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Excitonic signatures of ferroelectric order in parallel-stacked MoS2

Author

Listed:
  • Swarup Deb

    (University of Rostock)

  • Johannes Krause

    (University of Rostock)

  • Paulo E. Faria Junior

    (University of Regensburg)

  • Michael Andreas Kempf

    (University of Rostock)

  • Rico Schwartz

    (University of Rostock)

  • Kenji Watanabe

    (NIMS)

  • Takashi Taniguchi

    (NIMS)

  • Jaroslav Fabian

    (University of Regensburg)

  • Tobias Korn

    (University of Rostock)

Abstract

Interfacial ferroelectricity, prevalent in various parallel-stacked layered materials, allows switching of out-of-plane ferroelectric order by in-plane sliding of adjacent layers. Its resilience against doping potentially enables next-generation storage and logic devices. However, studies have been limited to indirect sensing or visualization of ferroelectricity. For transition metal dichalcogenides, there is little knowledge about the influence of ferroelectric order on their intrinsic valley and excitonic properties. Here, we report direct probing of ferroelectricity in few-layer 3R-MoS2 using reflectance contrast spectroscopy. Contrary to a simple electrostatic perception, layer-hybridized excitons with out-of-plane electric dipole moment remain decoupled from ferroelectric ordering, while intralayer excitons with in-plane dipole orientation are sensitive to it. Ab initio calculations identify stacking-specific interlayer hybridization leading to this asymmetric response. Exploiting this sensitivity, we demonstrate optical readout and control of multi-state polarization with hysteretic switching in a field-effect device. Time-resolved Kerr ellipticity reveals direct correspondence between spin-valley dynamics and stacking order.

Suggested Citation

  • Swarup Deb & Johannes Krause & Paulo E. Faria Junior & Michael Andreas Kempf & Rico Schwartz & Kenji Watanabe & Takashi Taniguchi & Jaroslav Fabian & Tobias Korn, 2024. "Excitonic signatures of ferroelectric order in parallel-stacked MoS2," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52011-3
    DOI: 10.1038/s41467-024-52011-3
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