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Critical ionic transport across an oxygen-vacancy ordering transition

Author

Listed:
  • Ji Soo Lim

    (Korea Advanced Institute of Science and Technology (KAIST)
    Center for Lattice Defectronics, KAIST)

  • Ho-Hyun Nahm

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Marco Campanini

    (Electron Microscopy Center, Empa)

  • Jounghee Lee

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Yong-Jin Kim

    (Korea Advanced Institute of Science and Technology (KAIST)
    Center for Lattice Defectronics, KAIST)

  • Heung-Sik Park

    (Korea Advanced Institute of Science and Technology (KAIST)
    Center for Lattice Defectronics, KAIST)

  • Jeonghun Suh

    (Korea Advanced Institute of Science and Technology (KAIST)
    Center for Lattice Defectronics, KAIST)

  • Jun Jung

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Yongsoo Yang

    (Korea Advanced Institute of Science and Technology (KAIST))

  • Tae Yeong Koo

    (Pohang Accelerator Laboratory, POSTECH)

  • Marta D. Rossell

    (Electron Microscopy Center, Empa)

  • Yong-Hyun Kim

    (Korea Advanced Institute of Science and Technology (KAIST)
    Graduate School of Nanoscience and Technology, KAIST)

  • Chan-Ho Yang

    (Korea Advanced Institute of Science and Technology (KAIST)
    Center for Lattice Defectronics, KAIST
    KAIST Institute for the NanoCentury, KAIST)

Abstract

Phase transition points can be used to critically reduce the ionic migration activation energy, which is important for realizing high-performance electrolytes at low temperatures. Here, we demonstrate a route toward low-temperature thermionic conduction in solids, by exploiting the critically lowered activation energy associated with oxygen transport in Ca-substituted bismuth ferrite (Bi1-xCaxFeO3-δ) films. Our demonstration relies on the finding that a compositional phase transition occurs by varying Ca doping ratio across xCa ≃ 0.45 between two structural phases with oxygen-vacancy channel ordering along or crystal axis, respectively. Regardless of the atomic-scale irregularity in defect distribution at the doping ratio, the activation energy is largely suppressed to 0.43 eV, compared with ~0.9 eV measured in otherwise rigid phases. From first-principles calculations, we propose that the effective short-range attraction between two positively charged oxygen vacancies sharing lattice deformation not only forms the defect orders but also suppresses the activation energy through concerted hopping.

Suggested Citation

  • Ji Soo Lim & Ho-Hyun Nahm & Marco Campanini & Jounghee Lee & Yong-Jin Kim & Heung-Sik Park & Jeonghun Suh & Jun Jung & Yongsoo Yang & Tae Yeong Koo & Marta D. Rossell & Yong-Hyun Kim & Chan-Ho Yang, 2022. "Critical ionic transport across an oxygen-vacancy ordering transition," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32826-8
    DOI: 10.1038/s41467-022-32826-8
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    References listed on IDEAS

    as
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