IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-54601-7.html
   My bibliography  Save this article

Pd hydride metallene aerogels with lattice hydrogen participation for efficient hydrogen evolution reaction

Author

Listed:
  • Hengjia Wang

    (Central China Normal University)

  • Ying Qin

    (Central China Normal University)

  • Yu Wu

    (Central China Normal University)

  • Yiwei Qiu

    (Central China Normal University)

  • Ling Ling

    (Central China Normal University)

  • Qie Fang

    (Central China Normal University)

  • Canglong Wang

    (Chinese Academy of Science)

  • Liuyong Hu

    (Wuhan Institute of Technology)

  • Wenling Gu

    (Central China Normal University)

  • Chengzhou Zhu

    (Central China Normal University)

Abstract

Hydrogen adsorption and desorption in single-phase catalysts often occur at a single catalytic site based on the traditional hydrogen evolution reaction (HER) pathway, which makes it difficult to break the limitation entailed by the Sabatier principle. Herein, β-Pd hydride metallene (β-PdHene) aerogels are synthesized as advanced HER catalysts. A lattice hydrogen-involved mechanism is reported to separate adsorption and desorption sites, which is thermodynamically favorable compared to the traditional reaction pathway. In situ differential electrochemical mass spectrometry and theoretical calculations reveal that lattice hydrogen as additional active sites directly participate in the HER process. Consequently, β-PdHene aerogels exhibit a low overpotential of only 20 mV at 10 mA cm−2 and remarkable HER stability, which are even comparable to commercial Pt/C. Our work opens an avenue to rationally develop highly active HER catalysts, bypassing the design limitations of catalysts under traditional mechanisms.

