IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-35339-6.html
   My bibliography  Save this article

Sliding induced multiple polarization states in two-dimensional ferroelectrics

Author

Listed:
  • Peng Meng

    (University of Electronic Science and Technology of China
    University of Electronic Science and Technology of China)

  • Yaze Wu

    (Agency for Science, Technology and Research (A*STAR))

  • Renji Bian

    (University of Electronic Science and Technology of China)

  • Er Pan

    (University of Electronic Science and Technology of China)

  • Biao Dong

    (Nanjing University)

  • Xiaoxu Zhao

    (Peking University)

  • Jiangang Chen

    (University of Electronic Science and Technology of China)

  • Lishu Wu

    (Nanyang Technological University)

  • Yuqi Sun

    (University of Electronic Science and Technology of China)

  • Qundong Fu

    (Nanyang Technological University)

  • Qing Liu

    (University of Electronic Science and Technology of China)

  • Dong Shi

    (University of Electronic Science and Technology of China)

  • Qi Zhang

    (Nanjing University)

  • Yong-Wei Zhang

    (Agency for Science, Technology and Research (A*STAR))

  • Zheng Liu

    (Nanyang Technological University
    CINTRA CNRS/NTU/THALES, UMI 3288, Research Techno Plaza
    National University of Singapore)

  • Fucai Liu

    (University of Electronic Science and Technology of China
    University of Electronic Science and Technology of China)

Abstract

When the atomic layers in a non-centrosymmetric van der Waals structure slide against each other, the interfacial charge transfer results in a reversal of the structure’s spontaneous polarization. This phenomenon is known as sliding ferroelectricity and it is markedly different from conventional ferroelectric switching mechanisms relying on ion displacement. Here, we present layer dependence as a new dimension to control sliding ferroelectricity. By fabricating 3 R MoS2 of various thicknesses into dual-gate field-effect transistors, we obtain anomalous intermediate polarization states in multilayer (more than bilayer) 3 R MoS2. Using results from ab initio density functional theory calculations, we propose a generalized model to describe the ferroelectric switching process in multilayer 3 R MoS2 and to explain the formation of these intermediate polarization states. This work reveals the critical roles layer number and interlayer dipole coupling play in sliding ferroelectricity and presents a new strategy for the design of novel sliding ferroelectric devices.

