IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-33651-9.html
   My bibliography  Save this article

Assembly-induced spin transfer and distance-dependent spin coupling in atomically precise AgCu nanoclusters

Author

Listed:
  • Nan Xia

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    Anhui University)

  • Jianpei Xing

    (Ion and Electron Beams (Dalian University of Technology), Ministry of Education)

  • Di Peng

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    University of Science and Technology of China)

  • Shiyu Ji

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    University of Science and Technology of China)

  • Jun Zha

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    University of Science and Technology of China)

  • Nan Yan

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    Anhui University)

  • Yan Su

    (Ion and Electron Beams (Dalian University of Technology), Ministry of Education)

  • Xue Jiang

    (Ion and Electron Beams (Dalian University of Technology), Ministry of Education)

  • Zhi Zeng

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences)

  • Jijun Zhao

    (Ion and Electron Beams (Dalian University of Technology), Ministry of Education)

  • Zhikun Wu

    (Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences
    Anhui University)

Abstract

Nanoparticle assembly paves the way for unanticipated properties and applications from the nanoscale to the macroscopic world. However, the study of such material systems is greatly inhibited due to the obscure compositions and structures of nanoparticles (especially the surface structures). The assembly of atomically precise nanoparticles is challenging, and such an assembly of nanoparticles with metal core sizes strictly larger than 1 nm has not been achieved yet. Here, we introduced an on-site synthesis-and-assembly strategy, and successfully obtained a straight-chain assembly structure consisting of Ag77Cu22(CHT)48 (CHT: cyclohexanethiolate) nanoparticles with two nanoparticles separated by one S atom, as revealed by mass spectrometry and single crystal X-ray crystallography. Although Ag77Cu22(CHT)48 bears one unpaired shell-closing electron, the magnetic moment is found to be mainly localized at the S linker with magnetic isotropy, and the sulfur radicals were experimentally verified and found to be unstable after disassembly, demonstrating assembly-induced spin transfer. Besides, spin nanoparticles are found to couple and lose their paramagnetism at sufficiently short inter-nanoparticle distance, namely, the spin coupling depends on the inter-nanoparticle distance. However, it is not found that the spin coupling leads to the nanoparticle growth.