Suggested Citation

  • Hengjia Wang & Ying Qin & Yu Wu & Yiwei Qiu & Ling Ling & Qie Fang & Canglong Wang & Liuyong Hu & Wenling Gu & Chengzhou Zhu, 2024. "Pd hydride metallene aerogels with lattice hydrogen participation for efficient hydrogen evolution reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54601-7
    DOI: 10.1038/s41467-024-54601-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-54601-7
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-54601-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Kai Liu & Hao Yang & Yilan Jiang & Zhaojun Liu & Shumeng Zhang & Zhixue Zhang & Zhun Qiao & Yiming Lu & Tao Cheng & Osamu Terasaki & Qing Zhang & Chuanbo Gao, 2023. "Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Mingchuan Luo & Zhonglong Zhao & Yelong Zhang & Yingjun Sun & Yi Xing & Fan Lv & Yong Yang & Xu Zhang & Sooyeon Hwang & Yingnan Qin & Jing-Yuan Ma & Fei Lin & Dong Su & Gang Lu & Shaojun Guo, 2019. "PdMo bimetallene for oxygen reduction catalysis," Nature, Nature, vol. 574(7776), pages 81-85, October.
    3. Lili Zhu & Haiping Lin & Youyong Li & Fan Liao & Yeshayahu Lifshitz & Minqi Sheng & Shuit-Tong Lee & Mingwang Shao, 2016. "A rhodium/silicon co-electrocatalyst design concept to surpass platinum hydrogen evolution activity at high overpotentials," Nature Communications, Nature, vol. 7(1), pages 1-7, November.
    4. Jiadong Chen & Chunhong Chen & Minkai Qin & Ben Li & Binbin Lin & Qing Mao & Hongbin Yang & Bin Liu & Yong Wang, 2022. "Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Jie Dai & Yinlong Zhu & Yu Chen & Xue Wen & Mingce Long & Xinhao Wu & Zhiwei Hu & Daqin Guan & Xixi Wang & Chuan Zhou & Qian Lin & Yifei Sun & Shih-Chang Weng & Huanting Wang & Wei Zhou & Zongping Sha, 2022. "Hydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Jiayuan Li & Jun Hu & Mingkai Zhang & Wangyan Gou & Sai Zhang & Zhong Chen & Yongquan Qu & Yuanyuan Ma, 2021. "A fundamental viewpoint on the hydrogen spillover phenomenon of electrocatalytic hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    7. Qi Hu & Keru Gao & Xiaodeng Wang & Hongju Zheng & Jianyong Cao & Lingren Mi & Qihua Huo & Hengpan Yang & Jianhong Liu & Chuanxin He, 2022. "Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    8. Dohyung Kim & Joaquin Resasco & Yi Yu & Abdullah Mohamed Asiri & Peidong Yang, 2014. "Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    9. Xing Chen & Xiao-Ting Wang & Jia-Bo Le & Shu-Min Li & Xue Wang & Yu-Jin Zhang & Petar Radjenovic & Yu Zhao & Yao-Hui Wang & Xiu-Mei Lin & Jin-Chao Dong & Jian-Feng Li, 2023. "Revealing the role of interfacial water and key intermediates at ruthenium surfaces in the alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhi Wen Chen & Jian Li & Pengfei Ou & Jianan Erick Huang & Zi Wen & LiXin Chen & Xue Yao & GuangMing Cai & Chun Cheng Yang & Chandra Veer Singh & Qing Jiang, 2024. "Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Zhenglong Fan & Fan Liao & Yujin Ji & Yang Liu & Hui Huang & Dan Wang & Kui Yin & Haiwei Yang & Mengjie Ma & Wenxiang Zhu & Meng Wang & Zhenhui Kang & Youyong Li & Mingwang Shao & Zhiwei Hu & Qi Shao, 2022. "Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Yinghao Li & Chun-Kuo Peng & Yuntong Sun & L. D. Nicole Sui & Yu-Chung Chang & San-Yuan Chen & Yingtang Zhou & Yan-Gu Lin & Jong-Min Lee, 2024. "Operando elucidation of hydrogen production mechanisms on sub-nanometric high-entropy metallenes," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    4. Sheng Zhao & Sung-Fu Hung & Liming Deng & Wen-Jing Zeng & Tian Xiao & Shaoxiong Li & Chun-Han Kuo & Han-Yi Chen & Feng Hu & Shengjie Peng, 2024. "Constructing regulable supports via non-stoichiometric engineering to stabilize ruthenium nanoparticles for enhanced pH-universal water splitting," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Zhan Zhao & Jianpeng Sun & Xiang Li & Shiyu Qin & Chunhu Li & Zisheng Zhang & Zizhen Li & Xiangchao Meng, 2024. "Engineering active and robust alloy-based electrocatalyst by rapid Joule-heating toward ampere-level hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    6. Jie Dai & Yinlong Zhu & Yu Chen & Xue Wen & Mingce Long & Xinhao Wu & Zhiwei Hu & Daqin Guan & Xixi Wang & Chuan Zhou & Qian Lin & Yifei Sun & Shih-Chang Weng & Huanting Wang & Wei Zhou & Zongping Sha, 2022. "Hydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Qian Dang & Haiping Lin & Zhenglong