IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v11y2020i1d10.1038_s41467-020-14565-w.html
   My bibliography  Save this article

Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction

Author

Listed:
  • Shuai Liu

    (University of Science and Technology of China)

  • Zedong Li

    (University of Science and Technology of China)

  • Changlai Wang

    (University of Science and Technology of China)

  • Weiwei Tao

    (Boston University)

  • Minxue Huang

    (University of Science and Technology of China)

  • Ming Zuo

    (University of Science and Technology of China)

  • Yang Yang

    (University of Science and Technology of China)

  • Kang Yang

    (University of Science and Technology of China)

  • Lijuan Zhang

    (Shanghai Institute of Applied Physics)

  • Shi Chen

    (University of Science and Technology of China)

  • Pengping Xu

    (University of Science and Technology of China)

  • Qianwang Chen

    (University of Science and Technology of China
    Academy of Sciences)

Abstract

It is known that the main-group metals and their related materials show poor catalytic activity due to a broadened single resonance derived from the interaction of valence orbitals of adsorbates with the broad sp-band of main-group metals. However, Mg cofactors existing in enzymes are extremely active in biochemical reactions. Our density function theory calculations reveal that the catalytic activity of the main-group metals (Mg, Al and Ca) in oxygen reduction reaction is severely hampered by the tight-bonding of active centers with hydroxyl group intermediate, while the Mg atom coordinated to two nitrogen atoms has the near-optimal adsorption strength with intermediate oxygen species by the rise of p-band center position compared to other coordination environments. We experimentally demonstrate that the atomically dispersed Mg cofactors incorporated within graphene framework exhibits a strikingly high half-wave potential of 910 mV in alkaline media, turning a s/p-band metal into a highly active electrocatalyst.

Suggested Citation

  • Shuai Liu & Zedong Li & Changlai Wang & Weiwei Tao & Minxue Huang & Ming Zuo & Yang Yang & Kang Yang & Lijuan Zhang & Shi Chen & Pengping Xu & Qianwang Chen, 2020. "Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-14565-w
    DOI: 10.1038/s41467-020-14565-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-020-14565-w
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-020-14565-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Minmin Yan & Zengxi Wei & Zhichao Gong & Bernt Johannessen & Gonglan Ye & Guanchao He & Jingjing Liu & Shuangliang Zhao & Chunyu Cui & Huilong Fei, 2023. "Sb2S3-templated synthesis of sulfur-doped Sb-N-C with hierarchical architecture and high metal loading for H2O2 electrosynthesis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Xiao Zhou & Yuan Min & Changming Zhao & Cai Chen & Ming-Kun Ke & Shi-Lin Xu & Jie-Jie Chen & Yuen Wu & Han-Qing Yu, 2024. "Constructing sulfur and oxygen super-coordinated main-group electrocatalysts for selective and cumulative H2O2 production," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Fenghui Ye & Shishi Zhang & Qingqing Cheng & Yongde Long & Dong Liu & Rajib Paul & Yunming Fang & Yaqiong Su & Liangti Qu & Liming Dai & Chuangang Hu, 2023. "The role of oxygen-vacancy in bifunctional indium oxyhydroxide catalysts for electrochemical coupling of biomass valorization with CO2 conversion," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-14565-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.