IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-49760-6.html
   My bibliography  Save this article

Dual polarization-enabled ultrafast bulk photovoltaic response in van der Waals heterostructures

Author

Listed:
  • Zhouxiaosong Zeng

    (Hunan University
    Hunan University
    University of Tübingen)

  • Zhiqiang Tian

    (Hunan Normal University)

  • Yufan Wang

    (Hunan University)

  • Cuihuan Ge

    (Hunan University)

  • Fabian Strauß

    (University of Tübingen)

  • Kai Braun

    (University of Tübingen)

  • Patrick Michel

    (University of Tübingen)

  • Lanyu Huang

    (Hunan University)

  • Guixian Liu

    (Hunan University)

  • Dong Li

    (Hunan University)

  • Marcus Scheele

    (University of Tübingen)

  • Mingxing Chen

    (Hunan Normal University
    Central South University)

  • Anlian Pan

    (Hunan University
    Hunan Normal University)

  • Xiao Wang

    (Hunan University
    Hunan University)

Abstract

The bulk photovoltaic effect (BPVE) originating from spontaneous charge polarizations can reach high conversion efficiency exceeding the Shockley-Queisser limit. Emerging van der Waals (vdW) heterostructures provide the ideal platform for BPVE due to interfacial interactions naturally breaking the crystal symmetries of the individual constituents and thus inducing charge polarizations. Here, we show an approach to obtain ultrafast BPVE by taking advantage of dual interfacial polarizations in vdW heterostructures. While the in-plane polarization gives rise to the BPVE in the overlayer, the charge carrier transfer assisted by the out-of-plane polarization further accelerates the interlayer electronic transport and enhances the BPVE. We illustrate the concept in MoS2/black phosphorus heterostructures, where the experimentally observed intrinsic BPVE response time achieves 26 ps, orders of magnitude faster than that of conventional non-centrosymmetric materials. Moreover, the heterostructure device possesses an extrinsic response time of approximately 2.2 ns and a bulk photovoltaic coefficient of 0.6 V−1, which is among the highest values for vdW BPV devices reported so far. Our study thus points to an effective way of designing ultrafast BPVE for high-speed photodetection.

