IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v5y2014i1d10.1038_ncomms6634.html
   My bibliography  Save this article

FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes

Author

Listed:
  • Haisheng Wei

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China
    University of Chinese Academy of Sciences)

  • Xiaoyan Liu

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Aiqin Wang

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Leilei Zhang

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Botao Qiao

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China
    Arizona State University)

  • Xiaofeng Yang

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Yanqiang Huang

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Shu Miao

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

  • Jingyue Liu

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China
    Arizona State University)

  • Tao Zhang

    (Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, China)

Abstract

The catalytic hydrogenation of nitroarenes is an environmentally benign technology for the production of anilines, which are key intermediates for manufacturing agrochemicals, pharmaceuticals and dyes. Most of the precious metal catalysts, however, suffer from low chemoselectivity when one or more reducible groups are present in a nitroarene molecule. Herein we report FeOx-supported platinum single-atom and pseudo-single-atom structures as highly active, chemoselective and reusable catalysts for hydrogenation of a variety of substituted nitroarenes. For hydrogenation of 3-nitrostyrene, the catalyst yields a TOF of ~1,500 h−1, 20-fold higher than the best result reported in literature, and a selectivity to 3-aminostyrene close to 99%, the best ever achieved over platinum group metals. The superior performance can be attributed to the presence of positively charged platinum centres and the absence of Pt–Pt metallic bonding, both of which favour the preferential adsorption of nitro groups.

Suggested Citation

  • Haisheng Wei & Xiaoyan Liu & Aiqin Wang & Leilei Zhang & Botao Qiao & Xiaofeng Yang & Yanqiang Huang & Shu Miao & Jingyue Liu & Tao Zhang, 2014. "FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6634
    DOI: 10.1038/ncomms6634
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms6634
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms6634?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yan, Xianyao & Duan, Chenyu & Yu, Shuihua & Dai, Bing & Sun, Chaoying & Chu, Huaqiang, 2024. "Recent advances on CO2 reduction reactions using single-atom catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    2. Peng Rao & Yijie Deng & Wenjun Fan & Junming Luo & Peilin Deng & Jing Li & Yijun Shen & Xinlong Tian, 2022. "Movable type printing method to synthesize high-entropy single-atom catalysts," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Weiwei Fu & Jin Wan & Huijuan Zhang & Jian Li & Weigen Chen & Yuke Li & Zaiping Guo & Yu Wang, 2022. "Photoinduced loading of electron-rich Cu single atoms by moderate coordination for hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Wei Liu & Haisong Feng & Yusen Yang & Yiming Niu & Lei Wang & Pan Yin & Song Hong & Bingsen Zhang & Xin Zhang & Min Wei, 2022. "Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Zhongxin Chen & Jingting Song & Rongrong Zhang & Runlai Li & Qikun Hu & Pingping Wei & Shibo Xi & Xin Zhou & Phuc T. T. Nguyen & Hai M. Duong & Poh Seng Lee & Xiaoxu Zhao & Ming Joo Koh & Ning Yan & K, 2022. "Addressing the quantitative conversion bottleneck in single-atom catalysis," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Hongqiang Jin & Peipei Li & Peixin Cui & Jinan Shi & Wu Zhou & Xiaohu Yu & Weiguo Song & Changyan Cao, 2022. "Unprecedentedly high activity and selectivity for hydrogenation of nitroarenes with single atomic Co1-N3P1 sites," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Zhongkai Xie & Shengjie Xu & Longhua Li & Shanhe Gong & Xiaojie Wu & Dongbo Xu & Baodong Mao & Ting Zhou & Min Chen & Xiao Wang & Weidong Shi & Shuyan Song, 2024. "Well-defined diatomic catalysis for photosynthesis of C2H4 from CO2," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6634. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.