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Engineering active and robust alloy-based electrocatalyst by rapid Joule-heating toward ampere-level hydrogen evolution

Author

Listed:
  • Zhan Zhao

    (Ocean University of China)

  • Jianpeng Sun

    (Ocean University of China)

  • Xiang Li

    (Ocean University of China)

  • Shiyu Qin

    (Ocean University of China)

  • Chunhu Li

    (Ocean University of China)

  • Zisheng Zhang

    (University of Ottawa)

  • Zizhen Li

    (Ocean University of China)

  • Xiangchao Meng

    (Ocean University of China)

Abstract

Rational design of bimetallic alloy is an effective way to improve the electrocatalytic activity and stability of Mo-based cathode for ampere-level hydrogen evolution. However, it is still critical to realise desirable syntheses due to the wide reduction potentials between different metal elements and uncontrollable nucleation processes. Herein, we propose a rapid Joule heating method to effectively load RuMo alloy onto MoOx matrix. As-prepared catalyst exhibits excellent stability (2000 h @ 1000 mA cm−2) and ultralow overpotential (9 mV, 18 mV and 15 mV in 1 M KOH, 1 M PBS, 0.5 M H2SO4 solution, respectively) at 10 mA cm−2. Based on first-principle simulations and operando measurements, the impressive electrocatalytic stability and activity are investigated. And the role of rapid Joule heating method is highlighted and discussed in details. This study showcases rapid Joule heating as a feasible strategy to construct highly efficient alloy-based electrocatalysts.

Suggested Citation

  • Zhan Zhao & Jianpeng Sun & Xiang Li & Shiyu Qin & Chunhu Li & Zisheng Zhang & Zizhen Li & Xiangchao Meng, 2024. "Engineering active and robust alloy-based electrocatalyst by rapid Joule-heating toward ampere-level hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51976-5
    DOI: 10.1038/s41467-024-51976-5
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