivity in a wide potential range from −0.4 to −1.1 V. This work broadens the studying and improving of the CO2 electroreduction properties of metal oxide systems.

Suggested Citation

  • Junyuan Duan & Tianyang Liu & Yinghe Zhao & Ruoou Yang & Yang Zhao & Wenbin Wang & Youwen Liu & Huiqiao Li & Yafei Li & Tianyou Zhai, 2022. "Active and conductive layer stacked superlattices for highly selective CO2 electroreduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29699-2
    DOI: 10.1038/s41467-022-29699-2
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    References listed on IDEAS

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    1. Dexin Yang & Qinggong Zhu & Chunjun Chen & Huizhen Liu & Zhimin Liu & Zhijuan Zhao & Xiaoyu Zhang & Shoujie Liu & Buxing Han, 2019. "Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    2. Na Han & Yu Wang & Hui Yang & Jun Deng & Jinghua Wu & Yafei Li & Yanguang Li, 2018. "Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    3. James Gallagher, 2019. "A framework for forming formate," Nature Energy, Nature, vol. 4(1), pages 7-7, January.
    4. Lei Fan & Chuan Xia & Peng Zhu & Yingying Lu & Haotian Wang, 2020. "Electrochemical CO2 reduction to high-concentration pure formic acid solutions in an all-solid-state reactor," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Yuvraj Y. Birdja & Elena Pérez-Gallent & Marta C. Figueiredo & Adrien J. Göttle & Federico Calle-Vallejo & Marc T. M. Koper, 2019. "Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels," Nature Energy, Nature, vol. 4(9), pages 732-745, September.
    6. Shan Gao & Yue Lin & Xingchen Jiao & Yongfu Sun & Qiquan Luo & Wenhua Zhang & Dianqi Li & Jinlong Yang & Yi Xie, 2016. "Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel," Nature, Nature, vol. 529(7584), pages 68-71, January.
    7. Qiufang Gong & Pan Ding & Mingquan Xu & Xiaorong Zhu & Maoyu Wang & Jun Deng & Qing Ma & Na Han & Yong Zhu & Jun Lu & Zhenxing Feng & Yafei Li & Wu Zhou & Yanguang Li, 2019. "Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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