Suggested Citation

  • Nan Xia & Jianpei Xing & Di Peng & Shiyu Ji & Jun Zha & Nan Yan & Yan Su & Xue Jiang & Zhi Zeng & Jijun Zhao & Zhikun Wu, 2022. "Assembly-induced spin transfer and distance-dependent spin coupling in atomically precise AgCu nanoclusters," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33651-9
    DOI: 10.1038/s41467-022-33651-9
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-33651-9
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-33651-9?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Anton Kuzyk & Robert Schreiber & Zhiyuan Fan & Günther Pardatscher & Eva-Maria Roller & Alexander Högele & Friedrich C. Simmel & Alexander O. Govorov & Tim Liedl, 2012. "DNA-based self-assembly of chiral plasmonic nanostructures with tailored optical response," Nature, Nature, vol. 483(7389), pages 311-314, March.
    2. Qi Li & Jake C. Russell & Tian-Yi Luo & Xavier Roy & Nathaniel L. Rosi & Yan Zhu & Rongchao Jin, 2018. "Modulating the hierarchical fibrous assembly of Au nanoparticles with atomic precision," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    3. Zibao Gan & Jishi Chen & Juan Wang & Chengming Wang & Man-Bo Li & Chuanhao Yao & Shengli Zhuang & An Xu & Lingling Li & Zhikun Wu, 2017. "The fourth crystallographic closest packing unveiled in the gold nanocluster crystal," Nature Communications, Nature, vol. 8(1), pages 1-6, April.
    4. Yingwei Li & Meng Zhou & Yongbo Song & Tatsuya Higaki & He Wang & Rongchao Jin, 2021. "Double-helical assembly of heterodimeric nanoclusters into supercrystals," Nature, Nature, vol. 594(7863), pages 380-384, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuan Wang & Dian Niu & Guanghui Ouyang & Minghua Liu, 2022. "Double helical π-aggregate nanoarchitectonics for amplified circularly polarized luminescence," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Liang Qiao & Nia Pollard & Ravithree D. Senanayake & Zhi Yang & Minjung Kim & Arzeena S. Ali & Minh Tam Hoang & Nan Yao & Yimo Han & Rigoberto Hernandez & Andre Z. Clayborne & Matthew R. Jones, 2023. "Atomically precise nanoclusters predominantly seed gold nanoparticle syntheses," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Jun Guo & Yulong Duan & Yunling Jia & Zelong Zhao & Xiaoqing Gao & Pai Liu & Fangfang Li & Hongli Chen & Yutong Ye & Yujiao Liu & Meiting Zhao & Zhiyong Tang & Yi Liu, 2024. "Biomimetic chiral hydrogen-bonded organic-inorganic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Zhiyuan Ding & Si Gao & Weina Fang & Chen Huang & Liqi Zhou & Xudong Pei & Xiaoguo Liu & Xiaoqing Pan & Chunhai Fan & Angus I. Kirkland & Peng Wang, 2022. "Three-dimensional electron ptychography of organic–inorganic hybrid nanostructures," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Zhiwei Yang & Yanze Wei & Jingjing Wei & Zhijie Yang, 2022. "Chiral superstructures of inorganic nanorods by macroscopic mechanical grinding," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Yongbo Song & Yingwei Li & Meng Zhou & Hao Li & Tingting Xu & Chuanjun Zhou & Feng Ke & Dayujia Huo & Yan Wan & Jialong Jie & Wen Wu Xu & Manzhou Zhu & Rongchao Jin, 2022. "Atomic structure of a seed-sized gold nanoprism," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    7. Li-Juan Liu & Fahri Alkan & Shengli Zhuang & Dongyi Liu & Tehseen Nawaz & Jun Guo & Xiaozhou Luo & Jian He, 2023. "Atomically precise gold nanoclusters at the molecular-to-metallic transition with intrinsic chirality from surface layers," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Jeroen F. Dyck & Jonathan R. Burns & Kyle I. P. Huray & Albert Konijnenberg & Stefan Howorka & Frank Sobott, 2022. "Sizing up DNA nanostructure assembly with native mass spectrometry and ion mobility," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Hao Li & Tian Wang & Jiaojiao Han & Ying Xu & Xi Kang & Xiaosong Li & Manzhou Zhu, 2024. "Fluorescence resonance energy transfer in atomically precise metal nanoclusters by cocrystallization-induced spatial confinement," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    10. Huacheng Li & Xin Xu & Rongcheng Guan & Artur Movsesyan & Zhenni Lu & Qiliang Xu & Ziyun Jiang & Yurong Yang & Majid Khan & Jin Wen & Hongwei Wu & Santiago Moya & Gil Markovich & Huatian Hu & Zhiming , 2024. "Collective chiroptical activity through the interplay of excitonic and charge-transfer effects in localized plasmonic fields," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Yoon Ho Lee & Yousang Won & Jungho Mun & Sanghyuk Lee & Yeseul Kim & Bongjun Yeom & Letian Dou & Junsuk Rho & Joon Hak Oh, 2023. "Hierarchically manufactured chiral plasmonic nanostructures with gigantic chirality for polarized emission and information encryption," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Nam Heon Cho & Young Bi Kim & Yoon Young Lee & Sang Won Im & Ryeong Myeong Kim & Jeong Won Kim & Seok Daniel Namgung & Hye-Eun Lee & Hyeohn Kim & Jeong Hyun Han & Hye Won Chung & Yoon Ho Lee & Jeong W, 2022. "Adenine oligomer directed synthesis of chiral gold nanoparticles," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Yuan Zhong & Jiangwei Zhang & Tingting Li & Wenwu Xu & Qiaofeng Yao & Min Lu & Xue Bai & Zhennan Wu & Jianping Xie & Yu Zhang, 2023. "Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. Muhammad Yaseen & Muhammad Humayun & Abbas Khan & Muhammad Usman & Habib Ullah & Asif Ali Tahir & Habib Ullah, 2021. "Preparation, Functionalization, Modification, and Applications of Nanostructured Gold: A Critical Review," Energies, MDPI, vol. 14(5), pages 1-88, February.
    15. Yahong Chen & Chaoyong Yang & Zhi Zhu & Wei Sun, 2022. "Suppressing high-dimensional crystallographic defects for ultra-scaled DNA arrays," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    16. Alexandru Amărioarei & Frankie Spencer & Gefry Barad & Ana-Maria Gheorghe & Corina Iţcuş & Iris Tuşa & Ana-Maria Prelipcean & Andrei Păun & Mihaela Păun & Alfonso Rodriguez-Paton & Romică Trandafir & , 2021. "DNA-Guided Assembly for Fibril Proteins," Mathematics, MDPI, vol. 9(4), pages 1-17, February.
    17. Chang Liu & Yan Zhao & Tai-Song Zhang & Cheng-Bo Tao & Wenwen Fei & Sheng Zhang & Man-Bo Li, 2023. "Asymmetric transformation of achiral gold nanoclusters with negative nonlinear dependence between chiroptical activity and enantiomeric excess," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33651-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.