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Sb2S3-templated synthesis of sulfur-doped Sb-N-C with hierarchical architecture and high metal loading for H2O2 electrosynthesis

Author

Listed:
  • Minmin Yan

    (Hunan University)

  • Zengxi Wei

    (Guangxi University)

  • Zhichao Gong

    (Hunan University)

  • Bernt Johannessen

    (Australian Synchrotron)

  • Gonglan Ye

    (Hunan University)

  • Guanchao He

    (Hunan University)

  • Jingjing Liu

    (Hunan University)

  • Shuangliang Zhao

    (Guangxi University)

  • Chunyu Cui

    (Hunan University)

  • Huilong Fei

    (Hunan University
    Hunan University)

Abstract

Selective two-electron (2e−) oxygen reduction reaction (ORR) offers great opportunities for hydrogen peroxide (H2O2) electrosynthesis and its widespread employment depends on identifying cost-effective catalysts with high activity and selectivity. Main-group metal and nitrogen coordinated carbons (M-N-Cs) are promising but remain largely underexplored due to the low metal-atom density and the lack of understanding in the structure-property correlation. Here, we report using a nanoarchitectured Sb2S3 template to synthesize high-density (10.32 wt%) antimony (Sb) single atoms on nitrogen- and sulfur-codoped carbon nanofibers (Sb-NSCF), which exhibits both high selectivity (97.2%) and mass activity (114.9 A g−1 at 0.65 V) toward the 2e− ORR in alkaline electrolyte. Further, when evaluated with a practical flow cell, Sb-NSCF shows a high production rate of 7.46 mol gcatalyst−1 h−1 with negligible loss in activity and selectivity in a 75-h continuous electrolysis. Density functional theory calculations demonstrate that the coordination configuration and the S dopants synergistically contribute to the enhanced 2e− ORR activity and selectivity of the Sb-N4 moieties.

Suggested Citation

  • Minmin Yan & Zengxi Wei & Zhichao Gong & Bernt Johannessen & Gonglan Ye & Guanchao He & Jingjing Liu & Shuangliang Zhao & Chunyu Cui & Huilong Fei, 2023. "Sb2S3-templated synthesis of sulfur-doped Sb-N-C with hierarchical architecture and high metal loading for H2O2 electrosynthesis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36078-y
    DOI: 10.1038/s41467-023-36078-y
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    Cited by:

    1. Yining Sun & Kui Fan & Jinze Li & Lei Wang & Yusen Yang & Zhenhua Li & Mingfei Shao & Xue Duan, 2024. "Boosting electrochemical oxygen reduction to hydrogen peroxide coupled with organic oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Xiao Zhou & Yuan Min & Changming Zhao & Cai Chen & Ming-Kun Ke & Shi-Lin Xu & Jie-Jie Chen & Yuen Wu & Han-Qing Yu, 2024. "Constructing sulfur and oxygen super-coordinated main-group electrocatalysts for selective and cumulative H2O2 production," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Hongni Chen & Chao Wang & Han Wu & Lili Li & Yali Xing & Chuanhui Zhang & Xiaojing Long, 2024. "Host-guest-induced electronic state triggers two-electron oxygen reduction electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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