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Switching p-type to high-performance n-type organic electrochemical transistors via doped state engineering

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  • Peiyun Li

    (Peking University)

  • Junwei Shi

    (Peking University
    Peking University)

  • Yuqiu Lei

    (Peking University)

  • Zhen Huang

    (Peking University)

  • Ting Lei

    (Peking University)

Abstract

High-performance n-type organic electrochemical transistors (OECTs) are essential for logic circuits and sensors. However, the performances of n-type OECTs lag far behind that of p-type ones. Conventional wisdom posits that the LUMO energy level dictates the n-type performance. Herein, we show that engineering the doped state is more critical for n-type OECT polymers. By balancing more charges to the donor moiety, we could effectively switch a p-type polymer to high-performance n-type material. Based on this concept, the polymer, P(gTDPP2FT), exhibits a record high n-type OECT performance with μC* of 54.8 F cm−1 V−1 s−1, mobility of 0.35 cm2 V−1 s−1, and response speed of τon/τoff = 1.75/0.15 ms. Calculations and comparison studies show that the conversion is primarily due to the more uniform charges, stabilized negative polaron, enhanced conformation, and backbone planarity at negatively charged states. Our work highlights the critical role of understanding and engineering polymers’ doped states.

Suggested Citation

  • Peiyun Li & Junwei Shi & Yuqiu Lei & Zhen Huang & Ting Lei, 2022. "Switching p-type to high-performance n-type organic electrochemical transistors via doped state engineering," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33553-w
    DOI: 10.1038/s41467-022-33553-w
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    References listed on IDEAS

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    1. J. Kim & M. Swager, 2001. "Erratum: Control of conformational and interpolymer effects in conjugated polymers," Nature, Nature, vol. 413(6855), pages 548-548, October.
    2. Alexandra F. Paterson & Achilleas Savva & Shofarul Wustoni & Leonidas Tsetseris & Bryan D. Paulsen & Hendrik Faber & Abdul Hamid Emwas & Xingxing Chen & Georgios Nikiforidis & Tania C. Hidalgo & Maxim, 2020. "Water stable molecular n-doping produces organic electrochemical transistors with high transconductance and record stability," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    3. Xudong Ji & Bryan D. Paulsen & Gary K. K. Chik & Ruiheng Wu & Yuyang Yin & Paddy K. L. Chan & Jonathan Rivnay, 2021. "Mimicking associative learning using an ion-trapping non-volatile synaptic organic electrochemical transistor," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    4. Paolo Romele & Paschalis Gkoupidenis & Dimitrios A. Koutsouras & Katharina Lieberth & Zsolt M. Kovács-Vajna & Paul W. M. Blom & Fabrizio Torricelli, 2020. "Multiscale real time and high sensitivity ion detection with complementary organic electrochemical transistors amplifier," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    5. Chi-Yuan Yang & Marc-Antoine Stoeckel & Tero-Petri Ruoko & Han-Yan Wu & Xianjie Liu & Nagesh B. Kolhe & Ziang Wu & Yuttapoom Puttisong & Chiara Musumeci & Matteo Massetti & Hengda Sun & Kai Xu & Deyu , 2021. "A high-conductivity n-type polymeric ink for printed electronics," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    6. J. Kim & T. M. Swager, 2001. "Control of conformational and interpolymer effects in conjugated polymers," Nature, Nature, vol. 411(6841), pages 1030-1034, June.
    7. Alexander Giovannitti & Christian B. Nielsen & Dan-Tiberiu Sbircea & Sahika Inal & Mary Donahue & Muhammad R. Niazi & David A. Hanifi & Aram Amassian & George G. Malliaras & Jonathan Rivnay & Iain McC, 2016. "N-type organic electrochemical transistors with stability in water," Nature Communications, Nature, vol. 7(1), pages 1-10, December.
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