Suggested Citation

  • Peng Meng & Yaze Wu & Renji Bian & Er Pan & Biao Dong & Xiaoxu Zhao & Jiangang Chen & Lishu Wu & Yuqi Sun & Qundong Fu & Qing Liu & Dong Shi & Qi Zhang & Yong-Wei Zhang & Zheng Liu & Fucai Liu, 2022. "Sliding induced multiple polarization states in two-dimensional ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35339-6
    DOI: 10.1038/s41467-022-35339-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-35339-6
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-35339-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Shuoguo Yuan & Xin Luo & Hung Lit Chan & Chengcheng Xiao & Yawei Dai & Maohai Xie & Jianhua Hao, 2019. "Room-temperature ferroelectricity in MoTe2 down to the atomic monolayer limit," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    2. C. R. Woods & P. Ares & H. Nevison-Andrews & M. J. Holwill & R. Fabregas & F. Guinea & A. K. Geim & K. S. Novoselov & N. R. Walet & L. Fumagalli, 2021. "Charge-polarized interfacial superlattices in marginally twisted hexagonal boron nitride," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    3. Swarup Deb & Wei Cao & Noam Raab & Kenji Watanabe & Takashi Taniguchi & Moshe Goldstein & Leeor Kronik & Michael Urbakh & Oded Hod & Moshe Ben Shalom, 2022. "Cumulative polarization in conductive interfacial ferroelectrics," Nature, Nature, vol. 612(7940), pages 465-469, December.
    4. A. K. Geim & I. V. Grigorieva, 2013. "Van der Waals heterostructures," Nature, Nature, vol. 499(7459), pages 419-425, July.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Dongyang Yang & Jing Liang & Jingda Wu & Yunhuan Xiao & Jerry I. Dadap & Kenji Watanabe & Takashi Taniguchi & Ziliang Ye, 2024. "Non-volatile electrical polarization switching via domain wall release in 3R-MoS2 bilayer," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. James G. McHugh & Xue Li & Isaac Soltero & Vladimir I. Fal’ko, 2024. "Two-dimensional electrons at mirror and twistronic twin boundaries in van der Waals ferroelectrics," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    3. Tao Li & Yongyi Wu & Guoliang Yu & Shengxian Li & Yifeng Ren & Yadong Liu & Jiarui Liu & Hao Feng & Yu Deng & Mingxing Chen & Zhenyu Zhang & Tai Min, 2024. "Realization of sextuple polarization states and interstate switching in antiferroelectric CuInP2S6," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Zhouxiaosong Zeng & Zhiqiang Tian & Yufan Wang & Cuihuan Ge & Fabian Strauß & Kai Braun & Patrick Michel & Lanyu Huang & Guixian Liu & Dong Li & Marcus Scheele & Mingxing Chen & Anlian Pan & Xiao Wang, 2024. "Dual polarization-enabled ultrafast bulk photovoltaic response in van der Waals heterostructures," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Luying Song & Ying Zhao & Bingqian Xu & Ruofan Du & Hui Li & Wang Feng & Junbo Yang & Xiaohui Li & Zijia Liu & Xia Wen & Yanan Peng & Yuzhu Wang & Hang Sun & Ling Huang & Yulin Jiang & Yao Cai & Xue J, 2024. "Robust multiferroic in interfacial modulation synthesized wafer-scale one-unit-cell of chromium sulfide," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Yue Niu & Lei Li & Zhiying Qi & Hein Htet Aung & Xinyi Han & Reshef Tenne & Yugui Yao & Alla Zak & Yao Guo, 2023. "0D van der Waals interfacial ferroelectricity," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Ming Lv & Jiulong Wang & Ming Tian & Neng Wan & Wenyi Tong & Chungang Duan & Jiamin Xue, 2024. "Multiresistance states in ferro- and antiferroelectric trilayer boron nitride," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    8. Weijia Liu & Zhijian Du & Zhongyi Duan & La Li & Guozhen Shen, 2024. "Neuroprosthetic contact lens enabled sensorimotor system for point-of-care monitoring and feedback of intraocular pressure," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    9. Wenhui Li & Xuanlin Zhang & Jia Yang & Song Zhou & Chuangye Song & Peng Cheng & Yi-Qi Zhang & Baojie Feng & Zhenxing Wang & Yunhao Lu & Kehui Wu & Lan Chen, 2023. "Emergence of ferroelectricity in a nonferroelectric monolayer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Shuai Zhang & Yang Liu & Zhiyuan Sun & Xinzhong Chen & Baichang Li & S. L. Moore & Song Liu & Zhiying Wang & S. E. Rossi & Ran Jing & Jordan Fonseca & Birui Yang & Yinming Shao & Chun-Ying Huang & Tak, 2023. "Visualizing moiré ferroelectricity via plasmons and nano-photocurrent in graphene/twisted-WSe2 structures," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    11. Swarup Deb & Johannes Krause & Paulo E. Faria Junior & Michael Andreas Kempf & Rico Schwartz & Kenji Watanabe & Takashi Taniguchi & Jaroslav Fabian & Tobias Korn, 2024. "Excitonic signatures of ferroelectric order in parallel-stacked MoS2," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    12. Fengrui Sui & Haoyang Li & Ruijuan Qi & Min Jin & Zhiwei Lv & Menghao Wu & Xuechao Liu & Yufan Zheng & Beituo Liu & Rui Ge & Yu-Ning Wu & Rong Huang & Fangyu Yue & Junhao Chu & Chungang Duan, 2024. "Atomic-level polarization reversal in sliding ferroelectric semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yunze Gao & Astrid Weston & Vladimir Enaldiev & Xiao Li & Wendong Wang & James E. Nunn & Isaac Soltero & Eli G. Castanon & Amy Carl & Hugo Latour & Alex Summerfield & Matthew Hamer & James Howarth & N, 2024. "Tunnel junctions based on interfacial two dimensional ferroelectrics," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    2. Dongyang Yang & Jing Liang & Jingda Wu & Yunhuan Xiao & Jerry I. Dadap & Kenji