Suggested Citation

  • Zhouxiaosong Zeng & Zhiqiang Tian & Yufan Wang & Cuihuan Ge & Fabian Strauß & Kai Braun & Patrick Michel & Lanyu Huang & Guixian Liu & Dong Li & Marcus Scheele & Mingxing Chen & Anlian Pan & Xiao Wang, 2024. "Dual polarization-enabled ultrafast bulk photovoltaic response in van der Waals heterostructures," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49760-6
    DOI: 10.1038/s41467-024-49760-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-49760-6
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-49760-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. M. Nakamura & S. Horiuchi & F. Kagawa & N. Ogawa & T. Kurumaji & Y. Tokura & M. Kawasaki, 2017. "Shift current photovoltaic effect in a ferroelectric charge-transfer complex," Nature Communications, Nature, vol. 8(1), pages 1-6, December.
    2. Shuoguo Yuan & Xin Luo & Hung Lit Chan & Chengcheng Xiao & Yawei Dai & Maohai Xie & Jianhua Hao, 2019. "Room-temperature ferroelectricity in MoTe2 down to the atomic monolayer limit," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    3. Wenhui Li & Xuanlin Zhang & Jia Yang & Song Zhou & Chuangye Song & Peng Cheng & Yi-Qi Zhang & Baojie Feng & Zhenxing Wang & Yunhao Lu & Kehui Wu & Lan Chen, 2023. "Emergence of ferroelectricity in a nonferroelectric monolayer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Ilya Grinberg & D. Vincent West & Maria Torres & Gaoyang Gou & David M. Stein & Liyan Wu & Guannan Chen & Eric M. Gallo & Andrew R. Akbashev & Peter K. Davies & Jonathan E. Spanier & Andrew M. Rappe, 2013. "Perovskite oxides for visible-light-absorbing ferroelectric and photovoltaic materials," Nature, Nature, vol. 503(7477), pages 509-512, November.
    5. Y. J. Zhang & T. Ideue & M. Onga & F. Qin & R. Suzuki & A. Zak & R. Tenne & J. H. Smet & Y. Iwasa, 2019. "Enhanced intrinsic photovoltaic effect in tungsten disulfide nanotubes," Nature, Nature, vol. 570(7761), pages 349-353, June.
    6. Yongheng Zhou & Xin Zhou & Xiang-Long Yu & Zihan Liang & Xiaoxu Zhao & Taihong Wang & Jinshui Miao & Xiaolong Chen, 2024. "Giant intrinsic photovoltaic effect in one-dimensional van der Waals grain boundaries," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    7. Peng Meng & Yaze Wu & Renji Bian & Er Pan & Biao Dong & Xiaoxu Zhao & Jiangang Chen & Lishu Wu & Yuqi Sun & Qundong Fu & Qing Liu & Dong Shi & Qi Zhang & Yong-Wei Zhang & Zheng Liu & Fucai Liu, 2022. "Sliding induced multiple polarization states in two-dimensional ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    8. Yue Li & Jun Fu & Xiaoyu Mao & Chen Chen & Heng Liu & Ming Gong & Hualing Zeng, 2021. "Enhanced bulk photovoltaic effect in two-dimensional ferroelectric CuInP2S6," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    9. Zihan Liang & Xin Zhou & Le Zhang & Xiang-Long Yu & Yan Lv & Xuefen Song & Yongheng Zhou & Han Wang & Shuo Wang & Taihong Wang & Perry Ping Shum & Qian He & Yanjun Liu & Chao Zhu & Lin Wang & Xiaolong, 2023. "Strong bulk photovoltaic effect in engineered edge-embedded van der Waals structures," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Lukas Braun & Gregor Mussler & Andrzej Hruban & Marcin Konczykowski & Thomas Schumann & Martin Wolf & Markus Münzenberg & Luca Perfetti & Tobias Kampfrath, 2016. "Ultrafast photocurrents at the surface of the three-dimensional topological insulator Bi2Se3," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    11. Shiguo Han & Maofan Li & Yi Liu & Wuqian Guo & Mao-Chun Hong & Zhihua Sun & Junhua Luo, 2021. "Tailoring of a visible-light-absorbing biaxial ferroelectric towards broadband self-driven photodetection," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yongheng Zhou & Xin Zhou & Xiang-Long Yu & Zihan Liang & Xiaoxu Zhao & Taihong Wang & Jinshui Miao & Xiaolong Chen, 2024. "Giant intrinsic photovoltaic effect in one-dimensional van der Waals grain boundaries," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    2. Yue Niu & Lei Li & Zhiying Qi & Hein Htet Aung & Xinyi Han & Reshef Tenne & Yugui Yao & Alla Zak & Yao Guo, 2023. "0D van der Waals interfacial ferroelectricity," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Xiaoyi Xie & Pengliang Leng & Zhenyu Ding & Jinshan Yang & Jingyi Yan & Junchen Zhou & Zihan Li & Linfeng Ai & Xiangyu Cao & Zehao Jia & Yuda Zhang & Minhao Zhao & Wenguang Zhu & Yang Gao & Shaoming D, 2024. "Surface photogalvanic effect in Ag2Te," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    4. Luying Song & Ying Zhao & Bingqian Xu & Ruofan Du & Hui Li & Wang Feng & Junbo Yang & Xiaohui Li & Zijia Liu & Xia Wen & Yanan Peng & Yuzhu Wang & Hang Sun & Ling Huang & Yulin Jiang & Yao Cai & Xue J, 2024. "Robust multiferroic in interfacial