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Realization of sextuple polarization states and interstate switching in antiferroelectric CuInP2S6

Author

Listed:
  • Tao Li

    (Xi’an Jiaotong University)

  • Yongyi Wu

    (Xi’an Jiaotong University)

  • Guoliang Yu

    (Hunan Normal University)

  • Shengxian Li

    (Hunan Normal University)

  • Yifeng Ren

    (Nanjing University)

  • Yadong Liu

    (Xi’an Jiaotong University)

  • Jiarui Liu

    (Xi’an Jiaotong University)

  • Hao Feng

    (Xi’an Jiaotong University)

  • Yu Deng

    (Nanjing University)

  • Mingxing Chen

    (Hunan Normal University
    Central South University)

  • Zhenyu Zhang

    (University of Science and Technology of China)

  • Tai Min

    (Xi’an Jiaotong University)

Abstract

Realization of higher-order multistates with mutual interstate switching in ferroelectric materials is a perpetual drive for high-density storage devices and beyond-Moore technologies. Here we demonstrate experimentally that antiferroelectric van der Waals CuInP2S6 films can be controllably stabilized into double, quadruple, and sextuple polarization states, and a system harboring polarization order of six is also reversibly tunable into order of four or two. Furthermore, for a given polarization order, mutual interstate switching can be achieved via moderate electric field modulation. First-principles studies of CuInP2S6 multilayers help to reveal that the double, quadruple, and sextuple states are attributable to the existence of respective single, double, and triple ferroelectric domains with antiferroelectric interdomain coupling and Cu ion migration. These findings offer appealing platforms for developing multistate ferroelectric devices, while the underlining mechanism is transformative to other non-volatile material systems.

Suggested Citation

  • Tao Li & Yongyi Wu & Guoliang Yu & Shengxian Li & Yifeng Ren & Yadong Liu & Jiarui Liu & Hao Feng & Yu Deng & Mingxing Chen & Zhenyu Zhang & Tai Min, 2024. "Realization of sextuple polarization states and interstate switching in antiferroelectric CuInP2S6," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46891-8
    DOI: 10.1038/s41467-024-46891-8
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