Watanabe & Takashi Taniguchi & Ziliang Ye, 2024. "Non-volatile electrical polarization switching via domain wall release in 3R-MoS2 bilayer," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Yue Niu & Lei Li & Zhiying Qi & Hein Htet Aung & Xinyi Han & Reshef Tenne & Yugui Yao & Alla Zak & Yao Guo, 2023. "0D van der Waals interfacial ferroelectricity," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Shuai Zhang & Yang Liu & Zhiyuan Sun & Xinzhong Chen & Baichang Li & S. L. Moore & Song Liu & Zhiying Wang & S. E. Rossi & Ran Jing & Jordan Fonseca & Birui Yang & Yinming Shao & Chun-Ying Huang & Tak, 2023. "Visualizing moiré ferroelectricity via plasmons and nano-photocurrent in graphene/twisted-WSe2 structures," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    5. Swarup Deb & Johannes Krause & Paulo E. Faria Junior & Michael Andreas Kempf & Rico Schwartz & Kenji Watanabe & Takashi Taniguchi & Jaroslav Fabian & Tobias Korn, 2024. "Excitonic signatures of ferroelectric order in parallel-stacked MoS2," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    6. Ming Lv & Jiulong Wang & Ming Tian & Neng Wan & Wenyi Tong & Chungang Duan & Jiamin Xue, 2024. "Multiresistance states in ferro- and antiferroelectric trilayer boron nitride," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    7. Ruirui Niu & Zhuoxian Li & Xiangyan Han & Zhuangzhuang Qu & Dongdong Ding & Zhiyu Wang & Qianling Liu & Tianyao Liu & Chunrui Han & Kenji Watanabe & Takashi Taniguchi & Menghao Wu & Qi Ren & Xueyun Wa, 2022. "Giant ferroelectric polarization in a bilayer graphene heterostructure," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Pandey, Mayank & Deshmukh, Kalim & Raman, Akhila & Asok, Aparna & Appukuttan, Saritha & Suman, G.R., 2024. "Prospects of MXene and graphene for energy storage and conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    9. Benjamin Carey & Nils Kolja Wessling & Paul Steeger & Robert Schmidt & Steffen Michaelis de Vasconcellos & Rudolf Bratschitsch & Ashish Arora, 2024. "Giant Faraday rotation in atomically thin semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    10. Eli Gerber & Steven B. Torrisi & Sara Shabani & Eric Seewald & Jordan Pack & Jennifer E. Hoffman & Cory R. Dean & Abhay N. Pasupathy & Eun-Ah Kim, 2023. "High-throughput ab initio design of atomic interfaces using InterMatch," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    11. Bohayra Mortazavi & Timon Rabczuk, 2018. "Boron Monochalcogenides; Stable and Strong Two-Dimensional Wide Band-Gap Semiconductors," Energies, MDPI, vol. 11(6), pages 1-10, June.
    12. Ruofan Du & Yuzhu Wang & Mo Cheng & Peng Wang & Hui Li & Wang Feng & Luying Song & Jianping Shi & Jun He, 2022. "Two-dimensional multiferroic material of metallic p-doped SnSe," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Yeonghun Lee & Yaoqiao Hu & Xiuyao Lang & Dongwook Kim & Kejun Li & Yuan Ping & Kai-Mei C. Fu & Kyeongjae Cho, 2022. "Spin-defect qubits in two-dimensional transition metal dichalcogenides operating at telecom wavelengths," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Nikhil Mathur & Arunabh Mukherjee & Xingyu Gao & Jialun Luo & Brendan A. McCullian & Tongcang Li & A. Nick Vamivakas & Gregory D. Fuchs, 2022. "Excited-state spin-resonance spectroscopy of V $${}_{{{{{{{{\rm{B}}}}}}}}}^{-}$$ B − defect centers in hexagonal boron nitride," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    15. Md Gius Uddin & Susobhan Das & Abde Mayeen Shafi & Lei Wang & Xiaoqi Cui & Fedor Nigmatulin & Faisal Ahmed & Andreas C. Liapis & Weiwei Cai & Zongyin Yang & Harri Lipsanen & Tawfique Hasan & Hoon Hahn, 2024. "Broadband miniaturized spectrometers with a van der Waals tunnel diode," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    16. Nathan Ronceray & Massimo Spina & Vanessa Hui Yin Chou & Chwee Teck Lim & Andre K. Geim & Slaven Garaj, 2024. "Elastocapillarity-driven 2D nano-switches enable zeptoliter-scale liquid encapsulation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    17. Guanghui Cheng & Mohammad Mushfiqur Rahman & Zhiping He & Andres Llacsahuanga Allcca & Avinash Rustagi & Kirstine Aggerbeck Stampe & Yanglin Zhu & Shaohua Yan & Shangjie Tian & Zhiqiang Mao & Hechang , 2022. "Emergence of electric-field-tunable interfacial ferromagnetism in 2D antiferromagnet heterostructures," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    18. Weng Fu Io & Sin -Yi Pang & Lok Wing Wong & Yuqian Zhao & Ran Ding & Jianfeng Mao & Yifei Zhao & Feng Guo & Shuoguo Yuan & Jiong Zhao & Jiabao Yi & Jianhua Hao, 2023. "Direct observation of intrinsic room-temperature ferroelectricity in 2D layered CuCrP2S6," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    19. Wei Liu & Viktor Ivády & Zhi-Peng Li & Yuan-Ze Yang & Shang Yu & Yu Meng & Zhao-An Wang & Nai-Jie Guo & Fei-Fei Yan & Qiang Li & Jun-Feng Wang & Jin-Shi Xu & Xiao Liu & Zong-Quan Zhou & Yang Dong & Xi, 2022. "Coherent dynamics of multi-spin V $${}_{{{{{{{{\rm{B}}}}}}}}}^{-}$$ B − center in hexagonal boron nitride," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    20. Georgy A. Ermolaev & Kirill V. Voronin & Adilet N. Toksumakov & Dmitriy V. Grudinin & Ilia M. Fradkin & Arslan Mazitov & Aleksandr S. Slavich & Mikhail K. Tatmyshevskiy & Dmitry I. Yakubovsky & Valent, 2024. "Wandering principal optical axes in van der Waals triclinic materials," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35339-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.