modulation synthesized wafer-scale one-unit-cell of chromium sulfide," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Zhenyu Sun & Yueqi Su & Aomiao Zhi & Zhicheng Gao & Xu Han & Kang Wu & Lihong Bao & Yuan Huang & Youguo Shi & Xuedong Bai & Peng Cheng & Lan Chen & Kehui Wu & Xuezeng Tian & Changzheng Wu & Baojie Fen, 2024. "Evidence for multiferroicity in single-layer CuCrSe2," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    6. Fengrui Sui & Haoyang Li & Ruijuan Qi & Min Jin & Zhiwei Lv & Menghao Wu & Xuechao Liu & Yufan Zheng & Beituo Liu & Rui Ge & Yu-Ning Wu & Rong Huang & Fangyu Yue & Junhao Chu & Chungang Duan, 2024. "Atomic-level polarization reversal in sliding ferroelectric semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    7. Jinhyoung Lee & Gunhoo Woo & Jinill Cho & Sihoon Son & Hyelim Shin & Hyunho Seok & Min-Jae Kim & Eungchul Kim & Ziyang Wang & Boseok Kang & Won-Jun Jang & Taesung Kim, 2024. "Free-standing two-dimensional ferro-ionic memristor," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Longjun Xiang & Hao Jin & Jian Wang, 2024. "Quantifying the photocurrent fluctuation in quantum materials by shot noise," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    9. Yi Hu & Lukas Rogée & Weizhen Wang & Lyuchao Zhuang & Fangyi Shi & Hui Dong & Songhua Cai & Beng Kang Tay & Shu Ping Lau, 2023. "Extendable piezo/ferroelectricity in nonstoichiometric 2D transition metal dichalcogenides," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Wenhui Li & Xuanlin Zhang & Jia Yang & Song Zhou & Chuangye Song & Peng Cheng & Yi-Qi Zhang & Baojie Feng & Zhenxing Wang & Yunhao Lu & Kehui Wu & Lan Chen, 2023. "Emergence of ferroelectricity in a nonferroelectric monolayer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    11. James G. McHugh & Xue Li & Isaac Soltero & Vladimir I. Fal’ko, 2024. "Two-dimensional electrons at mirror and twistronic twin boundaries in van der Waals ferroelectrics," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    12. Ruofan Du & Yuzhu Wang & Mo Cheng & Peng Wang & Hui Li & Wang Feng & Luying Song & Jianping Shi & Jun He, 2022. "Two-dimensional multiferroic material of metallic p-doped SnSe," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Dongyang Yang & Jing Liang & Jingda Wu & Yunhuan Xiao & Jerry I. Dadap & Kenji Watanabe & Takashi Taniguchi & Ziliang Ye, 2024. "Non-volatile electrical polarization switching via domain wall release in 3R-MoS2 bilayer," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    14. Weijia Liu & Zhijian Du & Zhongyi Duan & La Li & Guozhen Shen, 2024. "Neuroprosthetic contact lens enabled sensorimotor system for point-of-care monitoring and feedback of intraocular pressure," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    15. Weng Fu Io & Sin -Yi Pang & Lok Wing Wong & Yuqian Zhao & Ran Ding & Jianfeng Mao & Yifei Zhao & Feng Guo & Shuoguo Yuan & Jiong Zhao & Jiabao Yi & Jianhua Hao, 2023. "Direct observation of intrinsic room-temperature ferroelectricity in 2D layered CuCrP2S6," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Lin Zhou & Yihua Wu & Xiaoning Liu & Jiajia Quan & Zhijie Bi & Feng Yuan & Yong Wan, 2023. "Simulation of Boosting Efficiency of GaAs Absorption Layers with KNbO 3 Scatterers for Solar Cells," Energies, MDPI, vol. 16(7), pages 1-17, March.
    17. Yunze Gao & Astrid Weston & Vladimir Enaldiev & Xiao Li & Wendong Wang & James E. Nunn & Isaac Soltero & Eli G. Castanon & Amy Carl & Hugo Latour & Alex Summerfield & Matthew Hamer & James Howarth & N, 2024. "Tunnel junctions based on interfacial two dimensional ferroelectrics," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    18. Makiko Ogino & Yoshihiro Okamura & Kosuke Fujiwara & Takahiro Morimoto & Naoto Nagaosa & Yoshio Kaneko & Yoshinori Tokura & Youtarou Takahashi, 2024. "Terahertz photon to dc current conversion via magnetic excitations of multiferroics," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    19. Wei Lu & Zipu Fan & Yunkun Yang & Junchao Ma & Jiawei Lai & Xiaoming Song & Xiao Zhuo & Zhaoran Xu & Jing Liu & Xiaodong Hu & Shuyun Zhou & Faxian Xiu & Jinluo Cheng & Dong Sun, 2022. "Ultrafast photothermoelectric effect in Dirac semimetallic Cd3As2 revealed by terahertz emission," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    20. Zihan Liang & Xin Zhou & Le Zhang & Xiang-Long Yu & Yan Lv & Xuefen Song & Yongheng Zhou & Han Wang & Shuo Wang & Taihong Wang & Perry Ping Shum & Qian He & Yanjun Liu & Chao Zhu & Lin Wang & Xiaolong, 2023. "Strong bulk photovoltaic effect in engineered edge-embedded van der Waals structures," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49760-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.