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Synergistic passivation and stepped-dimensional perovskite analogs enable high-efficiency near-infrared light-emitting diodes

Author

Listed:
  • Yongjie Liu

    (Wuhan University)

  • Chen Tao

    (Wuhan University)

  • Yu Cao

    (Nanjing Tech University (Nanjing Tech)
    Northwestern Polytechnical University (NPU))

  • Liangyan Chen

    (Wuhan Polytechnic University)

  • Shuxin Wang

    (Wuhan University)

  • Pei Li

    (Wuhan University)

  • Cheng Wang

    (Wuhan University)

  • Chenwei Liu

    (Wuhan University)

  • Feihong Ye

    (Wuhan University)

  • Shengyong Hu

    (Nanjing University)

  • Meng Xiao

    (Wuhan University)

  • Zheng Gao

    (Wuhan University)

  • Pengbing Gui

    (Wuhan University)

  • Fang Yao

    (Wuhan University)

  • Kailian Dong

    (Wuhan University)

  • Jiashuai Li

    (Wuhan University)

  • Xuzhi Hu

    (Wuhan University)

  • Hengjiang Cong

    (Wuhan University)

  • Shuangfeng Jia

    (Wuhan University)

  • Ti Wang

    (Wuhan University)

  • Jianbo Wang

    (Wuhan University)

  • Gang Li

    (The Hong Kong Polytechnic University)

  • Wei Huang

    (Nanjing Tech University (Nanjing Tech)
    Northwestern Polytechnical University (NPU))

  • Weijun Ke

    (Wuhan University)

  • Jianpu Wang

    (Nanjing Tech University (Nanjing Tech))

  • Guojia Fang

    (Wuhan University)

Abstract

Formamidinium lead iodide (FAPbI3) perovskites are promising emitters for near-infrared light-emitting diodes. However, their performance is still limited by defect-assisted nonradiative recombination and band offset-induced carrier aggregation at the interface. Herein, we introduce a couple of cadmium salts with acetate or halide anion into the FAPbI3 perovskite precursors to synergistically passivate the material defects and optimize the device band structure. Particularly, the perovskite analogs, containing zero-dimensional formamidinium cadmium iodide, one-dimensional δ-FAPbI3, two-dimensional FA2FAn-1PbnI3n+1, and three-dimensional α-FAPbI3, can be obtained in one pot and play a pivotal and positive role in energy transfer in the formamidinium iodide-rich lead-based perovskite films. As a result, the near-infrared FAPbI3-based devices deliver a maximum external quantum efficiency of 24.1% together with substantially improved operational stability. Combining our findings on defect passivation and energy transfer, we also achieve near-infrared light communication with device twins of light emitting and unprecedented self-driven detection.

Suggested Citation

  • Yongjie Liu & Chen Tao & Yu Cao & Liangyan Chen & Shuxin Wang & Pei Li & Cheng Wang & Chenwei Liu & Feihong Ye & Shengyong Hu & Meng Xiao & Zheng Gao & Pengbing Gui & Fang Yao & Kailian Dong & Jiashua, 2022. "Synergistic passivation and stepped-dimensional perovskite analogs enable high-efficiency near-infrared light-emitting diodes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35218-0
    DOI: 10.1038/s41467-022-35218-0
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    as
    1. David J. Keeble & Julia Wiktor & Sandeep K. Pathak & Laurie J. Phillips & Marcel Dickmann & Ken Durose & Henry J. Snaith & Werner Egger, 2021. "Identification of lead vacancy defects in lead halide perovskites," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    2. Zhongcheng Yuan & Yanfeng Miao & Zhangjun Hu & Weidong Xu & Chaoyang Kuang & Kang Pan & Pinlei Liu & Jingya Lai & Baoquan Sun & Jianpu Wang & Sai Bai & Feng Gao, 2019. "Unveiling the synergistic effect of precursor stoichiometry and interfacial reactions for perovskite light-emitting diodes," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    3. Hobeom Kim & Joo Sung Kim & Jung-Min Heo & Mingyuan Pei & In-Hyeok Park & Zhun Liu & Hyung Joong Yun & Min-Ho Park & Su-Hun Jeong & Young-Hoon Kim & Jin-Woo Park & Emad Oveisi & Satyawan Nagane & Adit, 2020. "Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot," Nature Communications, Nature, vol. 11(1), pages 1-13, December.
    4. Changjiu Sun & Yuanzhi Jiang & Minghuan Cui & Lu Qiao & Junli Wei & Yanmin Huang & Li Zhang & Tingwei He & Saisai Li & Hsien-Yi Hsu & Chaochao Qin & Run Long & Mingjian Yuan, 2021. "High-performance large-area quasi-2D perovskite light-emitting diodes," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    5. Yu Cao & Nana Wang & He Tian & Jingshu Guo & Yingqiang Wei & Hong Chen & Yanfeng Miao & Wei Zou & Kang Pan & Yarong He & Hui Cao & You Ke & Mengmeng Xu & Ying Wang & Ming Yang & Kai Du & Zewu Fu & Dec, 2018. "Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures," Nature, Nature, vol. 562(7726), pages 249-253, October.
    6. Yanfeng Miao & You Ke & Nana Wang & Wei Zou & Mengmeng Xu & Yu Cao & Yan Sun & Rong Yang & Ying Wang & Yunfang Tong & Wenjie Xu & Liangdong Zhang & Renzhi Li & Jing Li & Haiping He & Yizheng Jin & Fen, 2019. "Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    7. Kebin Lin & Jun Xing & Li Na Quan & F. Pelayo García Arquer & Xiwen Gong & Jianxun Lu & Liqiang Xie & Weijie Zhao & Di Zhang & Chuanzhong Yan & Wenqiang Li & Xinyi Liu & Yan Lu & Jeffrey Kirman & Edwa, 2018. "Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent," Nature, Nature, vol. 562(7726), pages 245-248, October.
    8. Lin Zhu & Hui Cao & Chen Xue & Hao Zhang & Minchao Qin & Jie Wang & Kaichuan Wen & Zewu Fu & Tao Jiang & Lei Xu & Ya Zhang & Yu Cao & Cailing Tu & Ju Zhang & Dawei Liu & Guangbin Zhang & Decheng Kong , 2021. "Unveiling the additive-assisted oriented growth of perovskite crystallite for high performance light-emitting diodes," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    9. Bryan A. Rosales & Laura E. Mundt & Taylor G. Allen & David T. Moore & Kevin J. Prince & Colin A. Wolden & Garry Rumbles & Laura T. Schelhas & Lance M. Wheeler, 2020. "Reversible multicolor chromism in layered formamidinium metal halide perovskites," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    10. Naresh Kumar Kumawat & Wolfgang Tress & Feng Gao, 2021. "Mobile ions determine the luminescence yield of perovskite light-emitting diodes under pulsed operation," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
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    1. Yehui Wen & Tianchi Zhang & Xingtao Wang & Tiantian Liu & Yu Wang & Rui Zhang & Miao Kan & Li Wan & Weihua Ning & Yong Wang & Deren Yang, 2024. "Amorphous (lysine)2PbI2 layer enhanced perovskite photovoltaics," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

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