Fan & Lu Ma & Qi Shao & Yujin Ji & Fangfang Zheng & Shize Geng & Shi-Ze Yang & Ningning Kong & Wenxiang Zhu & Youyong Li & Fan Liao & Xiaoqing Huang & Mingwang Shao, 2021. "Iridium metallene oxide for acidic oxygen evolution catalysis," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    8. Shasha Guo & Maolin Yu & Jinn-Kye Lee & Mengyi Qiu & Dundong Yuan & Zhili Hu & Chao Zhu & Yao Wu & Zude Shi & Wei Ma & Shuangyin Wang & Yongmin He & Zhengyang Zhang & Zhuhua Zhang & Zheng Liu, 2025. "Separating nanobubble nucleation for transfer-resistance-free electrocatalysis," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    9. Anquan Zhu & Lulu Qiao & Kai Liu & Guoqiang Gan & Chuhao Luan & Dewu Lin & Yin Zhou & Shuyu Bu & Tian Zhang & Kunlun Liu & Tianyi Song & Heng Liu & Hao Li & Guo Hong & Wenjun Zhang, 2025. "Rational design of precatalysts and controlled evolution of catalyst-electrolyte interface for efficient hydrogen production," Nature Communications, Nature, vol. 16(1), pages 1-13, December.
    10. Yaoda Liu & Lei Li & Li Wang & Na Li & Xiaoxu Zhao & Ya Chen & Thangavel Sakthivel & Zhengfei Dai, 2024. "Janus electronic state of supported iridium nanoclusters for sustainable alkaline water electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Geng Wu & Xiao Han & Jinyan Cai & Peiqun Yin & Peixin Cui & Xusheng Zheng & Hai Li & Cai Chen & Gongming Wang & Xun Hong, 2022. "In-plane strain engineering in ultrathin noble metal nanosheets boosts the intrinsic electrocatalytic hydrogen evolution activity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    12. Lin He & Menggang Li & Longyu Qiu & Shuo Geng & Yequn Liu & Fenyang Tian & Mingchuan Luo & Hu Liu & Yongsheng Yu & Weiwei Yang & Shaojun Guo, 2024. "Single-atom Mo-tailored high-entropy-alloy ultrathin nanosheets with intrinsic tensile strain enhance electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    13. Ganesh, Ibram, 2016. "Electrochemical conversion of carbon dioxide into renewable fuel chemicals – The role of nanomaterials and the commercialization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1269-1297.
    14. Xianjin Shi & Wei Peng & Yu Huang & Chao Gao & Yiman Fu & Zhenyu Wang & Leting Yang & Zixuan Zhu & Junji Cao & Fei Rao & Gangqiang Zhu & Shuncheng Lee & Yujie Xiong, 2024. "Integrable utilization of intermittent sunlight and residual heat for on-demand CO2 conversion with water," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    15. Ke Chen & Guo Li & Xiaoqun Gong & Qinjuan Ren & Junying Wang & Shuang Zhao & Ling Liu & Yuxing Yan & Qingshan Liu & Yang Cao & Yaoyao Ren & Qiong Qin & Qi Xin & Shu-Lin Liu & Peiyu Yao & Bo Zhang & Ji, 2024. "Atomic-scale strain engineering of atomically resolved Pt clusters transcending natural enzymes," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    16. Chenhui Zhou & Lu Li & Zhaoqi Dong & Fan Lv & Hongyu Guo & Kai Wang & Menggang Li & Zhengyi Qian & Na Ye & Zheng Lin & Mingchuan Luo & Shaojun Guo, 2024. "Pinning effect of lattice Pb suppressing lattice oxygen reactivity of Pb-RuO2 enables stable industrial-level electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    17. Zhongzhe Wei & Zijiang Zhao & Chenglong Qiu & Songtao Huang & Zihao Yao & Mingxuan Wang & Yi Chen & Yue Lin & Xing Zhong & Xiaonian Li & Jianguo Wang, 2023. "Tripodal Pd metallenes mediated by Nb2C MXenes for boosting alkynes semihydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    18. Shan Lei & Jing Zhang & Nicholas Thomas Blum & Meng Li & Dong-Yang Zhang & Weimin Yin & Feng Zhao & Jing Lin & Peng Huang, 2022. "In vivo three-dimensional multispectral photoacoustic imaging of dual enzyme-driven cyclic cascade reaction for tumor catalytic therapy," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    19. Peng Li & Ya-Ling Jiang & Yana Men & Yu-Zhou Jiao & Shengli Chen, 2025. "Kinetic cation effect in alkaline hydrogen electrocatalysis and double layer proton transfer," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    20. Cong Zhao & Jiazheng Diao & Zhao Liu & Jie Hao & Suhang He & Shaojia Li & Xingxing Li & Guangwu Li & Qiang Fu & Chuancheng Jia & Xuefeng Guo, 2024. "Electrical monitoring of single-event protonation dynamics at the solid-liquid interface and its regulation by external mechanical forces," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54601-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.